SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF SOME NEW HYDROGENOXALATO ORGANOTIN (IV) COMPLEXES
The synthesis and spectroscopic studies (infrared and Mössbauer) of new hydrogenoxalato derivatives and adducts containing SnRn (R=Me, Ph; n=2, 3) residues are reported. Based on their spectroscopic data dimeric and polymeric structures containing hexacoordinated or pentacoordinated Sn are suggeste...
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| Autores principales: | , , |
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| Formato: | article |
| Lenguaje: | EN |
| Publicado: |
Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
2020
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| Materias: | |
| Acceso en línea: | https://doaj.org/article/e603dcbc6da24a0183a0e4387a5da405 |
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| Sumario: | The synthesis and spectroscopic studies (infrared and Mössbauer) of new hydrogenoxalato derivatives and adducts containing SnRn (R=Me, Ph; n=2, 3) residues are reported. Based on their spectroscopic data dimeric and polymeric structures containing hexacoordinated or pentacoordinated Sn are suggested, the hydrogenoxolate anion behaving as a monocoordinating or a monochelating ligand. In two studied adducts, supramolecular architectures may be obtained when extra hydrogen bonds involving the free NH groups are considered.
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