SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF SOME NEW HYDROGENOXALATO ORGANOTIN (IV) COMPLEXES

The synthesis and spectroscopic studies (infrared and Mössbauer) of new hydrogenoxalato derivatives and adducts containing SnRn (R=Me, Ph; n=2, 3) residues are reported. Based on their spectroscopic data dimeric and polymeric structures containing hexacoordinated or pentacoordinated Sn are suggeste...

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Autores principales:	MOUHAMADOU SEMBENE BOYE, AMINATA DIASSE-SARR, LIBASSE DIOP
Formato:	article
Lenguaje:	EN
Publicado:	Alma Mater Publishing House "Vasile Alecsandri" University of Bacau 2020
Materias:	dimeric and polymeric structures, hydrogenoxalate, monochelating, monocoordinating, octahedral or trigonal bipyramidal environments, spectroscopy, supramolecular architectures. Technology T Engineering (General). Civil engineering (General) TA1-2040
Acceso en línea:	https://doaj.org/article/e603dcbc6da24a0183a0e4387a5da405
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spelling	oai:doaj.org-article:e603dcbc6da24a0183a0e4387a5da4052021-12-02T19:52:49ZSYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF SOME NEW HYDROGENOXALATO ORGANOTIN (IV) COMPLEXES10.29081/jesr.v26i2.1722068-75592344-4932https://doaj.org/article/e603dcbc6da24a0183a0e4387a5da4052020-06-01T00:00:00Zhttp://www.jesr.ub.ro/1/article/view/172https://doaj.org/toc/2068-7559https://doaj.org/toc/2344-4932 The synthesis and spectroscopic studies (infrared and Mössbauer) of new hydrogenoxalato derivatives and adducts containing SnRn (R=Me, Ph; n=2, 3) residues are reported. Based on their spectroscopic data dimeric and polymeric structures containing hexacoordinated or pentacoordinated Sn are suggested, the hydrogenoxolate anion behaving as a monocoordinating or a monochelating ligand. In two studied adducts, supramolecular architectures may be obtained when extra hydrogen bonds involving the free NH groups are considered. MOUHAMADOU SEMBENE BOYEAMINATA DIASSE-SARRLIBASSE DIOPAlma Mater Publishing House "Vasile Alecsandri" University of Bacauarticledimeric and polymeric structures, hydrogenoxalate, monochelating, monocoordinating, octahedral or trigonal bipyramidal environments, spectroscopy, supramolecular architectures.TechnologyTEngineering (General). Civil engineering (General)TA1-2040ENJournal of Engineering Studies and Research, Vol 26, Iss 2 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	dimeric and polymeric structures, hydrogenoxalate, monochelating, monocoordinating, octahedral or trigonal bipyramidal environments, spectroscopy, supramolecular architectures. Technology T Engineering (General). Civil engineering (General) TA1-2040
spellingShingle	dimeric and polymeric structures, hydrogenoxalate, monochelating, monocoordinating, octahedral or trigonal bipyramidal environments, spectroscopy, supramolecular architectures. Technology T Engineering (General). Civil engineering (General) TA1-2040 MOUHAMADOU SEMBENE BOYE AMINATA DIASSE-SARR LIBASSE DIOP SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF SOME NEW HYDROGENOXALATO ORGANOTIN (IV) COMPLEXES
description	The synthesis and spectroscopic studies (infrared and Mössbauer) of new hydrogenoxalato derivatives and adducts containing SnRn (R=Me, Ph; n=2, 3) residues are reported. Based on their spectroscopic data dimeric and polymeric structures containing hexacoordinated or pentacoordinated Sn are suggested, the hydrogenoxolate anion behaving as a monocoordinating or a monochelating ligand. In two studied adducts, supramolecular architectures may be obtained when extra hydrogen bonds involving the free NH groups are considered.
format	article
author	MOUHAMADOU SEMBENE BOYE AMINATA DIASSE-SARR LIBASSE DIOP
author_facet	MOUHAMADOU SEMBENE BOYE AMINATA DIASSE-SARR LIBASSE DIOP
author_sort	MOUHAMADOU SEMBENE BOYE
title	SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF SOME NEW HYDROGENOXALATO ORGANOTIN (IV) COMPLEXES
title_short	SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF SOME NEW HYDROGENOXALATO ORGANOTIN (IV) COMPLEXES
title_full	SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF SOME NEW HYDROGENOXALATO ORGANOTIN (IV) COMPLEXES
title_fullStr	SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF SOME NEW HYDROGENOXALATO ORGANOTIN (IV) COMPLEXES
title_full_unstemmed	SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF SOME NEW HYDROGENOXALATO ORGANOTIN (IV) COMPLEXES
title_sort	synthesis and spectroscopic characterization of some new hydrogenoxalato organotin (iv) complexes
publisher	Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
publishDate	2020
url	https://doaj.org/article/e603dcbc6da24a0183a0e4387a5da405
work_keys_str_mv	AT mouhamadousembeneboye synthesisandspectroscopiccharacterizationofsomenewhydrogenoxalatoorganotinivcomplexes AT aminatadiassesarr synthesisandspectroscopiccharacterizationofsomenewhydrogenoxalatoorganotinivcomplexes AT libassediop synthesisandspectroscopiccharacterizationofsomenewhydrogenoxalatoorganotinivcomplexes
_version_	1718375934146379776

SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF SOME NEW HYDROGENOXALATO ORGANOTIN (IV) COMPLEXES

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