Electrochemical reduction of acetonitrile to ethylamine
Industrial synthesis of primary amine often features poor selectivity because of the formation of secondary and tertiary amine byproducts. Here, the authors report an electrocatalytic route to ethylamine through selective electroreduction of acetonitrile at ambient temperature and pressure.
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Nature Portfolio
2021
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oai:doaj.org-article:e614cd7dfdff44c8a51cddc84ba5866b2021-12-02T13:26:23ZElectrochemical reduction of acetonitrile to ethylamine10.1038/s41467-021-22291-02041-1723https://doaj.org/article/e614cd7dfdff44c8a51cddc84ba5866b2021-03-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-22291-0https://doaj.org/toc/2041-1723Industrial synthesis of primary amine often features poor selectivity because of the formation of secondary and tertiary amine byproducts. Here, the authors report an electrocatalytic route to ethylamine through selective electroreduction of acetonitrile at ambient temperature and pressure.Rong XiaDong TianShyam KattelBjorn HasaHaeun ShinXinbin MaJingguang G. ChenFeng JiaoNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-8 (2021) |
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Science Q Rong Xia Dong Tian Shyam Kattel Bjorn Hasa Haeun Shin Xinbin Ma Jingguang G. Chen Feng Jiao Electrochemical reduction of acetonitrile to ethylamine |
description |
Industrial synthesis of primary amine often features poor selectivity because of the formation of secondary and tertiary amine byproducts. Here, the authors report an electrocatalytic route to ethylamine through selective electroreduction of acetonitrile at ambient temperature and pressure. |
format |
article |
author |
Rong Xia Dong Tian Shyam Kattel Bjorn Hasa Haeun Shin Xinbin Ma Jingguang G. Chen Feng Jiao |
author_facet |
Rong Xia Dong Tian Shyam Kattel Bjorn Hasa Haeun Shin Xinbin Ma Jingguang G. Chen Feng Jiao |
author_sort |
Rong Xia |
title |
Electrochemical reduction of acetonitrile to ethylamine |
title_short |
Electrochemical reduction of acetonitrile to ethylamine |
title_full |
Electrochemical reduction of acetonitrile to ethylamine |
title_fullStr |
Electrochemical reduction of acetonitrile to ethylamine |
title_full_unstemmed |
Electrochemical reduction of acetonitrile to ethylamine |
title_sort |
electrochemical reduction of acetonitrile to ethylamine |
publisher |
Nature Portfolio |
publishDate |
2021 |
url |
https://doaj.org/article/e614cd7dfdff44c8a51cddc84ba5866b |
work_keys_str_mv |
AT rongxia electrochemicalreductionofacetonitriletoethylamine AT dongtian electrochemicalreductionofacetonitriletoethylamine AT shyamkattel electrochemicalreductionofacetonitriletoethylamine AT bjornhasa electrochemicalreductionofacetonitriletoethylamine AT haeunshin electrochemicalreductionofacetonitriletoethylamine AT xinbinma electrochemicalreductionofacetonitriletoethylamine AT jingguanggchen electrochemicalreductionofacetonitriletoethylamine AT fengjiao electrochemicalreductionofacetonitriletoethylamine |
_version_ |
1718393066433282048 |