Ammonium Formate-Pd/C as a New Reducing System for 1,2,4-Oxadiazoles. Synthesis of Guanidine Derivatives and Reductive Rearrangement to Quinazolin-4-Ones with Potential Anti-Diabetic Activity

Ammonium Formate-Pd/C as a New Reducing System for 1,2,4-Oxadiazoles. Synthesis of Guanidine Derivatives and Reductive Rearrangement to Quinazolin-4-Ones with Potential Anti-Diabetic Activity

1,2,4-Oxadiazole is a heterocycle with wide reactivity and many useful applications. The reactive O-N bond is usually reduced using molecular hydrogen to obtain amidine derivatives. NH<sub>4</sub>CO<sub>2</sub>H-Pd/C is here demonstrated as a new system for the O-N reduction,...

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Detalles Bibliográficos
Autores principales: Paola Marzullo, Sonya Vasto, Silvestre Buscemi, Andrea Pace, Domenico Nuzzo, Antonio Palumbo Piccionello
Formato: article
Lenguaje:EN
Publicado: MDPI AG 2021
Materias:
1,2,4-oxadiazole
reduction
quinazolin-4-one
acylguanidine
diacylguanidine
ammonium formate
Biology (General)
QH301-705.5
Chemistry
QD1-999
Acceso en línea:https://doaj.org/article/e64d262621b6435ab975ad4d9c74eaab
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