Smartphone-Based Colorimetric Detection of Chromium (VI) by Maleic Acid-Functionalized Gold Nanoparticles

Because of the significant environmental pollution produced by human activities, there is an ongoing need to develop transportable, simple, and reliable techniques for determining trace contaminants on the spot. This work reported a colorimetric detection method for aqueous Cr(VI) sensing by maleic...

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Autores principales: Ahmed Mohamed, Xuemeng Li, Chengfei Li, Xuegang Li, Chao Yuan, Hassan Barakat
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Lenguaje:EN
Publicado: MDPI AG 2021
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spelling oai:doaj.org-article:e6ab29698e3a40818d6eb9c6eb7bd5f22021-11-25T16:39:57ZSmartphone-Based Colorimetric Detection of Chromium (VI) by Maleic Acid-Functionalized Gold Nanoparticles10.3390/app1122108942076-3417https://doaj.org/article/e6ab29698e3a40818d6eb9c6eb7bd5f22021-11-01T00:00:00Zhttps://www.mdpi.com/2076-3417/11/22/10894https://doaj.org/toc/2076-3417Because of the significant environmental pollution produced by human activities, there is an ongoing need to develop transportable, simple, and reliable techniques for determining trace contaminants on the spot. This work reported a colorimetric detection method for aqueous Cr(VI) sensing by maleic acid-functionalized gold nanoparticles with high sensitivity and selectivity. The wine-red color of the probe solution can change to gray even in the presence of 1.0 µg L<sup>−1</sup> of aqueous Cr(VI). Moreover, with the assistance of a smartphone installed with a commercially available color scan application software, its concentration of could be readily quantified on the spot without the help of UV-Vis spectrometer. The detection limit could reach as low as 0.1 µg L<sup>−1</sup> with linear range from 0.2 to 2.0 µg L<sup>−1</sup>. Most importantly, the coefficient variation of the proposed smartphone-based method was equivalent to that of colorimetry, demonstrating the high accuracy of the proposed method for accurate detection of Cr(VI) in resource-constrained countries. Conclusively, with the help of the smartphone, this nanomaterials-based probe demonstrated the potential in the field of environment monitoring for on-site quantitative detection of any pollutants in resource-constrained countries.Ahmed MohamedXuemeng LiChengfei LiXuegang LiChao YuanHassan BarakatMDPI AGarticleChromiumcolorimetric measurementsmartphone-based detectiongold nanoparticlesTechnologyTEngineering (General). Civil engineering (General)TA1-2040Biology (General)QH301-705.5PhysicsQC1-999ChemistryQD1-999ENApplied Sciences, Vol 11, Iss 10894, p 10894 (2021)
institution DOAJ
collection DOAJ
language EN
topic Chromium
colorimetric measurement
smartphone-based detection
gold nanoparticles
Technology
T
Engineering (General). Civil engineering (General)
TA1-2040
Biology (General)
QH301-705.5
Physics
QC1-999
Chemistry
QD1-999
spellingShingle Chromium
colorimetric measurement
smartphone-based detection
gold nanoparticles
Technology
T
Engineering (General). Civil engineering (General)
TA1-2040
Biology (General)
QH301-705.5
Physics
QC1-999
Chemistry
QD1-999
Ahmed Mohamed
Xuemeng Li
Chengfei Li
Xuegang Li
Chao Yuan
Hassan Barakat
Smartphone-Based Colorimetric Detection of Chromium (VI) by Maleic Acid-Functionalized Gold Nanoparticles
description Because of the significant environmental pollution produced by human activities, there is an ongoing need to develop transportable, simple, and reliable techniques for determining trace contaminants on the spot. This work reported a colorimetric detection method for aqueous Cr(VI) sensing by maleic acid-functionalized gold nanoparticles with high sensitivity and selectivity. The wine-red color of the probe solution can change to gray even in the presence of 1.0 µg L<sup>−1</sup> of aqueous Cr(VI). Moreover, with the assistance of a smartphone installed with a commercially available color scan application software, its concentration of could be readily quantified on the spot without the help of UV-Vis spectrometer. The detection limit could reach as low as 0.1 µg L<sup>−1</sup> with linear range from 0.2 to 2.0 µg L<sup>−1</sup>. Most importantly, the coefficient variation of the proposed smartphone-based method was equivalent to that of colorimetry, demonstrating the high accuracy of the proposed method for accurate detection of Cr(VI) in resource-constrained countries. Conclusively, with the help of the smartphone, this nanomaterials-based probe demonstrated the potential in the field of environment monitoring for on-site quantitative detection of any pollutants in resource-constrained countries.
format article
author Ahmed Mohamed
Xuemeng Li
Chengfei Li
Xuegang Li
Chao Yuan
Hassan Barakat
author_facet Ahmed Mohamed
Xuemeng Li
Chengfei Li
Xuegang Li
Chao Yuan
Hassan Barakat
author_sort Ahmed Mohamed
title Smartphone-Based Colorimetric Detection of Chromium (VI) by Maleic Acid-Functionalized Gold Nanoparticles
title_short Smartphone-Based Colorimetric Detection of Chromium (VI) by Maleic Acid-Functionalized Gold Nanoparticles
title_full Smartphone-Based Colorimetric Detection of Chromium (VI) by Maleic Acid-Functionalized Gold Nanoparticles
title_fullStr Smartphone-Based Colorimetric Detection of Chromium (VI) by Maleic Acid-Functionalized Gold Nanoparticles
title_full_unstemmed Smartphone-Based Colorimetric Detection of Chromium (VI) by Maleic Acid-Functionalized Gold Nanoparticles
title_sort smartphone-based colorimetric detection of chromium (vi) by maleic acid-functionalized gold nanoparticles
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/e6ab29698e3a40818d6eb9c6eb7bd5f2
work_keys_str_mv AT ahmedmohamed smartphonebasedcolorimetricdetectionofchromiumvibymaleicacidfunctionalizedgoldnanoparticles
AT xuemengli smartphonebasedcolorimetricdetectionofchromiumvibymaleicacidfunctionalizedgoldnanoparticles
AT chengfeili smartphonebasedcolorimetricdetectionofchromiumvibymaleicacidfunctionalizedgoldnanoparticles
AT xuegangli smartphonebasedcolorimetricdetectionofchromiumvibymaleicacidfunctionalizedgoldnanoparticles
AT chaoyuan smartphonebasedcolorimetricdetectionofchromiumvibymaleicacidfunctionalizedgoldnanoparticles
AT hassanbarakat smartphonebasedcolorimetricdetectionofchromiumvibymaleicacidfunctionalizedgoldnanoparticles
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