Fabrication of NiO/SnO2 heterojunction based photocatalyst for efficient sunlight degradation of organic dyes
A new composite oxide (NiO/SnO2) photocatalyst was synthesized by simple co-precipitation route. The structural elucidation of composite oxide photocatalyst was carried out via X-rays diffraction (XRD) technique. The morphology was determined by scanning electron microscopy (SEM). The Fourier transf...
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oai:doaj.org-article:e766cfd19b6f4a1990f1b896cf253fbc2021-11-17T14:21:57ZFabrication of NiO/SnO2 heterojunction based photocatalyst for efficient sunlight degradation of organic dyes1658-365510.1080/16583655.2021.1996135https://doaj.org/article/e766cfd19b6f4a1990f1b896cf253fbc2021-01-01T00:00:00Zhttp://dx.doi.org/10.1080/16583655.2021.1996135https://doaj.org/toc/1658-3655A new composite oxide (NiO/SnO2) photocatalyst was synthesized by simple co-precipitation route. The structural elucidation of composite oxide photocatalyst was carried out via X-rays diffraction (XRD) technique. The morphology was determined by scanning electron microscopy (SEM). The Fourier transform infra-red (FTIR) and UV–visible spectroscopic techniques revealed the spectral and optical features. XRD analysis confirmed the formation of binary metal oxide nanocomposite comprising NiO in cubic and SnO2 in the tetragonal crystalline phase. The crystallite size for NiO/SnO2 calculated from XRD was < 15 nm. The spectroscopic studies also supported the XRD data. The morphological study of NiO/SnO2 revealed the formation of relatively small rounded nanoparticles. The solar light driven photocatalytic degradation study showed about 54% degradation of methylene blue and 34% degradation of Congo red and the value of rate constant for NiO/SnO2 was found to be 0.0059 min−1. The mechanism of degradation of dyes was also explored and discussed.Imran ShakirSajjad HaiderPhilips O. AgboolaNajeeb Faud Al-KhalliTaylor & Francis Grouparticlecomposite oxidecoprecipitationphotocatalysisdyes degradationScience (General)Q1-390ENJournal of Taibah University for Science, Vol 15, Iss 1, Pp 656-665 (2021) |
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composite oxide coprecipitation photocatalysis dyes degradation Science (General) Q1-390 |
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composite oxide coprecipitation photocatalysis dyes degradation Science (General) Q1-390 Imran Shakir Sajjad Haider Philips O. Agboola Najeeb Faud Al-Khalli Fabrication of NiO/SnO2 heterojunction based photocatalyst for efficient sunlight degradation of organic dyes |
description |
A new composite oxide (NiO/SnO2) photocatalyst was synthesized by simple co-precipitation route. The structural elucidation of composite oxide photocatalyst was carried out via X-rays diffraction (XRD) technique. The morphology was determined by scanning electron microscopy (SEM). The Fourier transform infra-red (FTIR) and UV–visible spectroscopic techniques revealed the spectral and optical features. XRD analysis confirmed the formation of binary metal oxide nanocomposite comprising NiO in cubic and SnO2 in the tetragonal crystalline phase. The crystallite size for NiO/SnO2 calculated from XRD was < 15 nm. The spectroscopic studies also supported the XRD data. The morphological study of NiO/SnO2 revealed the formation of relatively small rounded nanoparticles. The solar light driven photocatalytic degradation study showed about 54% degradation of methylene blue and 34% degradation of Congo red and the value of rate constant for NiO/SnO2 was found to be 0.0059 min−1. The mechanism of degradation of dyes was also explored and discussed. |
format |
article |
author |
Imran Shakir Sajjad Haider Philips O. Agboola Najeeb Faud Al-Khalli |
author_facet |
Imran Shakir Sajjad Haider Philips O. Agboola Najeeb Faud Al-Khalli |
author_sort |
Imran Shakir |
title |
Fabrication of NiO/SnO2 heterojunction based photocatalyst for efficient sunlight degradation of organic dyes |
title_short |
Fabrication of NiO/SnO2 heterojunction based photocatalyst for efficient sunlight degradation of organic dyes |
title_full |
Fabrication of NiO/SnO2 heterojunction based photocatalyst for efficient sunlight degradation of organic dyes |
title_fullStr |
Fabrication of NiO/SnO2 heterojunction based photocatalyst for efficient sunlight degradation of organic dyes |
title_full_unstemmed |
Fabrication of NiO/SnO2 heterojunction based photocatalyst for efficient sunlight degradation of organic dyes |
title_sort |
fabrication of nio/sno2 heterojunction based photocatalyst for efficient sunlight degradation of organic dyes |
publisher |
Taylor & Francis Group |
publishDate |
2021 |
url |
https://doaj.org/article/e766cfd19b6f4a1990f1b896cf253fbc |
work_keys_str_mv |
AT imranshakir fabricationofniosno2heterojunctionbasedphotocatalystforefficientsunlightdegradationoforganicdyes AT sajjadhaider fabricationofniosno2heterojunctionbasedphotocatalystforefficientsunlightdegradationoforganicdyes AT philipsoagboola fabricationofniosno2heterojunctionbasedphotocatalystforefficientsunlightdegradationoforganicdyes AT najeebfaudalkhalli fabricationofniosno2heterojunctionbasedphotocatalystforefficientsunlightdegradationoforganicdyes |
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1718425517184516096 |