Fabrication of NiO/SnO2 heterojunction based photocatalyst for efficient sunlight degradation of organic dyes

A new composite oxide (NiO/SnO2) photocatalyst was synthesized by simple co-precipitation route. The structural elucidation of composite oxide photocatalyst was carried out via X-rays diffraction (XRD) technique. The morphology was determined by scanning electron microscopy (SEM). The Fourier transf...

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Autores principales: Imran Shakir, Sajjad Haider, Philips O. Agboola, Najeeb Faud Al-Khalli
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Publicado: Taylor & Francis Group 2021
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spelling oai:doaj.org-article:e766cfd19b6f4a1990f1b896cf253fbc2021-11-17T14:21:57ZFabrication of NiO/SnO2 heterojunction based photocatalyst for efficient sunlight degradation of organic dyes1658-365510.1080/16583655.2021.1996135https://doaj.org/article/e766cfd19b6f4a1990f1b896cf253fbc2021-01-01T00:00:00Zhttp://dx.doi.org/10.1080/16583655.2021.1996135https://doaj.org/toc/1658-3655A new composite oxide (NiO/SnO2) photocatalyst was synthesized by simple co-precipitation route. The structural elucidation of composite oxide photocatalyst was carried out via X-rays diffraction (XRD) technique. The morphology was determined by scanning electron microscopy (SEM). The Fourier transform infra-red (FTIR) and UV–visible spectroscopic techniques revealed the spectral and optical features. XRD analysis confirmed the formation of binary metal oxide nanocomposite comprising NiO in cubic and SnO2 in the tetragonal crystalline phase. The crystallite size for NiO/SnO2 calculated from XRD was < 15 nm. The spectroscopic studies also supported the XRD data. The morphological study of NiO/SnO2 revealed the formation of relatively small rounded nanoparticles. The solar light driven photocatalytic degradation study showed about 54% degradation of methylene blue and 34% degradation of Congo red and the value of rate constant for NiO/SnO2 was found to be 0.0059 min−1. The mechanism of degradation of dyes was also explored and discussed.Imran ShakirSajjad HaiderPhilips O. AgboolaNajeeb Faud Al-KhalliTaylor & Francis Grouparticlecomposite oxidecoprecipitationphotocatalysisdyes degradationScience (General)Q1-390ENJournal of Taibah University for Science, Vol 15, Iss 1, Pp 656-665 (2021)
institution DOAJ
collection DOAJ
language EN
topic composite oxide
coprecipitation
photocatalysis
dyes degradation
Science (General)
Q1-390
spellingShingle composite oxide
coprecipitation
photocatalysis
dyes degradation
Science (General)
Q1-390
Imran Shakir
Sajjad Haider
Philips O. Agboola
Najeeb Faud Al-Khalli
Fabrication of NiO/SnO2 heterojunction based photocatalyst for efficient sunlight degradation of organic dyes
description A new composite oxide (NiO/SnO2) photocatalyst was synthesized by simple co-precipitation route. The structural elucidation of composite oxide photocatalyst was carried out via X-rays diffraction (XRD) technique. The morphology was determined by scanning electron microscopy (SEM). The Fourier transform infra-red (FTIR) and UV–visible spectroscopic techniques revealed the spectral and optical features. XRD analysis confirmed the formation of binary metal oxide nanocomposite comprising NiO in cubic and SnO2 in the tetragonal crystalline phase. The crystallite size for NiO/SnO2 calculated from XRD was < 15 nm. The spectroscopic studies also supported the XRD data. The morphological study of NiO/SnO2 revealed the formation of relatively small rounded nanoparticles. The solar light driven photocatalytic degradation study showed about 54% degradation of methylene blue and 34% degradation of Congo red and the value of rate constant for NiO/SnO2 was found to be 0.0059 min−1. The mechanism of degradation of dyes was also explored and discussed.
format article
author Imran Shakir
Sajjad Haider
Philips O. Agboola
Najeeb Faud Al-Khalli
author_facet Imran Shakir
Sajjad Haider
Philips O. Agboola
Najeeb Faud Al-Khalli
author_sort Imran Shakir
title Fabrication of NiO/SnO2 heterojunction based photocatalyst for efficient sunlight degradation of organic dyes
title_short Fabrication of NiO/SnO2 heterojunction based photocatalyst for efficient sunlight degradation of organic dyes
title_full Fabrication of NiO/SnO2 heterojunction based photocatalyst for efficient sunlight degradation of organic dyes
title_fullStr Fabrication of NiO/SnO2 heterojunction based photocatalyst for efficient sunlight degradation of organic dyes
title_full_unstemmed Fabrication of NiO/SnO2 heterojunction based photocatalyst for efficient sunlight degradation of organic dyes
title_sort fabrication of nio/sno2 heterojunction based photocatalyst for efficient sunlight degradation of organic dyes
publisher Taylor & Francis Group
publishDate 2021
url https://doaj.org/article/e766cfd19b6f4a1990f1b896cf253fbc
work_keys_str_mv AT imranshakir fabricationofniosno2heterojunctionbasedphotocatalystforefficientsunlightdegradationoforganicdyes
AT sajjadhaider fabricationofniosno2heterojunctionbasedphotocatalystforefficientsunlightdegradationoforganicdyes
AT philipsoagboola fabricationofniosno2heterojunctionbasedphotocatalystforefficientsunlightdegradationoforganicdyes
AT najeebfaudalkhalli fabricationofniosno2heterojunctionbasedphotocatalystforefficientsunlightdegradationoforganicdyes
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