Stereoselective alkoxycarbonylation of unactivated C(sp3)–H bonds with alkyl chloroformates via Pd(II)/Pd(IV) catalysis

Carbonylation of unactivated C-H bonds is typically carried out on primary C-H sites using gaseous carbon monoxide. Here the authors report a palladium cataylsed alkoxycarbonylation process using alkyl chloroformates that functionalises more challenging unactivated secondary C-H sites.

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Autores principales:	Gang Liao, Xue-Song Yin, Kai Chen, Qi Zhang, Shuo-Qing Zhang, Bing-Feng Shi
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2016
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/e79fad644ab943149229cbef60c494d5
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spelling	oai:doaj.org-article:e79fad644ab943149229cbef60c494d52021-12-02T16:49:41ZStereoselective alkoxycarbonylation of unactivated C(sp3)–H bonds with alkyl chloroformates via Pd(II)/Pd(IV) catalysis10.1038/ncomms129012041-1723https://doaj.org/article/e79fad644ab943149229cbef60c494d52016-09-01T00:00:00Zhttps://doi.org/10.1038/ncomms12901https://doaj.org/toc/2041-1723Carbonylation of unactivated C-H bonds is typically carried out on primary C-H sites using gaseous carbon monoxide. Here the authors report a palladium cataylsed alkoxycarbonylation process using alkyl chloroformates that functionalises more challenging unactivated secondary C-H sites.Gang LiaoXue-Song YinKai ChenQi ZhangShuo-Qing ZhangBing-Feng ShiNature PortfolioarticleScienceQENNature Communications, Vol 7, Iss 1, Pp 1-9 (2016)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Gang Liao Xue-Song Yin Kai Chen Qi Zhang Shuo-Qing Zhang Bing-Feng Shi Stereoselective alkoxycarbonylation of unactivated C(sp3)–H bonds with alkyl chloroformates via Pd(II)/Pd(IV) catalysis
description	Carbonylation of unactivated C-H bonds is typically carried out on primary C-H sites using gaseous carbon monoxide. Here the authors report a palladium cataylsed alkoxycarbonylation process using alkyl chloroformates that functionalises more challenging unactivated secondary C-H sites.
format	article
author	Gang Liao Xue-Song Yin Kai Chen Qi Zhang Shuo-Qing Zhang Bing-Feng Shi
author_facet	Gang Liao Xue-Song Yin Kai Chen Qi Zhang Shuo-Qing Zhang Bing-Feng Shi
author_sort	Gang Liao
title	Stereoselective alkoxycarbonylation of unactivated C(sp3)–H bonds with alkyl chloroformates via Pd(II)/Pd(IV) catalysis
title_short	Stereoselective alkoxycarbonylation of unactivated C(sp3)–H bonds with alkyl chloroformates via Pd(II)/Pd(IV) catalysis
title_full	Stereoselective alkoxycarbonylation of unactivated C(sp3)–H bonds with alkyl chloroformates via Pd(II)/Pd(IV) catalysis
title_fullStr	Stereoselective alkoxycarbonylation of unactivated C(sp3)–H bonds with alkyl chloroformates via Pd(II)/Pd(IV) catalysis
title_full_unstemmed	Stereoselective alkoxycarbonylation of unactivated C(sp3)–H bonds with alkyl chloroformates via Pd(II)/Pd(IV) catalysis
title_sort	stereoselective alkoxycarbonylation of unactivated c(sp3)–h bonds with alkyl chloroformates via pd(ii)/pd(iv) catalysis
publisher	Nature Portfolio
publishDate	2016
url	https://doaj.org/article/e79fad644ab943149229cbef60c494d5
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Stereoselective alkoxycarbonylation of unactivated C(sp3)–H bonds with alkyl chloroformates via Pd(II)/Pd(IV) catalysis

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