NEW SELENATO TRIPHENYLTIN (IV) AND TRIMETHYLTIN (IV) DERIVATIVES: SYNTHESIS, INFRARED AND NMR STUDIES
Five derivatives of general formulae [cation] [SeO4SnR3] (R = Ph, Me) have been studied by infrared (IR) and nuclear magnetic resonance (NMR) spectroscopy. The suggested structures are infinite chains or oligomers, the environment around the tin centre being trans trigonal bipyramidal, the phenyl a...
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Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
2017
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oai:doaj.org-article:e7ebd8b6183a40d08eb2f60c9a4a35a22021-12-02T19:52:43ZNEW SELENATO TRIPHENYLTIN (IV) AND TRIMETHYLTIN (IV) DERIVATIVES: SYNTHESIS, INFRARED AND NMR STUDIES10.29081/jesr.v23i2.812068-75592344-4932https://doaj.org/article/e7ebd8b6183a40d08eb2f60c9a4a35a22017-06-01T00:00:00Zhttp://www.jesr.ub.ro/1/article/view/81https://doaj.org/toc/2068-7559https://doaj.org/toc/2344-4932 Five derivatives of general formulae [cation] [SeO4SnR3] (R = Ph, Me) have been studied by infrared (IR) and nuclear magnetic resonance (NMR) spectroscopy. The suggested structures are infinite chains or oligomers, the environment around the tin centre being trans trigonal bipyramidal, the phenyl and methyl substituants occupying equatorial positions, the selenate anion behaving as a bridging bidentate ligand and occupying the apical positions. When cations are involved, supramolecular architectures may be obtained. WALY DIALLOLIBASSE DIOPAlma Mater Publishing House "Vasile Alecsandri" University of Bacauarticlebridging anionderivativessupramolecular architecturestrans trigonal bipyramidal environmenttriorganotin (IV) residuesTechnologyTEngineering (General). Civil engineering (General)TA1-2040ENJournal of Engineering Studies and Research, Vol 23, Iss 2 (2017) |
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bridging anion derivatives supramolecular architectures trans trigonal bipyramidal environment triorganotin (IV) residues Technology T Engineering (General). Civil engineering (General) TA1-2040 |
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bridging anion derivatives supramolecular architectures trans trigonal bipyramidal environment triorganotin (IV) residues Technology T Engineering (General). Civil engineering (General) TA1-2040 WALY DIALLO LIBASSE DIOP NEW SELENATO TRIPHENYLTIN (IV) AND TRIMETHYLTIN (IV) DERIVATIVES: SYNTHESIS, INFRARED AND NMR STUDIES |
description |
Five derivatives of general formulae [cation] [SeO4SnR3] (R = Ph, Me) have been studied by infrared (IR) and nuclear magnetic resonance (NMR) spectroscopy. The suggested structures are infinite chains or oligomers, the environment around the tin centre being trans trigonal bipyramidal, the phenyl and methyl substituants occupying equatorial positions, the selenate anion behaving as a bridging bidentate ligand and occupying the apical positions. When cations are involved, supramolecular architectures may be obtained.
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article |
author |
WALY DIALLO LIBASSE DIOP |
author_facet |
WALY DIALLO LIBASSE DIOP |
author_sort |
WALY DIALLO |
title |
NEW SELENATO TRIPHENYLTIN (IV) AND TRIMETHYLTIN (IV) DERIVATIVES: SYNTHESIS, INFRARED AND NMR STUDIES |
title_short |
NEW SELENATO TRIPHENYLTIN (IV) AND TRIMETHYLTIN (IV) DERIVATIVES: SYNTHESIS, INFRARED AND NMR STUDIES |
title_full |
NEW SELENATO TRIPHENYLTIN (IV) AND TRIMETHYLTIN (IV) DERIVATIVES: SYNTHESIS, INFRARED AND NMR STUDIES |
title_fullStr |
NEW SELENATO TRIPHENYLTIN (IV) AND TRIMETHYLTIN (IV) DERIVATIVES: SYNTHESIS, INFRARED AND NMR STUDIES |
title_full_unstemmed |
NEW SELENATO TRIPHENYLTIN (IV) AND TRIMETHYLTIN (IV) DERIVATIVES: SYNTHESIS, INFRARED AND NMR STUDIES |
title_sort |
new selenato triphenyltin (iv) and trimethyltin (iv) derivatives: synthesis, infrared and nmr studies |
publisher |
Alma Mater Publishing House "Vasile Alecsandri" University of Bacau |
publishDate |
2017 |
url |
https://doaj.org/article/e7ebd8b6183a40d08eb2f60c9a4a35a2 |
work_keys_str_mv |
AT walydiallo newselenatotriphenyltinivandtrimethyltinivderivativessynthesisinfraredandnmrstudies AT libassediop newselenatotriphenyltinivandtrimethyltinivderivativessynthesisinfraredandnmrstudies |
_version_ |
1718375935107923968 |