NEW SELENATO TRIPHENYLTIN (IV) AND TRIMETHYLTIN (IV) DERIVATIVES: SYNTHESIS, INFRARED AND NMR STUDIES

Five derivatives of general formulae [cation] [SeO4SnR3] (R = Ph, Me) have been studied by infrared (IR) and nuclear magnetic resonance (NMR) spectroscopy. The suggested structures are infinite chains or oligomers, the environment around the tin centre being trans trigonal bipyramidal, the phenyl a...

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Autores principales: WALY DIALLO, LIBASSE DIOP
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Lenguaje:EN
Publicado: Alma Mater Publishing House "Vasile Alecsandri" University of Bacau 2017
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Acceso en línea:https://doaj.org/article/e7ebd8b6183a40d08eb2f60c9a4a35a2
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spelling oai:doaj.org-article:e7ebd8b6183a40d08eb2f60c9a4a35a22021-12-02T19:52:43ZNEW SELENATO TRIPHENYLTIN (IV) AND TRIMETHYLTIN (IV) DERIVATIVES: SYNTHESIS, INFRARED AND NMR STUDIES10.29081/jesr.v23i2.812068-75592344-4932https://doaj.org/article/e7ebd8b6183a40d08eb2f60c9a4a35a22017-06-01T00:00:00Zhttp://www.jesr.ub.ro/1/article/view/81https://doaj.org/toc/2068-7559https://doaj.org/toc/2344-4932 Five derivatives of general formulae [cation] [SeO4SnR3] (R = Ph, Me) have been studied by infrared (IR) and nuclear magnetic resonance (NMR) spectroscopy. The suggested structures are infinite chains or oligomers, the environment around the tin centre being trans trigonal bipyramidal, the phenyl and methyl substituants occupying equatorial positions, the selenate anion behaving as a bridging bidentate ligand and occupying the apical positions. When cations are involved, supramolecular architectures may be obtained. WALY DIALLOLIBASSE DIOPAlma Mater Publishing House "Vasile Alecsandri" University of Bacauarticlebridging anionderivativessupramolecular architecturestrans trigonal bipyramidal environmenttriorganotin (IV) residuesTechnologyTEngineering (General). Civil engineering (General)TA1-2040ENJournal of Engineering Studies and Research, Vol 23, Iss 2 (2017)
institution DOAJ
collection DOAJ
language EN
topic bridging anion
derivatives
supramolecular architectures
trans trigonal bipyramidal environment
triorganotin (IV) residues
Technology
T
Engineering (General). Civil engineering (General)
TA1-2040
spellingShingle bridging anion
derivatives
supramolecular architectures
trans trigonal bipyramidal environment
triorganotin (IV) residues
Technology
T
Engineering (General). Civil engineering (General)
TA1-2040
WALY DIALLO
LIBASSE DIOP
NEW SELENATO TRIPHENYLTIN (IV) AND TRIMETHYLTIN (IV) DERIVATIVES: SYNTHESIS, INFRARED AND NMR STUDIES
description Five derivatives of general formulae [cation] [SeO4SnR3] (R = Ph, Me) have been studied by infrared (IR) and nuclear magnetic resonance (NMR) spectroscopy. The suggested structures are infinite chains or oligomers, the environment around the tin centre being trans trigonal bipyramidal, the phenyl and methyl substituants occupying equatorial positions, the selenate anion behaving as a bridging bidentate ligand and occupying the apical positions. When cations are involved, supramolecular architectures may be obtained.
format article
author WALY DIALLO
LIBASSE DIOP
author_facet WALY DIALLO
LIBASSE DIOP
author_sort WALY DIALLO
title NEW SELENATO TRIPHENYLTIN (IV) AND TRIMETHYLTIN (IV) DERIVATIVES: SYNTHESIS, INFRARED AND NMR STUDIES
title_short NEW SELENATO TRIPHENYLTIN (IV) AND TRIMETHYLTIN (IV) DERIVATIVES: SYNTHESIS, INFRARED AND NMR STUDIES
title_full NEW SELENATO TRIPHENYLTIN (IV) AND TRIMETHYLTIN (IV) DERIVATIVES: SYNTHESIS, INFRARED AND NMR STUDIES
title_fullStr NEW SELENATO TRIPHENYLTIN (IV) AND TRIMETHYLTIN (IV) DERIVATIVES: SYNTHESIS, INFRARED AND NMR STUDIES
title_full_unstemmed NEW SELENATO TRIPHENYLTIN (IV) AND TRIMETHYLTIN (IV) DERIVATIVES: SYNTHESIS, INFRARED AND NMR STUDIES
title_sort new selenato triphenyltin (iv) and trimethyltin (iv) derivatives: synthesis, infrared and nmr studies
publisher Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
publishDate 2017
url https://doaj.org/article/e7ebd8b6183a40d08eb2f60c9a4a35a2
work_keys_str_mv AT walydiallo newselenatotriphenyltinivandtrimethyltinivderivativessynthesisinfraredandnmrstudies
AT libassediop newselenatotriphenyltinivandtrimethyltinivderivativessynthesisinfraredandnmrstudies
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