Effect of Cu doping on the photocatalytic activity of InVO4 for hazardous dye photodegradation under LED light and its mechanism
Cu doped InVO4 (xCu-InVO4 (x = 0.06–0.15 wt %) was synthesized by a facile one-pot hydrothermal method for the removal of methylene blue (MB) under LED light irradiation. The X-ray photoelectron spectroscopy (XPS) analysis indicated the coexistence of V5+ and V4+ species due to the O-deficient natur...
Guardado en:
| Autores principales: | , , , |
|---|---|
| Formato: | article |
| Lenguaje: | EN |
| Publicado: |
IWA Publishing
2021
|
| Materias: | |
| Acceso en línea: | https://doaj.org/article/e836f6371bd847528668e536e8df9fe3 |
| Etiquetas: |
Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
|
| Sumario: | Cu doped InVO4 (xCu-InVO4 (x = 0.06–0.15 wt %) was synthesized by a facile one-pot hydrothermal method for the removal of methylene blue (MB) under LED light irradiation. The X-ray photoelectron spectroscopy (XPS) analysis indicated the coexistence of V5+ and V4+ species due to the O-deficient nature of the xCu-InVO4. The synthesized photocatalysts displayed a morphology of spherical and square shaped particles (20–40 nm) and micro-sized rectangle rods with a length range of 100–200 μm. The xCu-InVO4 exhibited superior adsorption and photodegradation efficiency compared to pristine InVO4 and TiO2 due to the presence of O2 vacancies, V4+/V5+ species, and Cu dopant. The optimum reaction conditions were found to be 5 mg L−1 (MB concentration), pH 6, and 100 mg of photocatalyst mass with a removal efficiency and mineralization degree of 100% and 96.67%, respectively. The main active species responsible for the degradation of MB were •OH radicals and h+. Reusability studies indicated that the 0.13Cu-InVO4 was deactivated after a single cycle of photocatalytic reaction due to significant leaching of V4+ and Cu2+ species. HIGHLIGHTS
xCu-InVO4 (x = 0.06 − 0.15 wt%) were synthesized via the hydrothermal method.;
0.13Cu-InVO4 active under the LED light irradiation for MB removal.;
Optimized catalytic conditions displayed complete MB removal with >96% mineralization.;
0.13Cu-InVO4 deactivated after first use due to V4+ and Cu2+ species leaching.; |
|---|