Easy access to nucleophilic boron through diborane to magnesium boryl metathesis

Organoboranes are widely employed in organic synthesis and typically are prepared using electrophilic boron sources. Here the authors report a route to nucleophilic boryl anions via organomagnesium-driven cleavage of boron-boron bonds.

Guardado en:

Detalles Bibliográficos
Autores principales:	Anne-Frédérique Pécharman, Annie L. Colebatch, Michael S. Hill, Claire L. McMullin, Mary F. Mahon, Catherine Weetman
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2017
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/e8659eb09b804bfb9bf50536728eb2fe
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:e8659eb09b804bfb9bf50536728eb2fe
record_format	dspace
spelling	oai:doaj.org-article:e8659eb09b804bfb9bf50536728eb2fe2021-12-02T15:38:36ZEasy access to nucleophilic boron through diborane to magnesium boryl metathesis10.1038/ncomms150222041-1723https://doaj.org/article/e8659eb09b804bfb9bf50536728eb2fe2017-04-01T00:00:00Zhttps://doi.org/10.1038/ncomms15022https://doaj.org/toc/2041-1723Organoboranes are widely employed in organic synthesis and typically are prepared using electrophilic boron sources. Here the authors report a route to nucleophilic boryl anions via organomagnesium-driven cleavage of boron-boron bonds.Anne-Frédérique PécharmanAnnie L. ColebatchMichael S. HillClaire L. McMullinMary F. MahonCatherine WeetmanNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-7 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Anne-Frédérique Pécharman Annie L. Colebatch Michael S. Hill Claire L. McMullin Mary F. Mahon Catherine Weetman Easy access to nucleophilic boron through diborane to magnesium boryl metathesis
description	Organoboranes are widely employed in organic synthesis and typically are prepared using electrophilic boron sources. Here the authors report a route to nucleophilic boryl anions via organomagnesium-driven cleavage of boron-boron bonds.
format	article
author	Anne-Frédérique Pécharman Annie L. Colebatch Michael S. Hill Claire L. McMullin Mary F. Mahon Catherine Weetman
author_facet	Anne-Frédérique Pécharman Annie L. Colebatch Michael S. Hill Claire L. McMullin Mary F. Mahon Catherine Weetman
author_sort	Anne-Frédérique Pécharman
title	Easy access to nucleophilic boron through diborane to magnesium boryl metathesis
title_short	Easy access to nucleophilic boron through diborane to magnesium boryl metathesis
title_full	Easy access to nucleophilic boron through diborane to magnesium boryl metathesis
title_fullStr	Easy access to nucleophilic boron through diborane to magnesium boryl metathesis
title_full_unstemmed	Easy access to nucleophilic boron through diborane to magnesium boryl metathesis
title_sort	easy access to nucleophilic boron through diborane to magnesium boryl metathesis
publisher	Nature Portfolio
publishDate	2017
url	https://doaj.org/article/e8659eb09b804bfb9bf50536728eb2fe
work_keys_str_mv	AT annefrederiquepecharman easyaccesstonucleophilicboronthroughdiboranetomagnesiumborylmetathesis AT annielcolebatch easyaccesstonucleophilicboronthroughdiboranetomagnesiumborylmetathesis AT michaelshill easyaccesstonucleophilicboronthroughdiboranetomagnesiumborylmetathesis AT clairelmcmullin easyaccesstonucleophilicboronthroughdiboranetomagnesiumborylmetathesis AT maryfmahon easyaccesstonucleophilicboronthroughdiboranetomagnesiumborylmetathesis AT catherineweetman easyaccesstonucleophilicboronthroughdiboranetomagnesiumborylmetathesis
_version_	1718386147058515968

Easy access to nucleophilic boron through diborane to magnesium boryl metathesis

Ejemplares similares