Multi-electron transfer enabled by topotactic reaction in magnetite
In contrast to the conventional wisdom on conversion-driven structural collapse of the host, this work shows that lithium conversion in magnetite resembles the intercalation process, going via topotactic reactions, thereby enabling multi-electron transfer and high reversible capacity.
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2019
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oai:doaj.org-article:e884783c5462419e890bfcc30439cfea2021-12-02T16:57:07ZMulti-electron transfer enabled by topotactic reaction in magnetite10.1038/s41467-019-09528-92041-1723https://doaj.org/article/e884783c5462419e890bfcc30439cfea2019-04-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-09528-9https://doaj.org/toc/2041-1723In contrast to the conventional wisdom on conversion-driven structural collapse of the host, this work shows that lithium conversion in magnetite resembles the intercalation process, going via topotactic reactions, thereby enabling multi-electron transfer and high reversible capacity.Wei ZhangYan LiLijun WuYandong DuanKim KisslingerChunlin ChenDavid C. BockFeng PanYimei ZhuAmy C. MarschilokEsther S. TakeuchiKenneth J. TakeuchiFeng WangNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-8 (2019) |
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Science Q Wei Zhang Yan Li Lijun Wu Yandong Duan Kim Kisslinger Chunlin Chen David C. Bock Feng Pan Yimei Zhu Amy C. Marschilok Esther S. Takeuchi Kenneth J. Takeuchi Feng Wang Multi-electron transfer enabled by topotactic reaction in magnetite |
description |
In contrast to the conventional wisdom on conversion-driven structural collapse of the host, this work shows that lithium conversion in magnetite resembles the intercalation process, going via topotactic reactions, thereby enabling multi-electron transfer and high reversible capacity. |
format |
article |
author |
Wei Zhang Yan Li Lijun Wu Yandong Duan Kim Kisslinger Chunlin Chen David C. Bock Feng Pan Yimei Zhu Amy C. Marschilok Esther S. Takeuchi Kenneth J. Takeuchi Feng Wang |
author_facet |
Wei Zhang Yan Li Lijun Wu Yandong Duan Kim Kisslinger Chunlin Chen David C. Bock Feng Pan Yimei Zhu Amy C. Marschilok Esther S. Takeuchi Kenneth J. Takeuchi Feng Wang |
author_sort |
Wei Zhang |
title |
Multi-electron transfer enabled by topotactic reaction in magnetite |
title_short |
Multi-electron transfer enabled by topotactic reaction in magnetite |
title_full |
Multi-electron transfer enabled by topotactic reaction in magnetite |
title_fullStr |
Multi-electron transfer enabled by topotactic reaction in magnetite |
title_full_unstemmed |
Multi-electron transfer enabled by topotactic reaction in magnetite |
title_sort |
multi-electron transfer enabled by topotactic reaction in magnetite |
publisher |
Nature Portfolio |
publishDate |
2019 |
url |
https://doaj.org/article/e884783c5462419e890bfcc30439cfea |
work_keys_str_mv |
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