A model for transient diffusion in bidisperse pore structures
Abstract A bidisperse model for transient diffusion and adsorption processes in porous materials is presented in this paper. The mathematical model is solved by numerical methods based on finite elements combined with the linear driving force approximation. A criterion based on the model to identify...
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KeAi Communications Co., Ltd.
2019
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oai:doaj.org-article:e896cd931c99410e90774435aa7143922021-12-02T10:17:02ZA model for transient diffusion in bidisperse pore structures10.1007/s12182-019-0338-21672-51071995-8226https://doaj.org/article/e896cd931c99410e90774435aa7143922019-06-01T00:00:00Zhttp://link.springer.com/article/10.1007/s12182-019-0338-2https://doaj.org/toc/1672-5107https://doaj.org/toc/1995-8226Abstract A bidisperse model for transient diffusion and adsorption processes in porous materials is presented in this paper. The mathematical model is solved by numerical methods based on finite elements combined with the linear driving force approximation. A criterion based on the model to identify the diffusion controlling mechanism (macropore diffusion, micropore diffusion, or both) is proposed. The effects of different adsorption isotherms (linear, Freundlich, or Langmuir) on the concentration profiles and on curves of fractional uptake versus time are investigated. In addition, the influences of model parameters concerning the pore networks on the fractional uptake are studied as well.Wei SunSheng-Li ChenMing-Ri XuYa-Qian WeiTing-Ting FanBao-Li MaJin-Tao GuoKeAi Communications Co., Ltd.articleTransient diffusionAdsorptionBidisperse poresMacroporeMicroporeLinear driving forceScienceQPetrologyQE420-499ENPetroleum Science, Vol 16, Iss 6, Pp 1455-1470 (2019) |
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Transient diffusion Adsorption Bidisperse pores Macropore Micropore Linear driving force Science Q Petrology QE420-499 |
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Transient diffusion Adsorption Bidisperse pores Macropore Micropore Linear driving force Science Q Petrology QE420-499 Wei Sun Sheng-Li Chen Ming-Ri Xu Ya-Qian Wei Ting-Ting Fan Bao-Li Ma Jin-Tao Guo A model for transient diffusion in bidisperse pore structures |
description |
Abstract A bidisperse model for transient diffusion and adsorption processes in porous materials is presented in this paper. The mathematical model is solved by numerical methods based on finite elements combined with the linear driving force approximation. A criterion based on the model to identify the diffusion controlling mechanism (macropore diffusion, micropore diffusion, or both) is proposed. The effects of different adsorption isotherms (linear, Freundlich, or Langmuir) on the concentration profiles and on curves of fractional uptake versus time are investigated. In addition, the influences of model parameters concerning the pore networks on the fractional uptake are studied as well. |
format |
article |
author |
Wei Sun Sheng-Li Chen Ming-Ri Xu Ya-Qian Wei Ting-Ting Fan Bao-Li Ma Jin-Tao Guo |
author_facet |
Wei Sun Sheng-Li Chen Ming-Ri Xu Ya-Qian Wei Ting-Ting Fan Bao-Li Ma Jin-Tao Guo |
author_sort |
Wei Sun |
title |
A model for transient diffusion in bidisperse pore structures |
title_short |
A model for transient diffusion in bidisperse pore structures |
title_full |
A model for transient diffusion in bidisperse pore structures |
title_fullStr |
A model for transient diffusion in bidisperse pore structures |
title_full_unstemmed |
A model for transient diffusion in bidisperse pore structures |
title_sort |
model for transient diffusion in bidisperse pore structures |
publisher |
KeAi Communications Co., Ltd. |
publishDate |
2019 |
url |
https://doaj.org/article/e896cd931c99410e90774435aa714392 |
work_keys_str_mv |
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1718397446537609216 |