Nitrophenol chemi-sensor and active solar photocatalyst based on spinel hetaerolite nanoparticles.

In this contribution, a significant catalyst based on spinel ZnMn2O4 composite nanoparticles has been developed for electro-catalysis of nitrophenol and photo-catalysis of brilliant cresyl blue. ZnMn2O4 composite (hetaerolite) nanoparticles were prepared by easy low temperature hydrothermal procedur...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Sher Bahadar Khan, Mohammed M Rahman, Kalsoom Akhtar, Abdullah M Asiri, Malik Abdul Rub
Formato:	article
Lenguaje:	EN
Publicado:	Public Library of Science (PLoS) 2014
Materias:	Medicine R Science Q
Acceso en línea:	https://doaj.org/article/e8bf0acb89204017ae24d8a5e4c28b73
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:e8bf0acb89204017ae24d8a5e4c28b73
record_format	dspace
spelling	oai:doaj.org-article:e8bf0acb89204017ae24d8a5e4c28b732021-11-18T08:37:04ZNitrophenol chemi-sensor and active solar photocatalyst based on spinel hetaerolite nanoparticles.1932-620310.1371/journal.pone.0085290https://doaj.org/article/e8bf0acb89204017ae24d8a5e4c28b732014-01-01T00:00:00Zhttps://www.ncbi.nlm.nih.gov/pmc/articles/pmid/24465525/?tool=EBIhttps://doaj.org/toc/1932-6203In this contribution, a significant catalyst based on spinel ZnMn2O4 composite nanoparticles has been developed for electro-catalysis of nitrophenol and photo-catalysis of brilliant cresyl blue. ZnMn2O4 composite (hetaerolite) nanoparticles were prepared by easy low temperature hydrothermal procedure and structurally characterized by X-ray powder diffraction (XRD), field emission scanning electron microscopy (FESEM), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared (FTIR) and UV-visible spectroscopy which illustrate that the prepared material is optical active and composed of well crystalline body-centered tetragonal nanoparticles with average size of ∼ 38 ± 10 nm. Hetaerolite nanoparticles were applied for the advancement of a nitrophenol sensor which exhibited high sensitivity (1.500 µAcm(-2) mM(-1)), stability, repeatability and lower limit of detection (20.0 µM) in short response time (10 sec). Moreover, hetaerolite nanoparticles executed high solar photo-catalytic degradation when applied to brilliant cresyl blue under visible light.Sher Bahadar KhanMohammed M RahmanKalsoom AkhtarAbdullah M AsiriMalik Abdul RubPublic Library of Science (PLoS)articleMedicineRScienceQENPLoS ONE, Vol 9, Iss 1, p e85290 (2014)
institution	DOAJ
collection	DOAJ
language	EN
topic	Medicine R Science Q
spellingShingle	Medicine R Science Q Sher Bahadar Khan Mohammed M Rahman Kalsoom Akhtar Abdullah M Asiri Malik Abdul Rub Nitrophenol chemi-sensor and active solar photocatalyst based on spinel hetaerolite nanoparticles.
description	In this contribution, a significant catalyst based on spinel ZnMn2O4 composite nanoparticles has been developed for electro-catalysis of nitrophenol and photo-catalysis of brilliant cresyl blue. ZnMn2O4 composite (hetaerolite) nanoparticles were prepared by easy low temperature hydrothermal procedure and structurally characterized by X-ray powder diffraction (XRD), field emission scanning electron microscopy (FESEM), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared (FTIR) and UV-visible spectroscopy which illustrate that the prepared material is optical active and composed of well crystalline body-centered tetragonal nanoparticles with average size of ∼ 38 ± 10 nm. Hetaerolite nanoparticles were applied for the advancement of a nitrophenol sensor which exhibited high sensitivity (1.500 µAcm(-2) mM(-1)), stability, repeatability and lower limit of detection (20.0 µM) in short response time (10 sec). Moreover, hetaerolite nanoparticles executed high solar photo-catalytic degradation when applied to brilliant cresyl blue under visible light.
format	article
author	Sher Bahadar Khan Mohammed M Rahman Kalsoom Akhtar Abdullah M Asiri Malik Abdul Rub
author_facet	Sher Bahadar Khan Mohammed M Rahman Kalsoom Akhtar Abdullah M Asiri Malik Abdul Rub
author_sort	Sher Bahadar Khan
title	Nitrophenol chemi-sensor and active solar photocatalyst based on spinel hetaerolite nanoparticles.
title_short	Nitrophenol chemi-sensor and active solar photocatalyst based on spinel hetaerolite nanoparticles.
title_full	Nitrophenol chemi-sensor and active solar photocatalyst based on spinel hetaerolite nanoparticles.
title_fullStr	Nitrophenol chemi-sensor and active solar photocatalyst based on spinel hetaerolite nanoparticles.
title_full_unstemmed	Nitrophenol chemi-sensor and active solar photocatalyst based on spinel hetaerolite nanoparticles.
title_sort	nitrophenol chemi-sensor and active solar photocatalyst based on spinel hetaerolite nanoparticles.
publisher	Public Library of Science (PLoS)
publishDate	2014
url	https://doaj.org/article/e8bf0acb89204017ae24d8a5e4c28b73
work_keys_str_mv	AT sherbahadarkhan nitrophenolchemisensorandactivesolarphotocatalystbasedonspinelhetaerolitenanoparticles AT mohammedmrahman nitrophenolchemisensorandactivesolarphotocatalystbasedonspinelhetaerolitenanoparticles AT kalsoomakhtar nitrophenolchemisensorandactivesolarphotocatalystbasedonspinelhetaerolitenanoparticles AT abdullahmasiri nitrophenolchemisensorandactivesolarphotocatalystbasedonspinelhetaerolitenanoparticles AT malikabdulrub nitrophenolchemisensorandactivesolarphotocatalystbasedonspinelhetaerolitenanoparticles
_version_	1718421594838138880

Nitrophenol chemi-sensor and active solar photocatalyst based on spinel hetaerolite nanoparticles.

Ejemplares similares