Dihydroxyacetone valorization with high atom efficiency via controlling radical oxidation pathways over natural mineral-inspired catalyst

Radicals-mediated Fenton chemistry has the potential for biomass valorization. Here, inspired from the natural goethite mineral, the authors develop a MnO2/goethite catalyst showing excellent yields of glycolic acid and formic acid from dihydroxyacetone, an important biomass-based platform molecule.

Guardado en:

Detalles Bibliográficos
Autores principales:	Jinling Wang, Xingchao Dai, Hualin Wang, Honglai Liu, Jabor Rabeah, Angelika Brückner, Feng Shi, Ming Gong, Xuejing Yang
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/e8d2684a54d64b22a4f32e63a70cacd8
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:e8d2684a54d64b22a4f32e63a70cacd8
record_format	dspace
spelling	oai:doaj.org-article:e8d2684a54d64b22a4f32e63a70cacd82021-11-28T12:34:53ZDihydroxyacetone valorization with high atom efficiency via controlling radical oxidation pathways over natural mineral-inspired catalyst10.1038/s41467-021-27240-52041-1723https://doaj.org/article/e8d2684a54d64b22a4f32e63a70cacd82021-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-27240-5https://doaj.org/toc/2041-1723Radicals-mediated Fenton chemistry has the potential for biomass valorization. Here, inspired from the natural goethite mineral, the authors develop a MnO2/goethite catalyst showing excellent yields of glycolic acid and formic acid from dihydroxyacetone, an important biomass-based platform molecule.Jinling WangXingchao DaiHualin WangHonglai LiuJabor RabeahAngelika BrücknerFeng ShiMing GongXuejing YangNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-11 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Jinling Wang Xingchao Dai Hualin Wang Honglai Liu Jabor Rabeah Angelika Brückner Feng Shi Ming Gong Xuejing Yang Dihydroxyacetone valorization with high atom efficiency via controlling radical oxidation pathways over natural mineral-inspired catalyst
description	Radicals-mediated Fenton chemistry has the potential for biomass valorization. Here, inspired from the natural goethite mineral, the authors develop a MnO2/goethite catalyst showing excellent yields of glycolic acid and formic acid from dihydroxyacetone, an important biomass-based platform molecule.
format	article
author	Jinling Wang Xingchao Dai Hualin Wang Honglai Liu Jabor Rabeah Angelika Brückner Feng Shi Ming Gong Xuejing Yang
author_facet	Jinling Wang Xingchao Dai Hualin Wang Honglai Liu Jabor Rabeah Angelika Brückner Feng Shi Ming Gong Xuejing Yang
author_sort	Jinling Wang
title	Dihydroxyacetone valorization with high atom efficiency via controlling radical oxidation pathways over natural mineral-inspired catalyst
title_short	Dihydroxyacetone valorization with high atom efficiency via controlling radical oxidation pathways over natural mineral-inspired catalyst
title_full	Dihydroxyacetone valorization with high atom efficiency via controlling radical oxidation pathways over natural mineral-inspired catalyst
title_fullStr	Dihydroxyacetone valorization with high atom efficiency via controlling radical oxidation pathways over natural mineral-inspired catalyst
title_full_unstemmed	Dihydroxyacetone valorization with high atom efficiency via controlling radical oxidation pathways over natural mineral-inspired catalyst
title_sort	dihydroxyacetone valorization with high atom efficiency via controlling radical oxidation pathways over natural mineral-inspired catalyst
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/e8d2684a54d64b22a4f32e63a70cacd8
work_keys_str_mv	AT jinlingwang dihydroxyacetonevalorizationwithhighatomefficiencyviacontrollingradicaloxidationpathwaysovernaturalmineralinspiredcatalyst AT xingchaodai dihydroxyacetonevalorizationwithhighatomefficiencyviacontrollingradicaloxidationpathwaysovernaturalmineralinspiredcatalyst AT hualinwang dihydroxyacetonevalorizationwithhighatomefficiencyviacontrollingradicaloxidationpathwaysovernaturalmineralinspiredcatalyst AT honglailiu dihydroxyacetonevalorizationwithhighatomefficiencyviacontrollingradicaloxidationpathwaysovernaturalmineralinspiredcatalyst AT jaborrabeah dihydroxyacetonevalorizationwithhighatomefficiencyviacontrollingradicaloxidationpathwaysovernaturalmineralinspiredcatalyst AT angelikabruckner dihydroxyacetonevalorizationwithhighatomefficiencyviacontrollingradicaloxidationpathwaysovernaturalmineralinspiredcatalyst AT fengshi dihydroxyacetonevalorizationwithhighatomefficiencyviacontrollingradicaloxidationpathwaysovernaturalmineralinspiredcatalyst AT minggong dihydroxyacetonevalorizationwithhighatomefficiencyviacontrollingradicaloxidationpathwaysovernaturalmineralinspiredcatalyst AT xuejingyang dihydroxyacetonevalorizationwithhighatomefficiencyviacontrollingradicaloxidationpathwaysovernaturalmineralinspiredcatalyst
_version_	1718407927415439360

Dihydroxyacetone valorization with high atom efficiency via controlling radical oxidation pathways over natural mineral-inspired catalyst

Ejemplares similares