Bimetallic Oxyhydroxide as a High-Performance Water Oxidation Electrocatalyst under Industry-Relevant Conditions
Developing high-performing oxygen evolution reaction (OER) electrocatalysts under high-current operation conditions is critical for future commercial applications of alkaline water electrolysis for clean energy generation. Herein, we prepared a three-dimensional (3D) bimetallic oxyhydroxide hybrid g...
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| Autores principales: | , , , , , , , , , |
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| Formato: | article |
| Lenguaje: | EN |
| Publicado: |
Elsevier
2021
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| Materias: | |
| Acceso en línea: | https://doaj.org/article/e8fe0cde96e54db086ff9ef3b40ced1b |
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| Sumario: | Developing high-performing oxygen evolution reaction (OER) electrocatalysts under high-current operation conditions is critical for future commercial applications of alkaline water electrolysis for clean energy generation. Herein, we prepared a three-dimensional (3D) bimetallic oxyhydroxide hybrid grown on a Ni foam (NiFeOOH/NF) prepared by immersing Ni foam (NF) into Fe(NO3)3 solution. In this unique 3D structure, the NiFeOOH/NF hybrid was composed of crystalline Ni(OH)2 and amorphous FeOOH evenly grown on the NF surface. As a bimetallic oxyhydroxide electrocatalyst, the NiFeOOH/NF hybrid exhibited excellent catalytic activity, surpassing not only the other reported Ni–Fe based electrocatalysts, but also the commercial Ir/C catalyst. In situ electrochemical Raman spectroscopy demonstrated the active FeOOH and NiOOH phases involved in the OER process. Profiting from the synergy of Fe and Ni catalytic sites, the NiFeOOH/NF hybrid delivered an outstanding OER performance under challenging industrial conditions in a 10.0 mol∙L−1 KOH electrolyte at 80 °C, requiring potentials as small as 1.47 and 1.51 V to achieve the super-high catalytic current densities of 100 and 500 mA∙cm−2, respectively. |
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