Dynamic chiral self-recognition in aromatic dimers of styrene oxide revealed by rotational spectroscopy

Chiral molecular recognition is critical in many natural processes, but probing the conformational landscape of chiral aromatic systems can be challenging. Here, high-resolution broadband rotational spectroscopy data is combined with quantum chemical computations to reveal the dynamic self-pairing t...

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Autores principales: Sérgio R. Domingos, Cristóbal Pérez, Nora M. Kreienborg, Christian Merten, Melanie Schnell
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/e913320618b24481a17762823cbd43bf
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Sumario:Chiral molecular recognition is critical in many natural processes, but probing the conformational landscape of chiral aromatic systems can be challenging. Here, high-resolution broadband rotational spectroscopy data is combined with quantum chemical computations to reveal the dynamic self-pairing topologies of the chiral molecule styrene oxide.