Dynamic chiral self-recognition in aromatic dimers of styrene oxide revealed by rotational spectroscopy

Chiral molecular recognition is critical in many natural processes, but probing the conformational landscape of chiral aromatic systems can be challenging. Here, high-resolution broadband rotational spectroscopy data is combined with quantum chemical computations to reveal the dynamic self-pairing t...

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Autores principales:	Sérgio R. Domingos, Cristóbal Pérez, Nora M. Kreienborg, Christian Merten, Melanie Schnell
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/e913320618b24481a17762823cbd43bf
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spelling	oai:doaj.org-article:e913320618b24481a17762823cbd43bf2021-12-02T16:27:09ZDynamic chiral self-recognition in aromatic dimers of styrene oxide revealed by rotational spectroscopy10.1038/s42004-021-00468-42399-3669https://doaj.org/article/e913320618b24481a17762823cbd43bf2021-03-01T00:00:00Zhttps://doi.org/10.1038/s42004-021-00468-4https://doaj.org/toc/2399-3669Chiral molecular recognition is critical in many natural processes, but probing the conformational landscape of chiral aromatic systems can be challenging. Here, high-resolution broadband rotational spectroscopy data is combined with quantum chemical computations to reveal the dynamic self-pairing topologies of the chiral molecule styrene oxide.Sérgio R. DomingosCristóbal PérezNora M. KreienborgChristian MertenMelanie SchnellNature PortfolioarticleChemistryQD1-999ENCommunications Chemistry, Vol 4, Iss 1, Pp 1-11 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Chemistry QD1-999
spellingShingle	Chemistry QD1-999 Sérgio R. Domingos Cristóbal Pérez Nora M. Kreienborg Christian Merten Melanie Schnell Dynamic chiral self-recognition in aromatic dimers of styrene oxide revealed by rotational spectroscopy
description	Chiral molecular recognition is critical in many natural processes, but probing the conformational landscape of chiral aromatic systems can be challenging. Here, high-resolution broadband rotational spectroscopy data is combined with quantum chemical computations to reveal the dynamic self-pairing topologies of the chiral molecule styrene oxide.
format	article
author	Sérgio R. Domingos Cristóbal Pérez Nora M. Kreienborg Christian Merten Melanie Schnell
author_facet	Sérgio R. Domingos Cristóbal Pérez Nora M. Kreienborg Christian Merten Melanie Schnell
author_sort	Sérgio R. Domingos
title	Dynamic chiral self-recognition in aromatic dimers of styrene oxide revealed by rotational spectroscopy
title_short	Dynamic chiral self-recognition in aromatic dimers of styrene oxide revealed by rotational spectroscopy
title_full	Dynamic chiral self-recognition in aromatic dimers of styrene oxide revealed by rotational spectroscopy
title_fullStr	Dynamic chiral self-recognition in aromatic dimers of styrene oxide revealed by rotational spectroscopy
title_full_unstemmed	Dynamic chiral self-recognition in aromatic dimers of styrene oxide revealed by rotational spectroscopy
title_sort	dynamic chiral self-recognition in aromatic dimers of styrene oxide revealed by rotational spectroscopy
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/e913320618b24481a17762823cbd43bf
work_keys_str_mv	AT sergiordomingos dynamicchiralselfrecognitioninaromaticdimersofstyreneoxiderevealedbyrotationalspectroscopy AT cristobalperez dynamicchiralselfrecognitioninaromaticdimersofstyreneoxiderevealedbyrotationalspectroscopy AT noramkreienborg dynamicchiralselfrecognitioninaromaticdimersofstyreneoxiderevealedbyrotationalspectroscopy AT christianmerten dynamicchiralselfrecognitioninaromaticdimersofstyreneoxiderevealedbyrotationalspectroscopy AT melanieschnell dynamicchiralselfrecognitioninaromaticdimersofstyreneoxiderevealedbyrotationalspectroscopy
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Dynamic chiral self-recognition in aromatic dimers of styrene oxide revealed by rotational spectroscopy

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