Penta- and hexa-coordinated beryllium and phosphorus in high-pressure modifications of CaBe2P2O8
Beryllium in inorganic compounds is usually coordinated to four oxygen atoms, but higher coordination numbers have been predicted. Here the authors observe a pressure induced stepwise transition in CaBe2P2O8 where Be coordination changes to trigonal-bipyramidal and octahedral, implying that d orbita...
Guardado en:
| Autores principales: | , , , , , , , |
|---|---|
| Formato: | article |
| Lenguaje: | EN |
| Publicado: |
Nature Portfolio
2019
|
| Materias: | |
| Acceso en línea: | https://doaj.org/article/eab6ecc8106342fb9c1ab4241dec374d |
| Etiquetas: |
Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
|
| Sumario: | Beryllium in inorganic compounds is usually coordinated to four oxygen atoms, but higher coordination numbers have been predicted. Here the authors observe a pressure induced stepwise transition in CaBe2P2O8 where Be coordination changes to trigonal-bipyramidal and octahedral, implying that d orbitals are not mandatory for high coordination. |
|---|