Penta- and hexa-coordinated beryllium and phosphorus in high-pressure modifications of CaBe2P2O8

Beryllium in inorganic compounds is usually coordinated to four oxygen atoms, but higher coordination numbers have been predicted. Here the authors observe a pressure induced stepwise transition in CaBe2P2O8 where Be coordination changes to trigonal-bipyramidal and octahedral, implying that d orbita...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Anna Pakhomova, Georgios Aprilis, Maxim Bykov, Liudmila Gorelova, Sergey S. Krivovichev, Maxim P. Belov, Igor A. Abrikosov, Leonid Dubrovinsky
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/eab6ecc8106342fb9c1ab4241dec374d
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:eab6ecc8106342fb9c1ab4241dec374d
record_format	dspace
spelling	oai:doaj.org-article:eab6ecc8106342fb9c1ab4241dec374d2021-12-02T15:35:40ZPenta- and hexa-coordinated beryllium and phosphorus in high-pressure modifications of CaBe2P2O810.1038/s41467-019-10589-z2041-1723https://doaj.org/article/eab6ecc8106342fb9c1ab4241dec374d2019-06-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-10589-zhttps://doaj.org/toc/2041-1723Beryllium in inorganic compounds is usually coordinated to four oxygen atoms, but higher coordination numbers have been predicted. Here the authors observe a pressure induced stepwise transition in CaBe2P2O8 where Be coordination changes to trigonal-bipyramidal and octahedral, implying that d orbitals are not mandatory for high coordination.Anna PakhomovaGeorgios AprilisMaxim BykovLiudmila GorelovaSergey S. KrivovichevMaxim P. BelovIgor A. AbrikosovLeonid DubrovinskyNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-6 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Anna Pakhomova Georgios Aprilis Maxim Bykov Liudmila Gorelova Sergey S. Krivovichev Maxim P. Belov Igor A. Abrikosov Leonid Dubrovinsky Penta- and hexa-coordinated beryllium and phosphorus in high-pressure modifications of CaBe2P2O8
description	Beryllium in inorganic compounds is usually coordinated to four oxygen atoms, but higher coordination numbers have been predicted. Here the authors observe a pressure induced stepwise transition in CaBe2P2O8 where Be coordination changes to trigonal-bipyramidal and octahedral, implying that d orbitals are not mandatory for high coordination.
format	article
author	Anna Pakhomova Georgios Aprilis Maxim Bykov Liudmila Gorelova Sergey S. Krivovichev Maxim P. Belov Igor A. Abrikosov Leonid Dubrovinsky
author_facet	Anna Pakhomova Georgios Aprilis Maxim Bykov Liudmila Gorelova Sergey S. Krivovichev Maxim P. Belov Igor A. Abrikosov Leonid Dubrovinsky
author_sort	Anna Pakhomova
title	Penta- and hexa-coordinated beryllium and phosphorus in high-pressure modifications of CaBe2P2O8
title_short	Penta- and hexa-coordinated beryllium and phosphorus in high-pressure modifications of CaBe2P2O8
title_full	Penta- and hexa-coordinated beryllium and phosphorus in high-pressure modifications of CaBe2P2O8
title_fullStr	Penta- and hexa-coordinated beryllium and phosphorus in high-pressure modifications of CaBe2P2O8
title_full_unstemmed	Penta- and hexa-coordinated beryllium and phosphorus in high-pressure modifications of CaBe2P2O8
title_sort	penta- and hexa-coordinated beryllium and phosphorus in high-pressure modifications of cabe2p2o8
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/eab6ecc8106342fb9c1ab4241dec374d
work_keys_str_mv	AT annapakhomova pentaandhexacoordinatedberylliumandphosphorusinhighpressuremodificationsofcabe2p2o8 AT georgiosaprilis pentaandhexacoordinatedberylliumandphosphorusinhighpressuremodificationsofcabe2p2o8 AT maximbykov pentaandhexacoordinatedberylliumandphosphorusinhighpressuremodificationsofcabe2p2o8 AT liudmilagorelova pentaandhexacoordinatedberylliumandphosphorusinhighpressuremodificationsofcabe2p2o8 AT sergeyskrivovichev pentaandhexacoordinatedberylliumandphosphorusinhighpressuremodificationsofcabe2p2o8 AT maximpbelov pentaandhexacoordinatedberylliumandphosphorusinhighpressuremodificationsofcabe2p2o8 AT igoraabrikosov pentaandhexacoordinatedberylliumandphosphorusinhighpressuremodificationsofcabe2p2o8 AT leoniddubrovinsky pentaandhexacoordinatedberylliumandphosphorusinhighpressuremodificationsofcabe2p2o8
_version_	1718386508291899392

Penta- and hexa-coordinated beryllium and phosphorus in high-pressure modifications of CaBe2P2O8

Ejemplares similares