Chromatographic Applications in the Multi-Way Calibration Field

In this review, recent advances and applications using multi-way calibration protocols based on the processing of multi-dimensional chromatographic data are discussed. We first describe the various modes in which multi-way chromatographic data sets can be generated, including some important characte...

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Autores principales:	Fabricio A. Chiappini, Mirta R. Alcaraz, Graciela M. Escandar, Héctor C. Goicoechea, Alejandro C. Olivieri
Formato:	article
Lenguaje:	EN
Publicado:	MDPI AG 2021
Materias:	liquid and gas chromatography multi-way chromatographic data generation multi-way models and calibration analytical figures of merit Organic chemistry QD241-441
Acceso en línea:	https://doaj.org/article/eb2bb2f954ff4ee38e2b507148b31abb
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id	oai:doaj.org-article:eb2bb2f954ff4ee38e2b507148b31abb
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spelling	oai:doaj.org-article:eb2bb2f954ff4ee38e2b507148b31abb2021-11-11T18:23:10ZChromatographic Applications in the Multi-Way Calibration Field10.3390/molecules262163571420-3049https://doaj.org/article/eb2bb2f954ff4ee38e2b507148b31abb2021-10-01T00:00:00Zhttps://www.mdpi.com/1420-3049/26/21/6357https://doaj.org/toc/1420-3049In this review, recent advances and applications using multi-way calibration protocols based on the processing of multi-dimensional chromatographic data are discussed. We first describe the various modes in which multi-way chromatographic data sets can be generated, including some important characteristics that should be taken into account for the selection of an adequate data processing model. We then discuss the different manners in which the collected instrumental data can be arranged, and the most usually applied models and algorithms for the decomposition of the data arrays. The latter activity leads to the estimation of surrogate variables (scores), useful for analyte quantitation in the presence of uncalibrated interferences, achieving the second-order advantage. Recent experimental reports based on multi-way liquid and gas chromatographic data are then reviewed. Finally, analytical figures of merit that should always accompany quantitative calibration reports are described.Fabricio A. ChiappiniMirta R. AlcarazGraciela M. EscandarHéctor C. GoicoecheaAlejandro C. OlivieriMDPI AGarticleliquid and gas chromatographymulti-way chromatographic data generationmulti-way models and calibrationanalytical figures of meritOrganic chemistryQD241-441ENMolecules, Vol 26, Iss 6357, p 6357 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	liquid and gas chromatography multi-way chromatographic data generation multi-way models and calibration analytical figures of merit Organic chemistry QD241-441
spellingShingle	liquid and gas chromatography multi-way chromatographic data generation multi-way models and calibration analytical figures of merit Organic chemistry QD241-441 Fabricio A. Chiappini Mirta R. Alcaraz Graciela M. Escandar Héctor C. Goicoechea Alejandro C. Olivieri Chromatographic Applications in the Multi-Way Calibration Field
description	In this review, recent advances and applications using multi-way calibration protocols based on the processing of multi-dimensional chromatographic data are discussed. We first describe the various modes in which multi-way chromatographic data sets can be generated, including some important characteristics that should be taken into account for the selection of an adequate data processing model. We then discuss the different manners in which the collected instrumental data can be arranged, and the most usually applied models and algorithms for the decomposition of the data arrays. The latter activity leads to the estimation of surrogate variables (scores), useful for analyte quantitation in the presence of uncalibrated interferences, achieving the second-order advantage. Recent experimental reports based on multi-way liquid and gas chromatographic data are then reviewed. Finally, analytical figures of merit that should always accompany quantitative calibration reports are described.
format	article
author	Fabricio A. Chiappini Mirta R. Alcaraz Graciela M. Escandar Héctor C. Goicoechea Alejandro C. Olivieri
author_facet	Fabricio A. Chiappini Mirta R. Alcaraz Graciela M. Escandar Héctor C. Goicoechea Alejandro C. Olivieri
author_sort	Fabricio A. Chiappini
title	Chromatographic Applications in the Multi-Way Calibration Field
title_short	Chromatographic Applications in the Multi-Way Calibration Field
title_full	Chromatographic Applications in the Multi-Way Calibration Field
title_fullStr	Chromatographic Applications in the Multi-Way Calibration Field
title_full_unstemmed	Chromatographic Applications in the Multi-Way Calibration Field
title_sort	chromatographic applications in the multi-way calibration field
publisher	MDPI AG
publishDate	2021
url	https://doaj.org/article/eb2bb2f954ff4ee38e2b507148b31abb
work_keys_str_mv	AT fabricioachiappini chromatographicapplicationsinthemultiwaycalibrationfield AT mirtaralcaraz chromatographicapplicationsinthemultiwaycalibrationfield AT gracielamescandar chromatographicapplicationsinthemultiwaycalibrationfield AT hectorcgoicoechea chromatographicapplicationsinthemultiwaycalibrationfield AT alejandrocolivieri chromatographicapplicationsinthemultiwaycalibrationfield
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Chromatographic Applications in the Multi-Way Calibration Field

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