A cross-dehydrogenative C(sp 3)−H heteroarylation via photo-induced catalytic chlorine radical generation

Hydrogen atom abstraction from C(sp 3)–H bonds of naturally abundant alkanes for alkyl radical generation represents a promising yet underexplored strategy in the alkylation reaction designs. Here the authors show a photo-induced and chemical oxidant-free cross-dehydrogenative coupling between alkan...

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Autores principales:	Chia-Yu Huang, Jianbin Li, Chao-Jun Li
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/eb47f53ada0848bc969084baeda50ac7
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spelling	oai:doaj.org-article:eb47f53ada0848bc969084baeda50ac72021-12-02T14:34:12ZA cross-dehydrogenative C(sp 3)−H heteroarylation via photo-induced catalytic chlorine radical generation10.1038/s41467-021-24280-92041-1723https://doaj.org/article/eb47f53ada0848bc969084baeda50ac72021-06-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-24280-9https://doaj.org/toc/2041-1723Hydrogen atom abstraction from C(sp 3)–H bonds of naturally abundant alkanes for alkyl radical generation represents a promising yet underexplored strategy in the alkylation reaction designs. Here the authors show a photo-induced and chemical oxidant-free cross-dehydrogenative coupling between alkanes and heteroarenes using catalytic chloride and cobalt catalyst.Chia-Yu HuangJianbin LiChao-Jun LiNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-9 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Chia-Yu Huang Jianbin Li Chao-Jun Li A cross-dehydrogenative C(sp 3)−H heteroarylation via photo-induced catalytic chlorine radical generation
description	Hydrogen atom abstraction from C(sp 3)–H bonds of naturally abundant alkanes for alkyl radical generation represents a promising yet underexplored strategy in the alkylation reaction designs. Here the authors show a photo-induced and chemical oxidant-free cross-dehydrogenative coupling between alkanes and heteroarenes using catalytic chloride and cobalt catalyst.
format	article
author	Chia-Yu Huang Jianbin Li Chao-Jun Li
author_facet	Chia-Yu Huang Jianbin Li Chao-Jun Li
author_sort	Chia-Yu Huang
title	A cross-dehydrogenative C(sp 3)−H heteroarylation via photo-induced catalytic chlorine radical generation
title_short	A cross-dehydrogenative C(sp 3)−H heteroarylation via photo-induced catalytic chlorine radical generation
title_full	A cross-dehydrogenative C(sp 3)−H heteroarylation via photo-induced catalytic chlorine radical generation
title_fullStr	A cross-dehydrogenative C(sp 3)−H heteroarylation via photo-induced catalytic chlorine radical generation
title_full_unstemmed	A cross-dehydrogenative C(sp 3)−H heteroarylation via photo-induced catalytic chlorine radical generation
title_sort	cross-dehydrogenative c(sp 3)−h heteroarylation via photo-induced catalytic chlorine radical generation
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/eb47f53ada0848bc969084baeda50ac7
work_keys_str_mv	AT chiayuhuang acrossdehydrogenativecsp3hheteroarylationviaphotoinducedcatalyticchlorineradicalgeneration AT jianbinli acrossdehydrogenativecsp3hheteroarylationviaphotoinducedcatalyticchlorineradicalgeneration AT chaojunli acrossdehydrogenativecsp3hheteroarylationviaphotoinducedcatalyticchlorineradicalgeneration AT chiayuhuang crossdehydrogenativecsp3hheteroarylationviaphotoinducedcatalyticchlorineradicalgeneration AT jianbinli crossdehydrogenativecsp3hheteroarylationviaphotoinducedcatalyticchlorineradicalgeneration AT chaojunli crossdehydrogenativecsp3hheteroarylationviaphotoinducedcatalyticchlorineradicalgeneration
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A cross-dehydrogenative C(sp 3)−H heteroarylation via photo-induced catalytic chlorine radical generation

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