Cramming versus threading of long amphiphilic oligomers into a polyaromatic capsule

Molecular capsules typically bind only guests with volumes smaller than their cavities. Here, the authors find that a polyaromatic capsule accommodates linear amphiphilic oligomers in a length-dependent manner, whereas short chains are fully crammed into the cavity, long chains can be incorporated i...

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Autores principales: Masahiro Yamashina, Shunsuke Kusaba, Munetaka Akita, Takashi Kikuchi, Michito Yoshizawa
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2018
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Acceso en línea:https://doaj.org/article/eb4f71d171d7423c8d2111cb2ab809e4
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spelling oai:doaj.org-article:eb4f71d171d7423c8d2111cb2ab809e42021-12-02T15:34:07ZCramming versus threading of long amphiphilic oligomers into a polyaromatic capsule10.1038/s41467-018-06458-w2041-1723https://doaj.org/article/eb4f71d171d7423c8d2111cb2ab809e42018-10-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-06458-whttps://doaj.org/toc/2041-1723Molecular capsules typically bind only guests with volumes smaller than their cavities. Here, the authors find that a polyaromatic capsule accommodates linear amphiphilic oligomers in a length-dependent manner, whereas short chains are fully crammed into the cavity, long chains can be incorporated into the capsule in a threaded fashion.Masahiro YamashinaShunsuke KusabaMunetaka AkitaTakashi KikuchiMichito YoshizawaNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-10 (2018)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Masahiro Yamashina
Shunsuke Kusaba
Munetaka Akita
Takashi Kikuchi
Michito Yoshizawa
Cramming versus threading of long amphiphilic oligomers into a polyaromatic capsule
description Molecular capsules typically bind only guests with volumes smaller than their cavities. Here, the authors find that a polyaromatic capsule accommodates linear amphiphilic oligomers in a length-dependent manner, whereas short chains are fully crammed into the cavity, long chains can be incorporated into the capsule in a threaded fashion.
format article
author Masahiro Yamashina
Shunsuke Kusaba
Munetaka Akita
Takashi Kikuchi
Michito Yoshizawa
author_facet Masahiro Yamashina
Shunsuke Kusaba
Munetaka Akita
Takashi Kikuchi
Michito Yoshizawa
author_sort Masahiro Yamashina
title Cramming versus threading of long amphiphilic oligomers into a polyaromatic capsule
title_short Cramming versus threading of long amphiphilic oligomers into a polyaromatic capsule
title_full Cramming versus threading of long amphiphilic oligomers into a polyaromatic capsule
title_fullStr Cramming versus threading of long amphiphilic oligomers into a polyaromatic capsule
title_full_unstemmed Cramming versus threading of long amphiphilic oligomers into a polyaromatic capsule
title_sort cramming versus threading of long amphiphilic oligomers into a polyaromatic capsule
publisher Nature Portfolio
publishDate 2018
url https://doaj.org/article/eb4f71d171d7423c8d2111cb2ab809e4
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AT munetakaakita crammingversusthreadingoflongamphiphilicoligomersintoapolyaromaticcapsule
AT takashikikuchi crammingversusthreadingoflongamphiphilicoligomersintoapolyaromaticcapsule
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