Blocking-cyclization technique for precise synthesis of cyclic polymers with regulated topology

Cyclic polymers can be usually accessed by ring-expansion and ring-closure approaches. Here, the authors report an alternative blocking-cyclization technique which enables the tunable synthesis of multicyclic polymers via commercial Ru-based Grubbs catalysts and conventional ring-opening metathesis...

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Autores principales:	Jie Chen, Hongfei Li, Hengchen Zhang, Xiaojuan Liao, Huijing Han, Lidong Zhang, Ruyi Sun, Meiran Xie
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/eb5b2a4b90b347999c0bf9cf1b9b1cc4
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spelling	oai:doaj.org-article:eb5b2a4b90b347999c0bf9cf1b9b1cc42021-12-02T14:38:51ZBlocking-cyclization technique for precise synthesis of cyclic polymers with regulated topology10.1038/s41467-018-07754-12041-1723https://doaj.org/article/eb5b2a4b90b347999c0bf9cf1b9b1cc42018-12-01T00:00:00Zhttps://doi.org/10.1038/s41467-018-07754-1https://doaj.org/toc/2041-1723Cyclic polymers can be usually accessed by ring-expansion and ring-closure approaches. Here, the authors report an alternative blocking-cyclization technique which enables the tunable synthesis of multicyclic polymers via commercial Ru-based Grubbs catalysts and conventional ring-opening metathesis polymerisation.Jie ChenHongfei LiHengchen ZhangXiaojuan LiaoHuijing HanLidong ZhangRuyi SunMeiran XieNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-9 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Jie Chen Hongfei Li Hengchen Zhang Xiaojuan Liao Huijing Han Lidong Zhang Ruyi Sun Meiran Xie Blocking-cyclization technique for precise synthesis of cyclic polymers with regulated topology
description	Cyclic polymers can be usually accessed by ring-expansion and ring-closure approaches. Here, the authors report an alternative blocking-cyclization technique which enables the tunable synthesis of multicyclic polymers via commercial Ru-based Grubbs catalysts and conventional ring-opening metathesis polymerisation.
format	article
author	Jie Chen Hongfei Li Hengchen Zhang Xiaojuan Liao Huijing Han Lidong Zhang Ruyi Sun Meiran Xie
author_facet	Jie Chen Hongfei Li Hengchen Zhang Xiaojuan Liao Huijing Han Lidong Zhang Ruyi Sun Meiran Xie
author_sort	Jie Chen
title	Blocking-cyclization technique for precise synthesis of cyclic polymers with regulated topology
title_short	Blocking-cyclization technique for precise synthesis of cyclic polymers with regulated topology
title_full	Blocking-cyclization technique for precise synthesis of cyclic polymers with regulated topology
title_fullStr	Blocking-cyclization technique for precise synthesis of cyclic polymers with regulated topology
title_full_unstemmed	Blocking-cyclization technique for precise synthesis of cyclic polymers with regulated topology
title_sort	blocking-cyclization technique for precise synthesis of cyclic polymers with regulated topology
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/eb5b2a4b90b347999c0bf9cf1b9b1cc4
work_keys_str_mv	AT jiechen blockingcyclizationtechniqueforprecisesynthesisofcyclicpolymerswithregulatedtopology AT hongfeili blockingcyclizationtechniqueforprecisesynthesisofcyclicpolymerswithregulatedtopology AT hengchenzhang blockingcyclizationtechniqueforprecisesynthesisofcyclicpolymerswithregulatedtopology AT xiaojuanliao blockingcyclizationtechniqueforprecisesynthesisofcyclicpolymerswithregulatedtopology AT huijinghan blockingcyclizationtechniqueforprecisesynthesisofcyclicpolymerswithregulatedtopology AT lidongzhang blockingcyclizationtechniqueforprecisesynthesisofcyclicpolymerswithregulatedtopology AT ruyisun blockingcyclizationtechniqueforprecisesynthesisofcyclicpolymerswithregulatedtopology AT meiranxie blockingcyclizationtechniqueforprecisesynthesisofcyclicpolymerswithregulatedtopology
_version_	1718390867095453696

Blocking-cyclization technique for precise synthesis of cyclic polymers with regulated topology

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