Resolution of P-Sterogenic 1-Phenylphosphin-2-en-4-one 1-Oxide into Two Enantiomers by (<i>R</i>,<i>R</i>)-TADDOL and Conformational Diversity of the Phosphinenone Ring and TADDOL in the Crystal State
The resolution of racemic 1-phenylphosphin-2-en-4-one 1-oxide (<b>2</b>), was achieved through the fractional crystallization of its diastereomeric complexes with (4<i>R</i>,5<i>R</i>)-(−)-2,2-dimethyl -α,α,α′,α′-tetraphenyl-dioxolan-4,5-dimethanol (<i>R,R&l...
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| Main Authors: | , , , , |
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| Format: | article |
| Language: | EN |
| Published: |
MDPI AG
2021
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| Subjects: | |
| Online Access: | https://doaj.org/article/eb5dc90824cf4b1387c8507a7284a917 |
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