Contaminant emissions as indicators of chemical elements in the snow along a latitudinal gradient in southern Andes

Abstract The chemical composition of snow provides insights on atmospheric transport of anthropogenic contaminants at different spatial scales. In this study, we assess how human activities influence the concentration of elements in the Andean mountain snow along a latitudinal transect throughout Ch...

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Autores principales: Jaime Pizarro, Pablo M. Vergara, Sergio Cerda, Raúl R. Cordero, Ximena Castillo, Penny M. Rowe, Gino Casassa, Jorge Carrasco, Alessandro Damiani, Pedro J. Llanillo, Fabrice Lambert, Roberto Rondanelli, Nicolas Huneeus, Francisco Fernandoy, Juan Alfonso, Steven Neshyba
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Publicado: Nature Portfolio 2021
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spelling oai:doaj.org-article:eb95b83146904187837817a8fd4fb25a2021-12-02T15:33:14ZContaminant emissions as indicators of chemical elements in the snow along a latitudinal gradient in southern Andes10.1038/s41598-021-93895-12045-2322https://doaj.org/article/eb95b83146904187837817a8fd4fb25a2021-07-01T00:00:00Zhttps://doi.org/10.1038/s41598-021-93895-1https://doaj.org/toc/2045-2322Abstract The chemical composition of snow provides insights on atmospheric transport of anthropogenic contaminants at different spatial scales. In this study, we assess how human activities influence the concentration of elements in the Andean mountain snow along a latitudinal transect throughout Chile. The concentration of seven elements (Al, Cu, Fe, Li, Mg, Mn and Zn) was associated to gaseous and particulate contaminants emitted at different spatial scales. Our results indicate carbon monoxide (CO) averaged at 20 km and nitrogen oxide (NOx) at 40 km as the main indicators of the chemical elements analyzed. CO was found to be a significant predictor of most element concentrations while concentrations of Cu, Mn, Mg and Zn were positively associated to emissions of NOx. Emission of 2.5 μm and 10 μm particulate matter averaged at different spatial scales was positively associated to concentration of Li. Finally, the concentration of Zn was positively associated to volatile organic compounds (VOC) averaged at 40 km around sampling sites. The association between air contaminants and chemical composition of snow suggests that regions with intensive anthropogenic pollution face reduced quality of freshwater originated from glacier and snow melting.Jaime PizarroPablo M. VergaraSergio CerdaRaúl R. CorderoXimena CastilloPenny M. RoweGino CasassaJorge CarrascoAlessandro DamianiPedro J. LlanilloFabrice LambertRoberto RondanelliNicolas HuneeusFrancisco FernandoyJuan AlfonsoSteven NeshybaNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 11, Iss 1, Pp 1-10 (2021)
institution DOAJ
collection DOAJ
language EN
topic Medicine
R
Science
Q
spellingShingle Medicine
R
Science
Q
Jaime Pizarro
Pablo M. Vergara
Sergio Cerda
Raúl R. Cordero
Ximena Castillo
Penny M. Rowe
Gino Casassa
Jorge Carrasco
Alessandro Damiani
Pedro J. Llanillo
Fabrice Lambert
Roberto Rondanelli
Nicolas Huneeus
Francisco Fernandoy
Juan Alfonso
Steven Neshyba
Contaminant emissions as indicators of chemical elements in the snow along a latitudinal gradient in southern Andes
description Abstract The chemical composition of snow provides insights on atmospheric transport of anthropogenic contaminants at different spatial scales. In this study, we assess how human activities influence the concentration of elements in the Andean mountain snow along a latitudinal transect throughout Chile. The concentration of seven elements (Al, Cu, Fe, Li, Mg, Mn and Zn) was associated to gaseous and particulate contaminants emitted at different spatial scales. Our results indicate carbon monoxide (CO) averaged at 20 km and nitrogen oxide (NOx) at 40 km as the main indicators of the chemical elements analyzed. CO was found to be a significant predictor of most element concentrations while concentrations of Cu, Mn, Mg and Zn were positively associated to emissions of NOx. Emission of 2.5 μm and 10 μm particulate matter averaged at different spatial scales was positively associated to concentration of Li. Finally, the concentration of Zn was positively associated to volatile organic compounds (VOC) averaged at 40 km around sampling sites. The association between air contaminants and chemical composition of snow suggests that regions with intensive anthropogenic pollution face reduced quality of freshwater originated from glacier and snow melting.
format article
author Jaime Pizarro
Pablo M. Vergara
Sergio Cerda
Raúl R. Cordero
Ximena Castillo
Penny M. Rowe
Gino Casassa
Jorge Carrasco
Alessandro Damiani
Pedro J. Llanillo
Fabrice Lambert
Roberto Rondanelli
Nicolas Huneeus
Francisco Fernandoy
Juan Alfonso
Steven Neshyba
author_facet Jaime Pizarro
Pablo M. Vergara
Sergio Cerda
Raúl R. Cordero
Ximena Castillo
Penny M. Rowe
Gino Casassa
Jorge Carrasco
Alessandro Damiani
Pedro J. Llanillo
Fabrice Lambert
Roberto Rondanelli
Nicolas Huneeus
Francisco Fernandoy
Juan Alfonso
Steven Neshyba
author_sort Jaime Pizarro
title Contaminant emissions as indicators of chemical elements in the snow along a latitudinal gradient in southern Andes
title_short Contaminant emissions as indicators of chemical elements in the snow along a latitudinal gradient in southern Andes
title_full Contaminant emissions as indicators of chemical elements in the snow along a latitudinal gradient in southern Andes
title_fullStr Contaminant emissions as indicators of chemical elements in the snow along a latitudinal gradient in southern Andes
title_full_unstemmed Contaminant emissions as indicators of chemical elements in the snow along a latitudinal gradient in southern Andes
title_sort contaminant emissions as indicators of chemical elements in the snow along a latitudinal gradient in southern andes
publisher Nature Portfolio
publishDate 2021
url https://doaj.org/article/eb95b83146904187837817a8fd4fb25a
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