Morphological and Structural Evolution of Chemically Deposited Epitaxially LaNiO<sub>3</sub> Thin Films

We report the preparation and characterization of epitaxial LaNiO<sub>3</sub> (LNO) thin films by chemical solution deposition method using lanthanum and nickel acetylacetonates as starting reagents dissolved in propionic acid. In order to obtain further information regarding the decompo...

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Autores principales: Mircea Nasui, Ramona Bianca Sonher, Ecaterina Ware, Andrada Daniel, Traian Petrisor, Mihai Sebastian Gabor, Lelia Ciontea
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Publicado: MDPI AG 2021
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spelling oai:doaj.org-article:ec0b344e3cff4fa2b60ccc74cd2821fc2021-11-25T17:16:37ZMorphological and Structural Evolution of Chemically Deposited Epitaxially LaNiO<sub>3</sub> Thin Films10.3390/coatings111113762079-6412https://doaj.org/article/ec0b344e3cff4fa2b60ccc74cd2821fc2021-11-01T00:00:00Zhttps://www.mdpi.com/2079-6412/11/11/1376https://doaj.org/toc/2079-6412We report the preparation and characterization of epitaxial LaNiO<sub>3</sub> (LNO) thin films by chemical solution deposition method using lanthanum and nickel acetylacetonates as starting reagents dissolved in propionic acid. In order to obtain further information regarding the decomposition behavior of the film, the precursor solution was dried to obtain the precursor powder, which was investigated by thermal analyses and X-ray diffraction measurements (XRD). The LNO perovskite thin films were deposited by spin coating on SrTiO<sub>3</sub>(100) single crystal substrates. A detailed study with different crystallization temperatures (600–900 °C) at two different heating ramps (5 and 10 °C/min) was performed. Oriented LaNiO<sub>3</sub> thin films with good out-of-plane textures were obtained with optimal surface morphologies.Mircea NasuiRamona Bianca SonherEcaterina WareAndrada DanielTraian PetrisorMihai Sebastian GaborLelia CionteaTraian PetrisorMDPI AGarticleLNO thin filmschemical depositionepitaxial growthEngineering (General). Civil engineering (General)TA1-2040ENCoatings, Vol 11, Iss 1376, p 1376 (2021)
institution DOAJ
collection DOAJ
language EN
topic LNO thin films
chemical deposition
epitaxial growth
Engineering (General). Civil engineering (General)
TA1-2040
spellingShingle LNO thin films
chemical deposition
epitaxial growth
Engineering (General). Civil engineering (General)
TA1-2040
Mircea Nasui
Ramona Bianca Sonher
Ecaterina Ware
Andrada Daniel
Traian Petrisor
Mihai Sebastian Gabor
Lelia Ciontea
Traian Petrisor
Morphological and Structural Evolution of Chemically Deposited Epitaxially LaNiO<sub>3</sub> Thin Films
description We report the preparation and characterization of epitaxial LaNiO<sub>3</sub> (LNO) thin films by chemical solution deposition method using lanthanum and nickel acetylacetonates as starting reagents dissolved in propionic acid. In order to obtain further information regarding the decomposition behavior of the film, the precursor solution was dried to obtain the precursor powder, which was investigated by thermal analyses and X-ray diffraction measurements (XRD). The LNO perovskite thin films were deposited by spin coating on SrTiO<sub>3</sub>(100) single crystal substrates. A detailed study with different crystallization temperatures (600–900 °C) at two different heating ramps (5 and 10 °C/min) was performed. Oriented LaNiO<sub>3</sub> thin films with good out-of-plane textures were obtained with optimal surface morphologies.
format article
author Mircea Nasui
Ramona Bianca Sonher
Ecaterina Ware
Andrada Daniel
Traian Petrisor
Mihai Sebastian Gabor
Lelia Ciontea
Traian Petrisor
author_facet Mircea Nasui
Ramona Bianca Sonher
Ecaterina Ware
Andrada Daniel
Traian Petrisor
Mihai Sebastian Gabor
Lelia Ciontea
Traian Petrisor
author_sort Mircea Nasui
title Morphological and Structural Evolution of Chemically Deposited Epitaxially LaNiO<sub>3</sub> Thin Films
title_short Morphological and Structural Evolution of Chemically Deposited Epitaxially LaNiO<sub>3</sub> Thin Films
title_full Morphological and Structural Evolution of Chemically Deposited Epitaxially LaNiO<sub>3</sub> Thin Films
title_fullStr Morphological and Structural Evolution of Chemically Deposited Epitaxially LaNiO<sub>3</sub> Thin Films
title_full_unstemmed Morphological and Structural Evolution of Chemically Deposited Epitaxially LaNiO<sub>3</sub> Thin Films
title_sort morphological and structural evolution of chemically deposited epitaxially lanio<sub>3</sub> thin films
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/ec0b344e3cff4fa2b60ccc74cd2821fc
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AT ecaterinaware morphologicalandstructuralevolutionofchemicallydepositedepitaxiallylaniosub3subthinfilms
AT andradadaniel morphologicalandstructuralevolutionofchemicallydepositedepitaxiallylaniosub3subthinfilms
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