Successive modification of polydentate complexes gives access to planar carbon- and nitrogen-based ligands

Coordination complexes based on polydentate ligands that contain both nitrogen and carbon ligating atoms are ubiquitous, but design of those with planar cores remains challenging. Here the authors show that complexes with planar CCCN, CCCCN and NCCCN cores can be accessed by modification of the coor...

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Autores principales: Xiaoxi Zhou, Xin Pang, Liming Nie, Congqing Zhu, Kaiyue Zhuo, Qingde Zhuo, Zhixin Chen, Gang Liu, Hong Zhang, Zhenyang Lin, Haiping Xia
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2019
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Acceso en línea:https://doaj.org/article/ec4dcc4d17f3463185d03b5114d91698
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Sumario:Coordination complexes based on polydentate ligands that contain both nitrogen and carbon ligating atoms are ubiquitous, but design of those with planar cores remains challenging. Here the authors show that complexes with planar CCCN, CCCCN and NCCCN cores can be accessed by modification of the coordinating atoms in CCCC core complexes.