Ni2P nanocrystals embedded Ni-MOF nanosheets supported on nickel foam as bifunctional electrocatalyst for urea electrolysis

Abstract It’s highly desired but challenging to synthesize self-supporting nanohybrid made of conductive nanoparticles with metal organic framework (MOF) materials for the application in the electrochemical field. In this work, we report the preparation of Ni2P embedded Ni-MOF nanosheets supported o...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Haitao Wang, Haiyan Zou, Yingying Liu, Zhenglong Liu, Wenshuang Sun, Kunyi Andrew Lin, Tielong Li, Shuangjiang Luo
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Medicine R Science Q
Acceso en línea:	https://doaj.org/article/ec8a780499fc47cd91a4451e6352dced
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:ec8a780499fc47cd91a4451e6352dced
record_format	dspace
spelling	oai:doaj.org-article:ec8a780499fc47cd91a4451e6352dced2021-11-08T10:52:13ZNi2P nanocrystals embedded Ni-MOF nanosheets supported on nickel foam as bifunctional electrocatalyst for urea electrolysis10.1038/s41598-021-00776-82045-2322https://doaj.org/article/ec8a780499fc47cd91a4451e6352dced2021-11-01T00:00:00Zhttps://doi.org/10.1038/s41598-021-00776-8https://doaj.org/toc/2045-2322Abstract It’s highly desired but challenging to synthesize self-supporting nanohybrid made of conductive nanoparticles with metal organic framework (MOF) materials for the application in the electrochemical field. In this work, we report the preparation of Ni2P embedded Ni-MOF nanosheets supported on nickel foam through partial phosphidation (Ni2P@Ni-MOF/NF). The self-supporting Ni2P@Ni-MOF/NF was directly tested as electrode for urea electrolysis. When served as anode for urea oxidation reaction (UOR), it only demands 1.41 V (vs RHE) to deliver a current of 100 mA cm−2. And the overpotential of Ni2P@Ni-MOF/NF to reach 10 mA cm−2 for hydrogen evolution reaction HER was only 66 mV, remarkably lower than Ni2P/NF (133 mV). The exceptional electrochemical performance was attributed to the unique structure of Ni2P@Ni-MOF and the well exposed surface of Ni2P. Furthermore, the Ni2P@Ni-MOF/NF demonstrated outstanding longevity for both HER and UOR. The electrolyzer constructed with Ni2P@Ni-MOF/NF as bifunctional electrode can attain a current density of 100 mA cm−2 at a cell voltage as low as 1.65 V. Our work provides new insights for prepare MOF based nanohydrid for electrochemical application.Haitao WangHaiyan ZouYingying LiuZhenglong LiuWenshuang SunKunyi Andrew LinTielong LiShuangjiang LuoNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 11, Iss 1, Pp 1-11 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Medicine R Science Q
spellingShingle	Medicine R Science Q Haitao Wang Haiyan Zou Yingying Liu Zhenglong Liu Wenshuang Sun Kunyi Andrew Lin Tielong Li Shuangjiang Luo Ni2P nanocrystals embedded Ni-MOF nanosheets supported on nickel foam as bifunctional electrocatalyst for urea electrolysis
description	Abstract It’s highly desired but challenging to synthesize self-supporting nanohybrid made of conductive nanoparticles with metal organic framework (MOF) materials for the application in the electrochemical field. In this work, we report the preparation of Ni2P embedded Ni-MOF nanosheets supported on nickel foam through partial phosphidation (Ni2P@Ni-MOF/NF). The self-supporting Ni2P@Ni-MOF/NF was directly tested as electrode for urea electrolysis. When served as anode for urea oxidation reaction (UOR), it only demands 1.41 V (vs RHE) to deliver a current of 100 mA cm−2. And the overpotential of Ni2P@Ni-MOF/NF to reach 10 mA cm−2 for hydrogen evolution reaction HER was only 66 mV, remarkably lower than Ni2P/NF (133 mV). The exceptional electrochemical performance was attributed to the unique structure of Ni2P@Ni-MOF and the well exposed surface of Ni2P. Furthermore, the Ni2P@Ni-MOF/NF demonstrated outstanding longevity for both HER and UOR. The electrolyzer constructed with Ni2P@Ni-MOF/NF as bifunctional electrode can attain a current density of 100 mA cm−2 at a cell voltage as low as 1.65 V. Our work provides new insights for prepare MOF based nanohydrid for electrochemical application.
format	article
author	Haitao Wang Haiyan Zou Yingying Liu Zhenglong Liu Wenshuang Sun Kunyi Andrew Lin Tielong Li Shuangjiang Luo
author_facet	Haitao Wang Haiyan Zou Yingying Liu Zhenglong Liu Wenshuang Sun Kunyi Andrew Lin Tielong Li Shuangjiang Luo
author_sort	Haitao Wang
title	Ni2P nanocrystals embedded Ni-MOF nanosheets supported on nickel foam as bifunctional electrocatalyst for urea electrolysis
title_short	Ni2P nanocrystals embedded Ni-MOF nanosheets supported on nickel foam as bifunctional electrocatalyst for urea electrolysis
title_full	Ni2P nanocrystals embedded Ni-MOF nanosheets supported on nickel foam as bifunctional electrocatalyst for urea electrolysis
title_fullStr	Ni2P nanocrystals embedded Ni-MOF nanosheets supported on nickel foam as bifunctional electrocatalyst for urea electrolysis
title_full_unstemmed	Ni2P nanocrystals embedded Ni-MOF nanosheets supported on nickel foam as bifunctional electrocatalyst for urea electrolysis
title_sort	ni2p nanocrystals embedded ni-mof nanosheets supported on nickel foam as bifunctional electrocatalyst for urea electrolysis
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/ec8a780499fc47cd91a4451e6352dced
work_keys_str_mv	AT haitaowang ni2pnanocrystalsembeddednimofnanosheetssupportedonnickelfoamasbifunctionalelectrocatalystforureaelectrolysis AT haiyanzou ni2pnanocrystalsembeddednimofnanosheetssupportedonnickelfoamasbifunctionalelectrocatalystforureaelectrolysis AT yingyingliu ni2pnanocrystalsembeddednimofnanosheetssupportedonnickelfoamasbifunctionalelectrocatalystforureaelectrolysis AT zhenglongliu ni2pnanocrystalsembeddednimofnanosheetssupportedonnickelfoamasbifunctionalelectrocatalystforureaelectrolysis AT wenshuangsun ni2pnanocrystalsembeddednimofnanosheetssupportedonnickelfoamasbifunctionalelectrocatalystforureaelectrolysis AT kunyiandrewlin ni2pnanocrystalsembeddednimofnanosheetssupportedonnickelfoamasbifunctionalelectrocatalystforureaelectrolysis AT tielongli ni2pnanocrystalsembeddednimofnanosheetssupportedonnickelfoamasbifunctionalelectrocatalystforureaelectrolysis AT shuangjiangluo ni2pnanocrystalsembeddednimofnanosheetssupportedonnickelfoamasbifunctionalelectrocatalystforureaelectrolysis
_version_	1718442577314709504

Ni2P nanocrystals embedded Ni-MOF nanosheets supported on nickel foam as bifunctional electrocatalyst for urea electrolysis

Ejemplares similares