Mechanisms of halosulfuron methyl pesticide biosorption onto neem seeds powder

Abstract The current investigation was designed to remove halosulfuron methyl from aqueous media by means of neem seed powder (NSP) in batch modes. Characterizations of NSP were carried out by using EDX, SEM, FTIR, point of zero charge and surface analysis. Optimum operation conditions were scrutini...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Atta ul Haq, Muhammad Saeed, Muhammad Usman, Ameer Fawad Zahoor, Muhammad Naveed Anjum, Tahir Maqbool, Shazia Naheed, Muhammad Kashif
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Medicine R Science Q
Acceso en línea:	https://doaj.org/article/ecf2df3df0e640c1a12943a3a46b73ed
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:ecf2df3df0e640c1a12943a3a46b73ed
record_format	dspace
spelling	oai:doaj.org-article:ecf2df3df0e640c1a12943a3a46b73ed2021-12-02T15:36:14ZMechanisms of halosulfuron methyl pesticide biosorption onto neem seeds powder10.1038/s41598-021-88929-72045-2322https://doaj.org/article/ecf2df3df0e640c1a12943a3a46b73ed2021-05-01T00:00:00Zhttps://doi.org/10.1038/s41598-021-88929-7https://doaj.org/toc/2045-2322Abstract The current investigation was designed to remove halosulfuron methyl from aqueous media by means of neem seed powder (NSP) in batch modes. Characterizations of NSP were carried out by using EDX, SEM, FTIR, point of zero charge and surface analysis. Optimum operation conditions were scrutinized by studying the influence of different factors like solution pH, dose of NSP, contact time, initial halosulfuron methyl concentration and temperature. Result indicates the dependency of the removal of halosulfuron methyl on solution pH and maximal removal (54%) was achieved in acidic medium (i.e. pH 3.0). To identify the chemical surface of NSP, point of zero charge of NSP was determined and was found to be 6.5 which imply that the surface of NSP is positively charged below pH 6.6 and favored the anionic sorption. Kinetics of halosulfuron methyl were demonstrated well by pseudo second order due to highest R2 (0.99) owing to the nearness between experimental and calculated sorption capacities. Isotherm results imply that Langmuir was found to the principal model to explain the removal of halosulfuron methyl and maximum monolayer sorption capacity was determined to be 200 mg g−1. Thermodynamic parameters like ΔH°, ΔG° and ΔS° were calculated from van’t Hoff plot and were found negative which suggest that removal of halosulfuron methyl is exothermic and spontaneous at low temperature. These outcomes insinuate that neem seed power may be a valuable, inexpensive and ecofriendly biosorbent for the removal of pesticides.Atta ul HaqMuhammad SaeedMuhammad UsmanAmeer Fawad ZahoorMuhammad Naveed AnjumTahir MaqboolShazia NaheedMuhammad KashifNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 11, Iss 1, Pp 1-13 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Medicine R Science Q
spellingShingle	Medicine R Science Q Atta ul Haq Muhammad Saeed Muhammad Usman Ameer Fawad Zahoor Muhammad Naveed Anjum Tahir Maqbool Shazia Naheed Muhammad Kashif Mechanisms of halosulfuron methyl pesticide biosorption onto neem seeds powder
description	Abstract The current investigation was designed to remove halosulfuron methyl from aqueous media by means of neem seed powder (NSP) in batch modes. Characterizations of NSP were carried out by using EDX, SEM, FTIR, point of zero charge and surface analysis. Optimum operation conditions were scrutinized by studying the influence of different factors like solution pH, dose of NSP, contact time, initial halosulfuron methyl concentration and temperature. Result indicates the dependency of the removal of halosulfuron methyl on solution pH and maximal removal (54%) was achieved in acidic medium (i.e. pH 3.0). To identify the chemical surface of NSP, point of zero charge of NSP was determined and was found to be 6.5 which imply that the surface of NSP is positively charged below pH 6.6 and favored the anionic sorption. Kinetics of halosulfuron methyl were demonstrated well by pseudo second order due to highest R2 (0.99) owing to the nearness between experimental and calculated sorption capacities. Isotherm results imply that Langmuir was found to the principal model to explain the removal of halosulfuron methyl and maximum monolayer sorption capacity was determined to be 200 mg g−1. Thermodynamic parameters like ΔH°, ΔG° and ΔS° were calculated from van’t Hoff plot and were found negative which suggest that removal of halosulfuron methyl is exothermic and spontaneous at low temperature. These outcomes insinuate that neem seed power may be a valuable, inexpensive and ecofriendly biosorbent for the removal of pesticides.
format	article
author	Atta ul Haq Muhammad Saeed Muhammad Usman Ameer Fawad Zahoor Muhammad Naveed Anjum Tahir Maqbool Shazia Naheed Muhammad Kashif
author_facet	Atta ul Haq Muhammad Saeed Muhammad Usman Ameer Fawad Zahoor Muhammad Naveed Anjum Tahir Maqbool Shazia Naheed Muhammad Kashif
author_sort	Atta ul Haq
title	Mechanisms of halosulfuron methyl pesticide biosorption onto neem seeds powder
title_short	Mechanisms of halosulfuron methyl pesticide biosorption onto neem seeds powder
title_full	Mechanisms of halosulfuron methyl pesticide biosorption onto neem seeds powder
title_fullStr	Mechanisms of halosulfuron methyl pesticide biosorption onto neem seeds powder
title_full_unstemmed	Mechanisms of halosulfuron methyl pesticide biosorption onto neem seeds powder
title_sort	mechanisms of halosulfuron methyl pesticide biosorption onto neem seeds powder
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/ecf2df3df0e640c1a12943a3a46b73ed
work_keys_str_mv	AT attaulhaq mechanismsofhalosulfuronmethylpesticidebiosorptionontoneemseedspowder AT muhammadsaeed mechanismsofhalosulfuronmethylpesticidebiosorptionontoneemseedspowder AT muhammadusman mechanismsofhalosulfuronmethylpesticidebiosorptionontoneemseedspowder AT ameerfawadzahoor mechanismsofhalosulfuronmethylpesticidebiosorptionontoneemseedspowder AT muhammadnaveedanjum mechanismsofhalosulfuronmethylpesticidebiosorptionontoneemseedspowder AT tahirmaqbool mechanismsofhalosulfuronmethylpesticidebiosorptionontoneemseedspowder AT shazianaheed mechanismsofhalosulfuronmethylpesticidebiosorptionontoneemseedspowder AT muhammadkashif mechanismsofhalosulfuronmethylpesticidebiosorptionontoneemseedspowder
_version_	1718386387668959232

Mechanisms of halosulfuron methyl pesticide biosorption onto neem seeds powder

Ejemplares similares