Structure and optical properties of GaSe-CdSe composites driven by Cd inetrcalation in gase lamellar crystals

A new composite material composed of GaSe and CdSe has been obtained by treatment of GaSe single-crystal lamellas in Cd vapors at temperatures of 773853 K and intercalation of Cd interlayers. The structure and optical properties of the GaSe-CdSe composite material have been studied. The content of...

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Autores principales: Caraman, Iuliana, Canţer, Valeriu, Evtodiev, Igor, Leontie, Liviu, Arzumanyan, Grigory, Untila, Dumitru, Dmitroglo, Liliana
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Publicado: D.Ghitu Institute of Electronic Engineering and Nanotechnologies 2015
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Acceso en línea:https://doaj.org/article/ed540416260949fc8e7c94939f0111a3
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spelling oai:doaj.org-article:ed540416260949fc8e7c94939f0111a32021-11-21T11:58:29ZStructure and optical properties of GaSe-CdSe composites driven by Cd inetrcalation in gase lamellar crystals539.12537-63651810-648Xhttps://doaj.org/article/ed540416260949fc8e7c94939f0111a32015-11-01T00:00:00Zhttps://mjps.nanotech.md/archive/2015/article/43389https://doaj.org/toc/1810-648Xhttps://doaj.org/toc/2537-6365A new composite material composed of GaSe and CdSe has been obtained by treatment of GaSe single-crystal lamellas in Cd vapors at temperatures of 773853 K and intercalation of Cd interlayers. The structure and optical properties of the GaSe-CdSe composite material have been studied. The content of CdSe crystallites was found to grow with increasing treatment temperature or with increasing duration of treatment at a constant temperature. Analysis of XRD, PL, XPS, AFM, and Raman patterns has shown that the heterogeneous composite composed of micro and nanocrystallites of CdSe in GaSe can be obtained by Cd intercalation in a temperature range of 753853 K. On the basis of Raman spectrum, the vibrational modes of the composite have been identified. The PL of these materials contains emission bands of free and bound excitons, donor-acceptor bands, and bands of recombination via impurity levels. The PL emission spectra measured at a temperature of 78 and 300 K for the composites result from the overlapping of the emission bands of the components of GaSe doped with Cd and the CdSe crystallites. Caraman, IulianaCanţer, ValeriuEvtodiev, IgorLeontie, LiviuArzumanyan, GrigoryUntila, DumitruDmitroglo, LilianaD.Ghitu Institute of Electronic Engineering and NanotechnologiesarticlePhysicsQC1-999ElectronicsTK7800-8360ENMoldavian Journal of the Physical Sciences, Vol 14, Iss 1-2, Pp 51-60 (2015)
institution DOAJ
collection DOAJ
language EN
topic Physics
QC1-999
Electronics
TK7800-8360
spellingShingle Physics
QC1-999
Electronics
TK7800-8360
Caraman, Iuliana
Canţer, Valeriu
Evtodiev, Igor
Leontie, Liviu
Arzumanyan, Grigory
Untila, Dumitru
Dmitroglo, Liliana
Structure and optical properties of GaSe-CdSe composites driven by Cd inetrcalation in gase lamellar crystals
description A new composite material composed of GaSe and CdSe has been obtained by treatment of GaSe single-crystal lamellas in Cd vapors at temperatures of 773853 K and intercalation of Cd interlayers. The structure and optical properties of the GaSe-CdSe composite material have been studied. The content of CdSe crystallites was found to grow with increasing treatment temperature or with increasing duration of treatment at a constant temperature. Analysis of XRD, PL, XPS, AFM, and Raman patterns has shown that the heterogeneous composite composed of micro and nanocrystallites of CdSe in GaSe can be obtained by Cd intercalation in a temperature range of 753853 K. On the basis of Raman spectrum, the vibrational modes of the composite have been identified. The PL of these materials contains emission bands of free and bound excitons, donor-acceptor bands, and bands of recombination via impurity levels. The PL emission spectra measured at a temperature of 78 and 300 K for the composites result from the overlapping of the emission bands of the components of GaSe doped with Cd and the CdSe crystallites.
format article
author Caraman, Iuliana
Canţer, Valeriu
Evtodiev, Igor
Leontie, Liviu
Arzumanyan, Grigory
Untila, Dumitru
Dmitroglo, Liliana
author_facet Caraman, Iuliana
Canţer, Valeriu
Evtodiev, Igor
Leontie, Liviu
Arzumanyan, Grigory
Untila, Dumitru
Dmitroglo, Liliana
author_sort Caraman, Iuliana
title Structure and optical properties of GaSe-CdSe composites driven by Cd inetrcalation in gase lamellar crystals
title_short Structure and optical properties of GaSe-CdSe composites driven by Cd inetrcalation in gase lamellar crystals
title_full Structure and optical properties of GaSe-CdSe composites driven by Cd inetrcalation in gase lamellar crystals
title_fullStr Structure and optical properties of GaSe-CdSe composites driven by Cd inetrcalation in gase lamellar crystals
title_full_unstemmed Structure and optical properties of GaSe-CdSe composites driven by Cd inetrcalation in gase lamellar crystals
title_sort structure and optical properties of gase-cdse composites driven by cd inetrcalation in gase lamellar crystals
publisher D.Ghitu Institute of Electronic Engineering and Nanotechnologies
publishDate 2015
url https://doaj.org/article/ed540416260949fc8e7c94939f0111a3
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