A comparative study on the chloride effectiveness of synthetic rutile and natural rutile manufactured from ilmenite ore

Abstract Studies on continuous and selective chlorination by using ilmenite have been actively conducted because the efficient removal of FeO from ilmenite(FeTiO3) ore using selective chlorination not only improves the reaction purity of TiCl4 but it also leads to price competitiveness compared to T...

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Autores principales:	Eun Jin Jung, Jinyoung Kim, Ye Rin Lee
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Medicine R Science Q
Acceso en línea:	https://doaj.org/article/ed622c4737444ffcb5c2904d86213dd1
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spelling	oai:doaj.org-article:ed622c4737444ffcb5c2904d86213dd12021-12-02T14:21:43ZA comparative study on the chloride effectiveness of synthetic rutile and natural rutile manufactured from ilmenite ore10.1038/s41598-021-83485-62045-2322https://doaj.org/article/ed622c4737444ffcb5c2904d86213dd12021-02-01T00:00:00Zhttps://doi.org/10.1038/s41598-021-83485-6https://doaj.org/toc/2045-2322Abstract Studies on continuous and selective chlorination by using ilmenite have been actively conducted because the efficient removal of FeO from ilmenite(FeTiO3) ore using selective chlorination not only improves the reaction purity of TiCl4 but it also leads to price competitiveness compared to TiCl4 synthesized from natural rutile. The chlorination of synthetic rutile with FeO removed was compared with that of natural rutile to examine the reaction efficiency. The selective chlorination efficiency depends on the input amounts of coke and Cl2, as shown by thermodynamic calculation, when FeO is selectively removed. It was found that manufacturing of TiCl4 was easier by using the synthetic rutile, because it had greater porosity than natural rutile. Relatively greater pore volumes were found in the synthetic rutile than in natural rutile. It was confirmed that the reaction efficiency of chlorination for TiCl4 production was directly related to the difference in the porosity distribution between the titanium ores, as verified by a kinetic comparison of synthetic and natural rutiles.Eun Jin JungJinyoung KimYe Rin LeeNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 11, Iss 1, Pp 1-9 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Medicine R Science Q
spellingShingle	Medicine R Science Q Eun Jin Jung Jinyoung Kim Ye Rin Lee A comparative study on the chloride effectiveness of synthetic rutile and natural rutile manufactured from ilmenite ore
description	Abstract Studies on continuous and selective chlorination by using ilmenite have been actively conducted because the efficient removal of FeO from ilmenite(FeTiO3) ore using selective chlorination not only improves the reaction purity of TiCl4 but it also leads to price competitiveness compared to TiCl4 synthesized from natural rutile. The chlorination of synthetic rutile with FeO removed was compared with that of natural rutile to examine the reaction efficiency. The selective chlorination efficiency depends on the input amounts of coke and Cl2, as shown by thermodynamic calculation, when FeO is selectively removed. It was found that manufacturing of TiCl4 was easier by using the synthetic rutile, because it had greater porosity than natural rutile. Relatively greater pore volumes were found in the synthetic rutile than in natural rutile. It was confirmed that the reaction efficiency of chlorination for TiCl4 production was directly related to the difference in the porosity distribution between the titanium ores, as verified by a kinetic comparison of synthetic and natural rutiles.
format	article
author	Eun Jin Jung Jinyoung Kim Ye Rin Lee
author_facet	Eun Jin Jung Jinyoung Kim Ye Rin Lee
author_sort	Eun Jin Jung
title	A comparative study on the chloride effectiveness of synthetic rutile and natural rutile manufactured from ilmenite ore
title_short	A comparative study on the chloride effectiveness of synthetic rutile and natural rutile manufactured from ilmenite ore
title_full	A comparative study on the chloride effectiveness of synthetic rutile and natural rutile manufactured from ilmenite ore
title_fullStr	A comparative study on the chloride effectiveness of synthetic rutile and natural rutile manufactured from ilmenite ore
title_full_unstemmed	A comparative study on the chloride effectiveness of synthetic rutile and natural rutile manufactured from ilmenite ore
title_sort	comparative study on the chloride effectiveness of synthetic rutile and natural rutile manufactured from ilmenite ore
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/ed622c4737444ffcb5c2904d86213dd1
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A comparative study on the chloride effectiveness of synthetic rutile and natural rutile manufactured from ilmenite ore

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