Single-molecule level control of host-guest interactions in metallocycle-C60 complexes

Studying the single-molecule behavior of host-guest complexes can provide fundamental insights into their supramolecular interactions. Here, the authors use the scanning tunneling microscopy break junction technique to show that encapsulation of a C60 molecule significantly enhances the conductance...

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Autores principales: Jian-Hong Tang, Yueqi Li, Qingqing Wu, Zixiao Wang, Songjun Hou, Kun Tang, Yue Sun, Hui Wang, Heng Wang, Cheng Lu, Xiang Wang, Xiaopeng Li, Dong Wang, Jiannian Yao, Colin J. Lambert, Nongjian Tao, Yu-Wu Zhong, Peter J. Stang
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Lenguaje:EN
Publicado: Nature Portfolio 2019
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Acceso en línea:https://doaj.org/article/ed7c0cd2f57a4f9db5e83f971ab358e1
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spelling oai:doaj.org-article:ed7c0cd2f57a4f9db5e83f971ab358e12021-12-02T14:39:56ZSingle-molecule level control of host-guest interactions in metallocycle-C60 complexes10.1038/s41467-019-12534-62041-1723https://doaj.org/article/ed7c0cd2f57a4f9db5e83f971ab358e12019-10-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-12534-6https://doaj.org/toc/2041-1723Studying the single-molecule behavior of host-guest complexes can provide fundamental insights into their supramolecular interactions. Here, the authors use the scanning tunneling microscopy break junction technique to show that encapsulation of a C60 molecule significantly enhances the conductance of an organoplatinum metallocycle; mechanical stretching of the junction releases the guest, returning the conductance to free-host level.Jian-Hong TangYueqi LiQingqing WuZixiao WangSongjun HouKun TangYue SunHui WangHeng WangCheng LuXiang WangXiaopeng LiDong WangJiannian YaoColin J. LambertNongjian TaoYu-Wu ZhongPeter J. StangNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-9 (2019)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Jian-Hong Tang
Yueqi Li
Qingqing Wu
Zixiao Wang
Songjun Hou
Kun Tang
Yue Sun
Hui Wang
Heng Wang
Cheng Lu
Xiang Wang
Xiaopeng Li
Dong Wang
Jiannian Yao
Colin J. Lambert
Nongjian Tao
Yu-Wu Zhong
Peter J. Stang
Single-molecule level control of host-guest interactions in metallocycle-C60 complexes
description Studying the single-molecule behavior of host-guest complexes can provide fundamental insights into their supramolecular interactions. Here, the authors use the scanning tunneling microscopy break junction technique to show that encapsulation of a C60 molecule significantly enhances the conductance of an organoplatinum metallocycle; mechanical stretching of the junction releases the guest, returning the conductance to free-host level.
format article
author Jian-Hong Tang
Yueqi Li
Qingqing Wu
Zixiao Wang
Songjun Hou
Kun Tang
Yue Sun
Hui Wang
Heng Wang
Cheng Lu
Xiang Wang
Xiaopeng Li
Dong Wang
Jiannian Yao
Colin J. Lambert
Nongjian Tao
Yu-Wu Zhong
Peter J. Stang
author_facet Jian-Hong Tang
Yueqi Li
Qingqing Wu
Zixiao Wang
Songjun Hou
Kun Tang
Yue Sun
Hui Wang
Heng Wang
Cheng Lu
Xiang Wang
Xiaopeng Li
Dong Wang
Jiannian Yao
Colin J. Lambert
Nongjian Tao
Yu-Wu Zhong
Peter J. Stang
author_sort Jian-Hong Tang
title Single-molecule level control of host-guest interactions in metallocycle-C60 complexes
title_short Single-molecule level control of host-guest interactions in metallocycle-C60 complexes
title_full Single-molecule level control of host-guest interactions in metallocycle-C60 complexes
title_fullStr Single-molecule level control of host-guest interactions in metallocycle-C60 complexes
title_full_unstemmed Single-molecule level control of host-guest interactions in metallocycle-C60 complexes
title_sort single-molecule level control of host-guest interactions in metallocycle-c60 complexes
publisher Nature Portfolio
publishDate 2019
url https://doaj.org/article/ed7c0cd2f57a4f9db5e83f971ab358e1
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