Single-molecule level control of host-guest interactions in metallocycle-C60 complexes
Studying the single-molecule behavior of host-guest complexes can provide fundamental insights into their supramolecular interactions. Here, the authors use the scanning tunneling microscopy break junction technique to show that encapsulation of a C60 molecule significantly enhances the conductance...
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Nature Portfolio
2019
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oai:doaj.org-article:ed7c0cd2f57a4f9db5e83f971ab358e12021-12-02T14:39:56ZSingle-molecule level control of host-guest interactions in metallocycle-C60 complexes10.1038/s41467-019-12534-62041-1723https://doaj.org/article/ed7c0cd2f57a4f9db5e83f971ab358e12019-10-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-12534-6https://doaj.org/toc/2041-1723Studying the single-molecule behavior of host-guest complexes can provide fundamental insights into their supramolecular interactions. Here, the authors use the scanning tunneling microscopy break junction technique to show that encapsulation of a C60 molecule significantly enhances the conductance of an organoplatinum metallocycle; mechanical stretching of the junction releases the guest, returning the conductance to free-host level.Jian-Hong TangYueqi LiQingqing WuZixiao WangSongjun HouKun TangYue SunHui WangHeng WangCheng LuXiang WangXiaopeng LiDong WangJiannian YaoColin J. LambertNongjian TaoYu-Wu ZhongPeter J. StangNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-9 (2019) |
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Science Q Jian-Hong Tang Yueqi Li Qingqing Wu Zixiao Wang Songjun Hou Kun Tang Yue Sun Hui Wang Heng Wang Cheng Lu Xiang Wang Xiaopeng Li Dong Wang Jiannian Yao Colin J. Lambert Nongjian Tao Yu-Wu Zhong Peter J. Stang Single-molecule level control of host-guest interactions in metallocycle-C60 complexes |
description |
Studying the single-molecule behavior of host-guest complexes can provide fundamental insights into their supramolecular interactions. Here, the authors use the scanning tunneling microscopy break junction technique to show that encapsulation of a C60 molecule significantly enhances the conductance of an organoplatinum metallocycle; mechanical stretching of the junction releases the guest, returning the conductance to free-host level. |
format |
article |
author |
Jian-Hong Tang Yueqi Li Qingqing Wu Zixiao Wang Songjun Hou Kun Tang Yue Sun Hui Wang Heng Wang Cheng Lu Xiang Wang Xiaopeng Li Dong Wang Jiannian Yao Colin J. Lambert Nongjian Tao Yu-Wu Zhong Peter J. Stang |
author_facet |
Jian-Hong Tang Yueqi Li Qingqing Wu Zixiao Wang Songjun Hou Kun Tang Yue Sun Hui Wang Heng Wang Cheng Lu Xiang Wang Xiaopeng Li Dong Wang Jiannian Yao Colin J. Lambert Nongjian Tao Yu-Wu Zhong Peter J. Stang |
author_sort |
Jian-Hong Tang |
title |
Single-molecule level control of host-guest interactions in metallocycle-C60 complexes |
title_short |
Single-molecule level control of host-guest interactions in metallocycle-C60 complexes |
title_full |
Single-molecule level control of host-guest interactions in metallocycle-C60 complexes |
title_fullStr |
Single-molecule level control of host-guest interactions in metallocycle-C60 complexes |
title_full_unstemmed |
Single-molecule level control of host-guest interactions in metallocycle-C60 complexes |
title_sort |
single-molecule level control of host-guest interactions in metallocycle-c60 complexes |
publisher |
Nature Portfolio |
publishDate |
2019 |
url |
https://doaj.org/article/ed7c0cd2f57a4f9db5e83f971ab358e1 |
work_keys_str_mv |
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