Denitrification in Intrinsic and Specific Groundwater Vulnerability Assessment: A Review

Several groundwater vulnerability methodologies have been implemented throughout the years to face the increasing worldwide groundwater pollution, ranging from simple rating methodologies to complex numerical, statistical, and hybrid methods. Most of these methods have been used to evaluate groundwa...

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Autores principales: Gianluigi Busico, Luigi Alessandrino, Micòl Mastrocicco
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Lenguaje:EN
Publicado: MDPI AG 2021
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Acceso en línea:https://doaj.org/article/ed8eb910681249a09b366937b1f89390
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spelling oai:doaj.org-article:ed8eb910681249a09b366937b1f893902021-11-25T16:34:31ZDenitrification in Intrinsic and Specific Groundwater Vulnerability Assessment: A Review10.3390/app1122106572076-3417https://doaj.org/article/ed8eb910681249a09b366937b1f893902021-11-01T00:00:00Zhttps://www.mdpi.com/2076-3417/11/22/10657https://doaj.org/toc/2076-3417Several groundwater vulnerability methodologies have been implemented throughout the years to face the increasing worldwide groundwater pollution, ranging from simple rating methodologies to complex numerical, statistical, and hybrid methods. Most of these methods have been used to evaluate groundwater vulnerability to nitrate, which is considered the major groundwater contaminant worldwide. Together with dilution, the degradation of nitrate via denitrification has been acknowledged as a process that can reduce reactive nitrogen mass loading rates in both deep and shallow aquifers. Thus, denitrification should be included in groundwater vulnerability studies and integrated into the various methodologies. This work reviewed the way in which denitrification has been considered within the vulnerability assessment methods and how it could increase the reliability of the overall results. Rating and statistical methods often disregard or indirectly incorporate denitrification, while numerical models make use of kinetic reactions that are able to quantify the spatial and temporal variations of denitrification rates. Nevertheless, the rating methods are still the most utilized, due to their linear structures, especially in watershed studies. More efforts should be paid in future studies to implement, calibrate, and validate user-friendly vulnerability assessment methods that are able to deal with denitrification capacity and rates at large spatial and temporal scales.Gianluigi BusicoLuigi AlessandrinoMicòl MastrociccoMDPI AGarticledenitrification rateaquifergroundwater qualityvulnerability assessmentnitrate pollutionsaturated and unsaturated zonesTechnologyTEngineering (General). Civil engineering (General)TA1-2040Biology (General)QH301-705.5PhysicsQC1-999ChemistryQD1-999ENApplied Sciences, Vol 11, Iss 10657, p 10657 (2021)
institution DOAJ
collection DOAJ
language EN
topic denitrification rate
aquifer
groundwater quality
vulnerability assessment
nitrate pollution
saturated and unsaturated zones
Technology
T
Engineering (General). Civil engineering (General)
TA1-2040
Biology (General)
QH301-705.5
Physics
QC1-999
Chemistry
QD1-999
spellingShingle denitrification rate
aquifer
groundwater quality
vulnerability assessment
nitrate pollution
saturated and unsaturated zones
Technology
T
Engineering (General). Civil engineering (General)
TA1-2040
Biology (General)
QH301-705.5
Physics
QC1-999
Chemistry
QD1-999
Gianluigi Busico
Luigi Alessandrino
Micòl Mastrocicco
Denitrification in Intrinsic and Specific Groundwater Vulnerability Assessment: A Review
description Several groundwater vulnerability methodologies have been implemented throughout the years to face the increasing worldwide groundwater pollution, ranging from simple rating methodologies to complex numerical, statistical, and hybrid methods. Most of these methods have been used to evaluate groundwater vulnerability to nitrate, which is considered the major groundwater contaminant worldwide. Together with dilution, the degradation of nitrate via denitrification has been acknowledged as a process that can reduce reactive nitrogen mass loading rates in both deep and shallow aquifers. Thus, denitrification should be included in groundwater vulnerability studies and integrated into the various methodologies. This work reviewed the way in which denitrification has been considered within the vulnerability assessment methods and how it could increase the reliability of the overall results. Rating and statistical methods often disregard or indirectly incorporate denitrification, while numerical models make use of kinetic reactions that are able to quantify the spatial and temporal variations of denitrification rates. Nevertheless, the rating methods are still the most utilized, due to their linear structures, especially in watershed studies. More efforts should be paid in future studies to implement, calibrate, and validate user-friendly vulnerability assessment methods that are able to deal with denitrification capacity and rates at large spatial and temporal scales.
format article
author Gianluigi Busico
Luigi Alessandrino
Micòl Mastrocicco
author_facet Gianluigi Busico
Luigi Alessandrino
Micòl Mastrocicco
author_sort Gianluigi Busico
title Denitrification in Intrinsic and Specific Groundwater Vulnerability Assessment: A Review
title_short Denitrification in Intrinsic and Specific Groundwater Vulnerability Assessment: A Review
title_full Denitrification in Intrinsic and Specific Groundwater Vulnerability Assessment: A Review
title_fullStr Denitrification in Intrinsic and Specific Groundwater Vulnerability Assessment: A Review
title_full_unstemmed Denitrification in Intrinsic and Specific Groundwater Vulnerability Assessment: A Review
title_sort denitrification in intrinsic and specific groundwater vulnerability assessment: a review
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/ed8eb910681249a09b366937b1f89390
work_keys_str_mv AT gianluigibusico denitrificationinintrinsicandspecificgroundwatervulnerabilityassessmentareview
AT luigialessandrino denitrificationinintrinsicandspecificgroundwatervulnerabilityassessmentareview
AT micolmastrocicco denitrificationinintrinsicandspecificgroundwatervulnerabilityassessmentareview
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