Triacylglycerol and Fatty Acid Compositions of Blackberry, Red Raspberry, Black Raspberry, Blueberry and Cranberry Seed Oils by Ultra-Performance Convergence Chromatography-Quadrupole Time-of-Flight Mass Spectrometry
The triacylglycerol (TAG) compositions of blackberry, red raspberry, black raspberry, blueberry and cranberry seed oils were examined using ultra-performance convergence chromatography-quadrupole time-of-flight mass spectrometry (UPC<sup>2</sup>-QTOF MS). A total of 52, 53, 52, 59 and 58...
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MDPI AG
2021
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oai:doaj.org-article:edc0683182124dfb91d6e241a5512b2a2021-11-25T17:32:11ZTriacylglycerol and Fatty Acid Compositions of Blackberry, Red Raspberry, Black Raspberry, Blueberry and Cranberry Seed Oils by Ultra-Performance Convergence Chromatography-Quadrupole Time-of-Flight Mass Spectrometry10.3390/foods101125302304-8158https://doaj.org/article/edc0683182124dfb91d6e241a5512b2a2021-10-01T00:00:00Zhttps://www.mdpi.com/2304-8158/10/11/2530https://doaj.org/toc/2304-8158The triacylglycerol (TAG) compositions of blackberry, red raspberry, black raspberry, blueberry and cranberry seed oils were examined using ultra-performance convergence chromatography-quadrupole time-of-flight mass spectrometry (UPC<sup>2</sup>-QTOF MS). A total of 52, 53, 52, 59 and 58 TAGs were detected and tentatively identified from the blackberry, red raspberry, black raspberry, blueberry and cranberry seed oils, respectively, according to their accurate molecular weight in MS1 and fragment ion profiles in MS2. OLL was the most abundant TAG in the blackberry, red raspberry and black raspberry seed oils. Furthermore, the fatty acid compositions of the five berry seed oils were directly determined by gas chromatography coupled with mass spectrometry (GC-MS). In addition, the seed oils had total phenolic contents ranging 13.68–177.06 µmol GAE (gallic acid equivalent)/L oil, and significant scavenging capacities against DPPH, peroxyl, and ABTS<sup>+</sup> radicals. These results indicated that the combination of UPC<sup>2</sup> and QTOF MS could effectively identify and semi-quantify the TAGs compositions of the berry seed oils with sn-position information for the fatty acids. Understanding the TAGs compositions of these berry seed oils could improve the utilization of these potentially high nutritional value oils for human health.Yinghua LuoFanghao YuanYanfang LiJunyi (Danny) WangBoyan GaoLiangli (Lucy) YuMDPI AGarticletriacylglycerol (TAG) compositionsberry seed oilsultra-performance convergence chromatography (UPC<sup>2</sup>)quadrupole time-of-flight mass spectrometry (QTOF MS)Chemical technologyTP1-1185ENFoods, Vol 10, Iss 2530, p 2530 (2021) |
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triacylglycerol (TAG) compositions berry seed oils ultra-performance convergence chromatography (UPC<sup>2</sup>) quadrupole time-of-flight mass spectrometry (QTOF MS) Chemical technology TP1-1185 |
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triacylglycerol (TAG) compositions berry seed oils ultra-performance convergence chromatography (UPC<sup>2</sup>) quadrupole time-of-flight mass spectrometry (QTOF MS) Chemical technology TP1-1185 Yinghua Luo Fanghao Yuan Yanfang Li Junyi (Danny) Wang Boyan Gao Liangli (Lucy) Yu Triacylglycerol and Fatty Acid Compositions of Blackberry, Red Raspberry, Black Raspberry, Blueberry and Cranberry Seed Oils by Ultra-Performance Convergence Chromatography-Quadrupole Time-of-Flight Mass Spectrometry |
description |
The triacylglycerol (TAG) compositions of blackberry, red raspberry, black raspberry, blueberry and cranberry seed oils were examined using ultra-performance convergence chromatography-quadrupole time-of-flight mass spectrometry (UPC<sup>2</sup>-QTOF MS). A total of 52, 53, 52, 59 and 58 TAGs were detected and tentatively identified from the blackberry, red raspberry, black raspberry, blueberry and cranberry seed oils, respectively, according to their accurate molecular weight in MS1 and fragment ion profiles in MS2. OLL was the most abundant TAG in the blackberry, red raspberry and black raspberry seed oils. Furthermore, the fatty acid compositions of the five berry seed oils were directly determined by gas chromatography coupled with mass spectrometry (GC-MS). In addition, the seed oils had total phenolic contents ranging 13.68–177.06 µmol GAE (gallic acid equivalent)/L oil, and significant scavenging capacities against DPPH, peroxyl, and ABTS<sup>+</sup> radicals. These results indicated that the combination of UPC<sup>2</sup> and QTOF MS could effectively identify and semi-quantify the TAGs compositions of the berry seed oils with sn-position information for the fatty acids. Understanding the TAGs compositions of these berry seed oils could improve the utilization of these potentially high nutritional value oils for human health. |
format |
article |
author |
Yinghua Luo Fanghao Yuan Yanfang Li Junyi (Danny) Wang Boyan Gao Liangli (Lucy) Yu |
author_facet |
Yinghua Luo Fanghao Yuan Yanfang Li Junyi (Danny) Wang Boyan Gao Liangli (Lucy) Yu |
author_sort |
Yinghua Luo |
title |
Triacylglycerol and Fatty Acid Compositions of Blackberry, Red Raspberry, Black Raspberry, Blueberry and Cranberry Seed Oils by Ultra-Performance Convergence Chromatography-Quadrupole Time-of-Flight Mass Spectrometry |
title_short |
Triacylglycerol and Fatty Acid Compositions of Blackberry, Red Raspberry, Black Raspberry, Blueberry and Cranberry Seed Oils by Ultra-Performance Convergence Chromatography-Quadrupole Time-of-Flight Mass Spectrometry |
title_full |
Triacylglycerol and Fatty Acid Compositions of Blackberry, Red Raspberry, Black Raspberry, Blueberry and Cranberry Seed Oils by Ultra-Performance Convergence Chromatography-Quadrupole Time-of-Flight Mass Spectrometry |
title_fullStr |
Triacylglycerol and Fatty Acid Compositions of Blackberry, Red Raspberry, Black Raspberry, Blueberry and Cranberry Seed Oils by Ultra-Performance Convergence Chromatography-Quadrupole Time-of-Flight Mass Spectrometry |
title_full_unstemmed |
Triacylglycerol and Fatty Acid Compositions of Blackberry, Red Raspberry, Black Raspberry, Blueberry and Cranberry Seed Oils by Ultra-Performance Convergence Chromatography-Quadrupole Time-of-Flight Mass Spectrometry |
title_sort |
triacylglycerol and fatty acid compositions of blackberry, red raspberry, black raspberry, blueberry and cranberry seed oils by ultra-performance convergence chromatography-quadrupole time-of-flight mass spectrometry |
publisher |
MDPI AG |
publishDate |
2021 |
url |
https://doaj.org/article/edc0683182124dfb91d6e241a5512b2a |
work_keys_str_mv |
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