Triacylglycerol and Fatty Acid Compositions of Blackberry, Red Raspberry, Black Raspberry, Blueberry and Cranberry Seed Oils by Ultra-Performance Convergence Chromatography-Quadrupole Time-of-Flight Mass Spectrometry

The triacylglycerol (TAG) compositions of blackberry, red raspberry, black raspberry, blueberry and cranberry seed oils were examined using ultra-performance convergence chromatography-quadrupole time-of-flight mass spectrometry (UPC<sup>2</sup>-QTOF MS). A total of 52, 53, 52, 59 and 58...

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Autores principales: Yinghua Luo, Fanghao Yuan, Yanfang Li, Junyi (Danny) Wang, Boyan Gao, Liangli (Lucy) Yu
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Publicado: MDPI AG 2021
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spelling oai:doaj.org-article:edc0683182124dfb91d6e241a5512b2a2021-11-25T17:32:11ZTriacylglycerol and Fatty Acid Compositions of Blackberry, Red Raspberry, Black Raspberry, Blueberry and Cranberry Seed Oils by Ultra-Performance Convergence Chromatography-Quadrupole Time-of-Flight Mass Spectrometry10.3390/foods101125302304-8158https://doaj.org/article/edc0683182124dfb91d6e241a5512b2a2021-10-01T00:00:00Zhttps://www.mdpi.com/2304-8158/10/11/2530https://doaj.org/toc/2304-8158The triacylglycerol (TAG) compositions of blackberry, red raspberry, black raspberry, blueberry and cranberry seed oils were examined using ultra-performance convergence chromatography-quadrupole time-of-flight mass spectrometry (UPC<sup>2</sup>-QTOF MS). A total of 52, 53, 52, 59 and 58 TAGs were detected and tentatively identified from the blackberry, red raspberry, black raspberry, blueberry and cranberry seed oils, respectively, according to their accurate molecular weight in MS1 and fragment ion profiles in MS2. OLL was the most abundant TAG in the blackberry, red raspberry and black raspberry seed oils. Furthermore, the fatty acid compositions of the five berry seed oils were directly determined by gas chromatography coupled with mass spectrometry (GC-MS). In addition, the seed oils had total phenolic contents ranging 13.68–177.06 µmol GAE (gallic acid equivalent)/L oil, and significant scavenging capacities against DPPH, peroxyl, and ABTS<sup>+</sup> radicals. These results indicated that the combination of UPC<sup>2</sup> and QTOF MS could effectively identify and semi-quantify the TAGs compositions of the berry seed oils with sn-position information for the fatty acids. Understanding the TAGs compositions of these berry seed oils could improve the utilization of these potentially high nutritional value oils for human health.Yinghua LuoFanghao YuanYanfang LiJunyi (Danny) WangBoyan GaoLiangli (Lucy) YuMDPI AGarticletriacylglycerol (TAG) compositionsberry seed oilsultra-performance convergence chromatography (UPC<sup>2</sup>)quadrupole time-of-flight mass spectrometry (QTOF MS)Chemical technologyTP1-1185ENFoods, Vol 10, Iss 2530, p 2530 (2021)
institution DOAJ
collection DOAJ
language EN
topic triacylglycerol (TAG) compositions
berry seed oils
ultra-performance convergence chromatography (UPC<sup>2</sup>)
quadrupole time-of-flight mass spectrometry (QTOF MS)
Chemical technology
TP1-1185
spellingShingle triacylglycerol (TAG) compositions
berry seed oils
ultra-performance convergence chromatography (UPC<sup>2</sup>)
quadrupole time-of-flight mass spectrometry (QTOF MS)
Chemical technology
TP1-1185
Yinghua Luo
Fanghao Yuan
Yanfang Li
Junyi (Danny) Wang
Boyan Gao
Liangli (Lucy) Yu
Triacylglycerol and Fatty Acid Compositions of Blackberry, Red Raspberry, Black Raspberry, Blueberry and Cranberry Seed Oils by Ultra-Performance Convergence Chromatography-Quadrupole Time-of-Flight Mass Spectrometry
description The triacylglycerol (TAG) compositions of blackberry, red raspberry, black raspberry, blueberry and cranberry seed oils were examined using ultra-performance convergence chromatography-quadrupole time-of-flight mass spectrometry (UPC<sup>2</sup>-QTOF MS). A total of 52, 53, 52, 59 and 58 TAGs were detected and tentatively identified from the blackberry, red raspberry, black raspberry, blueberry and cranberry seed oils, respectively, according to their accurate molecular weight in MS1 and fragment ion profiles in MS2. OLL was the most abundant TAG in the blackberry, red raspberry and black raspberry seed oils. Furthermore, the fatty acid compositions of the five berry seed oils were directly determined by gas chromatography coupled with mass spectrometry (GC-MS). In addition, the seed oils had total phenolic contents ranging 13.68–177.06 µmol GAE (gallic acid equivalent)/L oil, and significant scavenging capacities against DPPH, peroxyl, and ABTS<sup>+</sup> radicals. These results indicated that the combination of UPC<sup>2</sup> and QTOF MS could effectively identify and semi-quantify the TAGs compositions of the berry seed oils with sn-position information for the fatty acids. Understanding the TAGs compositions of these berry seed oils could improve the utilization of these potentially high nutritional value oils for human health.
format article
author Yinghua Luo
Fanghao Yuan
Yanfang Li
Junyi (Danny) Wang
Boyan Gao
Liangli (Lucy) Yu
author_facet Yinghua Luo
Fanghao Yuan
Yanfang Li
Junyi (Danny) Wang
Boyan Gao
Liangli (Lucy) Yu
author_sort Yinghua Luo
title Triacylglycerol and Fatty Acid Compositions of Blackberry, Red Raspberry, Black Raspberry, Blueberry and Cranberry Seed Oils by Ultra-Performance Convergence Chromatography-Quadrupole Time-of-Flight Mass Spectrometry
title_short Triacylglycerol and Fatty Acid Compositions of Blackberry, Red Raspberry, Black Raspberry, Blueberry and Cranberry Seed Oils by Ultra-Performance Convergence Chromatography-Quadrupole Time-of-Flight Mass Spectrometry
title_full Triacylglycerol and Fatty Acid Compositions of Blackberry, Red Raspberry, Black Raspberry, Blueberry and Cranberry Seed Oils by Ultra-Performance Convergence Chromatography-Quadrupole Time-of-Flight Mass Spectrometry
title_fullStr Triacylglycerol and Fatty Acid Compositions of Blackberry, Red Raspberry, Black Raspberry, Blueberry and Cranberry Seed Oils by Ultra-Performance Convergence Chromatography-Quadrupole Time-of-Flight Mass Spectrometry
title_full_unstemmed Triacylglycerol and Fatty Acid Compositions of Blackberry, Red Raspberry, Black Raspberry, Blueberry and Cranberry Seed Oils by Ultra-Performance Convergence Chromatography-Quadrupole Time-of-Flight Mass Spectrometry
title_sort triacylglycerol and fatty acid compositions of blackberry, red raspberry, black raspberry, blueberry and cranberry seed oils by ultra-performance convergence chromatography-quadrupole time-of-flight mass spectrometry
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/edc0683182124dfb91d6e241a5512b2a
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