Elucidation of the origin of chiral amplification in discrete molecular polyhedra

The sergeants-and-soldiers effect, in which a few chiral units induce chirality in a large number of achiral molecules, is difficult to quantify at the molecular level. Here, the authors devise an elegant strategy—combining theory and a system of pure organic polyhedra with chiral and achiral vertic...

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Autores principales:	Yu Wang, Hongxun Fang, Ionut Tranca, Hang Qu, Xinchang Wang, Albert J. Markvoort, Zhongqun Tian, Xiaoyu Cao
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/edc761a8530747be93fef908e03faf92
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spelling	oai:doaj.org-article:edc761a8530747be93fef908e03faf922021-12-02T15:34:07ZElucidation of the origin of chiral amplification in discrete molecular polyhedra10.1038/s41467-017-02605-x2041-1723https://doaj.org/article/edc761a8530747be93fef908e03faf922018-02-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-02605-xhttps://doaj.org/toc/2041-1723The sergeants-and-soldiers effect, in which a few chiral units induce chirality in a large number of achiral molecules, is difficult to quantify at the molecular level. Here, the authors devise an elegant strategy—combining theory and a system of pure organic polyhedra with chiral and achiral vertices—to understand the mechanism of chiral amplification in discrete molecular assemblies.Yu WangHongxun FangIonut TrancaHang QuXinchang WangAlbert J. MarkvoortZhongqun TianXiaoyu CaoNature PortfolioarticleScienceQENNature Communications, Vol 9, Iss 1, Pp 1-8 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Yu Wang Hongxun Fang Ionut Tranca Hang Qu Xinchang Wang Albert J. Markvoort Zhongqun Tian Xiaoyu Cao Elucidation of the origin of chiral amplification in discrete molecular polyhedra
description	The sergeants-and-soldiers effect, in which a few chiral units induce chirality in a large number of achiral molecules, is difficult to quantify at the molecular level. Here, the authors devise an elegant strategy—combining theory and a system of pure organic polyhedra with chiral and achiral vertices—to understand the mechanism of chiral amplification in discrete molecular assemblies.
format	article
author	Yu Wang Hongxun Fang Ionut Tranca Hang Qu Xinchang Wang Albert J. Markvoort Zhongqun Tian Xiaoyu Cao
author_facet	Yu Wang Hongxun Fang Ionut Tranca Hang Qu Xinchang Wang Albert J. Markvoort Zhongqun Tian Xiaoyu Cao
author_sort	Yu Wang
title	Elucidation of the origin of chiral amplification in discrete molecular polyhedra
title_short	Elucidation of the origin of chiral amplification in discrete molecular polyhedra
title_full	Elucidation of the origin of chiral amplification in discrete molecular polyhedra
title_fullStr	Elucidation of the origin of chiral amplification in discrete molecular polyhedra
title_full_unstemmed	Elucidation of the origin of chiral amplification in discrete molecular polyhedra
title_sort	elucidation of the origin of chiral amplification in discrete molecular polyhedra
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/edc761a8530747be93fef908e03faf92
work_keys_str_mv	AT yuwang elucidationoftheoriginofchiralamplificationindiscretemolecularpolyhedra AT hongxunfang elucidationoftheoriginofchiralamplificationindiscretemolecularpolyhedra AT ionuttranca elucidationoftheoriginofchiralamplificationindiscretemolecularpolyhedra AT hangqu elucidationoftheoriginofchiralamplificationindiscretemolecularpolyhedra AT xinchangwang elucidationoftheoriginofchiralamplificationindiscretemolecularpolyhedra AT albertjmarkvoort elucidationoftheoriginofchiralamplificationindiscretemolecularpolyhedra AT zhongquntian elucidationoftheoriginofchiralamplificationindiscretemolecularpolyhedra AT xiaoyucao elucidationoftheoriginofchiralamplificationindiscretemolecularpolyhedra
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Elucidation of the origin of chiral amplification in discrete molecular polyhedra

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