Catalytic asymmetric radical aminoperfluoroalkylation and aminodifluoromethylation of alkenes to versatile enantioenriched-fluoroalkyl amines

Methods for the asymmetric introduction of organofluorine groups are often limited by the lack of variability in the starting materials. Here the authors report an asymmetric radical process for the introduction of fluoroalkyl groups using readily available fluoroalkylated sulfonyl chlorides.

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Autores principales:	Jin-Shun Lin, Fu-Li Wang, Xiao-Yang Dong, Wei-Wei He, Yue Yuan, Su Chen, Xin-Yuan Liu
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2017
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/edd43031528b429fa392b2420cc36eec
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spelling	oai:doaj.org-article:edd43031528b429fa392b2420cc36eec2021-12-02T14:42:46ZCatalytic asymmetric radical aminoperfluoroalkylation and aminodifluoromethylation of alkenes to versatile enantioenriched-fluoroalkyl amines10.1038/ncomms148412041-1723https://doaj.org/article/edd43031528b429fa392b2420cc36eec2017-03-01T00:00:00Zhttps://doi.org/10.1038/ncomms14841https://doaj.org/toc/2041-1723Methods for the asymmetric introduction of organofluorine groups are often limited by the lack of variability in the starting materials. Here the authors report an asymmetric radical process for the introduction of fluoroalkyl groups using readily available fluoroalkylated sulfonyl chlorides.Jin-Shun LinFu-Li WangXiao-Yang DongWei-Wei HeYue YuanSu ChenXin-Yuan LiuNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-11 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Jin-Shun Lin Fu-Li Wang Xiao-Yang Dong Wei-Wei He Yue Yuan Su Chen Xin-Yuan Liu Catalytic asymmetric radical aminoperfluoroalkylation and aminodifluoromethylation of alkenes to versatile enantioenriched-fluoroalkyl amines
description	Methods for the asymmetric introduction of organofluorine groups are often limited by the lack of variability in the starting materials. Here the authors report an asymmetric radical process for the introduction of fluoroalkyl groups using readily available fluoroalkylated sulfonyl chlorides.
format	article
author	Jin-Shun Lin Fu-Li Wang Xiao-Yang Dong Wei-Wei He Yue Yuan Su Chen Xin-Yuan Liu
author_facet	Jin-Shun Lin Fu-Li Wang Xiao-Yang Dong Wei-Wei He Yue Yuan Su Chen Xin-Yuan Liu
author_sort	Jin-Shun Lin
title	Catalytic asymmetric radical aminoperfluoroalkylation and aminodifluoromethylation of alkenes to versatile enantioenriched-fluoroalkyl amines
title_short	Catalytic asymmetric radical aminoperfluoroalkylation and aminodifluoromethylation of alkenes to versatile enantioenriched-fluoroalkyl amines
title_full	Catalytic asymmetric radical aminoperfluoroalkylation and aminodifluoromethylation of alkenes to versatile enantioenriched-fluoroalkyl amines
title_fullStr	Catalytic asymmetric radical aminoperfluoroalkylation and aminodifluoromethylation of alkenes to versatile enantioenriched-fluoroalkyl amines
title_full_unstemmed	Catalytic asymmetric radical aminoperfluoroalkylation and aminodifluoromethylation of alkenes to versatile enantioenriched-fluoroalkyl amines
title_sort	catalytic asymmetric radical aminoperfluoroalkylation and aminodifluoromethylation of alkenes to versatile enantioenriched-fluoroalkyl amines
publisher	Nature Portfolio
publishDate	2017
url	https://doaj.org/article/edd43031528b429fa392b2420cc36eec
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Catalytic asymmetric radical aminoperfluoroalkylation and aminodifluoromethylation of alkenes to versatile enantioenriched-fluoroalkyl amines

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