Swelling Behaviour of Static Seals in Redox Flow Batteries

This paper analyses the implications of swelling in perspective of sealing technology for redox flow batteries (RFB). Mechanical failure due to swell in static sealing can occur on the elastomeric seal or on sealing flanges. The mechanical failure is in this case a fractured or deformed RFB componen...

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Autores principales: Detlef Jannes, Lothar Hörl, Frank Bauer
Formato: article
Lenguaje:EN
Publicado: Japanese Society of Tribologists 2021
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Acceso en línea:https://doaj.org/article/edd5c615985d43c1a85f3f987845c316
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spelling oai:doaj.org-article:edd5c615985d43c1a85f3f987845c3162021-11-05T09:31:04ZSwelling Behaviour of Static Seals in Redox Flow Batteries1881-219810.2474/trol.16.138https://doaj.org/article/edd5c615985d43c1a85f3f987845c3162021-06-01T00:00:00Zhttps://www.jstage.jst.go.jp/article/trol/16/2/16_138/_pdf/-char/enhttps://doaj.org/toc/1881-2198This paper analyses the implications of swelling in perspective of sealing technology for redox flow batteries (RFB). Mechanical failure due to swell in static sealing can occur on the elastomeric seal or on sealing flanges. The mechanical failure is in this case a fractured or deformed RFB component because of the swelling pressure. Swelling of such an elastomeric seal is a coupling of different physics phenomena, namely diffusion and solid mechanics. In an assembled RFB, seal swelling increases the contact pressure with the sealing flange, while making the components softer. It shifts the mechanical material properties of the components and also the stress tolerances. Graphite-polymer bipolar plates or PTFE / PP flowframes are common RFB sealing flanges and can become softer due to diffusion of the electrolyte fluid, making the flanges more prone to creep. These are time dependent effects that can create sealing failure or mechanical break of the sealing flanges and must be taken into account in RFB design. The presented experimental and modelling results validate the swelling behaviour for an assembled RFB. The compatibility tables of sealing materials in catalogues do not often differentiate swelling compatibility from chemical compatibility of a fluid. In addition, this paper proposes a basic selection procedure for swelling compatibility based on group experiments on Hansen solubility parameters (HSP).Detlef JannesLothar HörlFrank BauerJapanese Society of Tribologistsarticleredox flow batteriesswelling behaviourstatic sealsmodelexperimentPhysicsQC1-999Engineering (General). Civil engineering (General)TA1-2040Mechanical engineering and machineryTJ1-1570ChemistryQD1-999ENTribology Online, Vol 16, Iss 2, Pp 138-145 (2021)
institution DOAJ
collection DOAJ
language EN
topic redox flow batteries
swelling behaviour
static seals
model
experiment
Physics
QC1-999
Engineering (General). Civil engineering (General)
TA1-2040
Mechanical engineering and machinery
TJ1-1570
Chemistry
QD1-999
spellingShingle redox flow batteries
swelling behaviour
static seals
model
experiment
Physics
QC1-999
Engineering (General). Civil engineering (General)
TA1-2040
Mechanical engineering and machinery
TJ1-1570
Chemistry
QD1-999
Detlef Jannes
Lothar Hörl
Frank Bauer
Swelling Behaviour of Static Seals in Redox Flow Batteries
description This paper analyses the implications of swelling in perspective of sealing technology for redox flow batteries (RFB). Mechanical failure due to swell in static sealing can occur on the elastomeric seal or on sealing flanges. The mechanical failure is in this case a fractured or deformed RFB component because of the swelling pressure. Swelling of such an elastomeric seal is a coupling of different physics phenomena, namely diffusion and solid mechanics. In an assembled RFB, seal swelling increases the contact pressure with the sealing flange, while making the components softer. It shifts the mechanical material properties of the components and also the stress tolerances. Graphite-polymer bipolar plates or PTFE / PP flowframes are common RFB sealing flanges and can become softer due to diffusion of the electrolyte fluid, making the flanges more prone to creep. These are time dependent effects that can create sealing failure or mechanical break of the sealing flanges and must be taken into account in RFB design. The presented experimental and modelling results validate the swelling behaviour for an assembled RFB. The compatibility tables of sealing materials in catalogues do not often differentiate swelling compatibility from chemical compatibility of a fluid. In addition, this paper proposes a basic selection procedure for swelling compatibility based on group experiments on Hansen solubility parameters (HSP).
format article
author Detlef Jannes
Lothar Hörl
Frank Bauer
author_facet Detlef Jannes
Lothar Hörl
Frank Bauer
author_sort Detlef Jannes
title Swelling Behaviour of Static Seals in Redox Flow Batteries
title_short Swelling Behaviour of Static Seals in Redox Flow Batteries
title_full Swelling Behaviour of Static Seals in Redox Flow Batteries
title_fullStr Swelling Behaviour of Static Seals in Redox Flow Batteries
title_full_unstemmed Swelling Behaviour of Static Seals in Redox Flow Batteries
title_sort swelling behaviour of static seals in redox flow batteries
publisher Japanese Society of Tribologists
publishDate 2021
url https://doaj.org/article/edd5c615985d43c1a85f3f987845c316
work_keys_str_mv AT detlefjannes swellingbehaviourofstaticsealsinredoxflowbatteries
AT lotharhorl swellingbehaviourofstaticsealsinredoxflowbatteries
AT frankbauer swellingbehaviourofstaticsealsinredoxflowbatteries
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