NEW TRANS-1,2- CYCLOHEXYLDIAMINO-NN,N’N’ (CH2CO2)(CH2CO2H)3 ANION CONTAINING ADDUCTS AND DERIVATIVES: SYNTHESIS AND INFRARED STUDY
Five Cyclohexyldiamino-NN, N’N’(CH2CO2)(CH2CO2H)3 anion containing adducts and derivatives with tin, antimony and mercury halides have been synthesized and characterized by infrared spectroscopy. The suggested structures are discrete, the anion behaving as a monodentate or a monochelating ligand: t...
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| Autores principales: | , , |
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| Formato: | article |
| Lenguaje: | EN |
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Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
2017
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| Materias: | |
| Acceso en línea: | https://doaj.org/article/edf9abed1f5a4f53a2630537264dfda8 |
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| Sumario: | Five Cyclohexyldiamino-NN, N’N’(CH2CO2)(CH2CO2H)3 anion containing adducts and derivatives with tin, antimony and mercury halides have been synthesized and characterized by infrared spectroscopy. The suggested structures are discrete, the anion behaving as a monodentate or a monochelating ligand: the environments around the metallic centres are trigonal bipyramidal or octahedral.The carboxylic groups and the cation, when involved in extra OH---O, OH----Cl or NH---Cl or O hydrogen bonds may lead to supramolecular architectures.
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