Di-μ-chlorido-bis[(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)copper(II)] bis(trifluoromethanesulfonate)

In the centrosymmetric title complex, [Cu2Cl2(C15H11N3)2](CF3O3S)2, the CuII metal center is fivefold coordinated by two chloride ions and three nitrogen atoms of the terpyridine ligand in a distorted square-pyramidal geometry; two trifluoromethanesulfonate ions complete the outer coordination spher...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Rafael A. Adrian, Jose J. Duarte, Hadi D. Arman
Formato:	article
Lenguaje:	EN
Publicado:	International Union of Crystallography 2021
Materias:	crystal structure terpyridine copper trifluoromethanesulfonate salt bridging chloride π–π stacking Crystallography QD901-999
Acceso en línea:	https://doaj.org/article/ee13987fa16c44128986c91db400686f
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:ee13987fa16c44128986c91db400686f
record_format	dspace
spelling	oai:doaj.org-article:ee13987fa16c44128986c91db400686f2021-11-12T12:26:16ZDi-μ-chlorido-bis[(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)copper(II)] bis(trifluoromethanesulfonate)2414-314610.1107/S2414314621010968https://doaj.org/article/ee13987fa16c44128986c91db400686f2021-10-01T00:00:00Zhttp://scripts.iucr.org/cgi-bin/paper?S2414314621010968https://doaj.org/toc/2414-3146In the centrosymmetric title complex, [Cu2Cl2(C15H11N3)2](CF3O3S)2, the CuII metal center is fivefold coordinated by two chloride ions and three nitrogen atoms of the terpyridine ligand in a distorted square-pyramidal geometry; two trifluoromethanesulfonate ions complete the outer coordination sphere. π–π stacking interactions between the pyridyl rings in adjacent molecules contribute to the alignment of the complexes in columns along the a-axis. This structure represents the first example of a binuclear dication of formula [Cu(terpy)2Cl2]2+ with trifluoromethanesulfonate as counter-ions.Rafael A. AdrianJose J. DuarteHadi D. ArmanInternational Union of Crystallographyarticlecrystal structureterpyridinecoppertrifluoromethanesulfonate saltbridging chlorideπ–π stackingCrystallographyQD901-999ENIUCrData, Vol 6, Iss 10, p x211096 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	crystal structure terpyridine copper trifluoromethanesulfonate salt bridging chloride π–π stacking Crystallography QD901-999
spellingShingle	crystal structure terpyridine copper trifluoromethanesulfonate salt bridging chloride π–π stacking Crystallography QD901-999 Rafael A. Adrian Jose J. Duarte Hadi D. Arman Di-μ-chlorido-bis[(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)copper(II)] bis(trifluoromethanesulfonate)
description	In the centrosymmetric title complex, [Cu2Cl2(C15H11N3)2](CF3O3S)2, the CuII metal center is fivefold coordinated by two chloride ions and three nitrogen atoms of the terpyridine ligand in a distorted square-pyramidal geometry; two trifluoromethanesulfonate ions complete the outer coordination sphere. π–π stacking interactions between the pyridyl rings in adjacent molecules contribute to the alignment of the complexes in columns along the a-axis. This structure represents the first example of a binuclear dication of formula [Cu(terpy)2Cl2]2+ with trifluoromethanesulfonate as counter-ions.
format	article
author	Rafael A. Adrian Jose J. Duarte Hadi D. Arman
author_facet	Rafael A. Adrian Jose J. Duarte Hadi D. Arman
author_sort	Rafael A. Adrian
title	Di-μ-chlorido-bis[(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)copper(II)] bis(trifluoromethanesulfonate)
title_short	Di-μ-chlorido-bis[(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)copper(II)] bis(trifluoromethanesulfonate)
title_full	Di-μ-chlorido-bis[(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)copper(II)] bis(trifluoromethanesulfonate)
title_fullStr	Di-μ-chlorido-bis[(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)copper(II)] bis(trifluoromethanesulfonate)
title_full_unstemmed	Di-μ-chlorido-bis[(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)copper(II)] bis(trifluoromethanesulfonate)
title_sort	di-μ-chlorido-bis[(2,2′:6′,2′′-terpyridine-κ3n,n′,n′′)copper(ii)] bis(trifluoromethanesulfonate)
publisher	International Union of Crystallography
publishDate	2021
url	https://doaj.org/article/ee13987fa16c44128986c91db400686f
work_keys_str_mv	AT rafaelaadrian dimchloridobis2262terpyridinek3nnncopperiibistrifluoromethanesulfonate AT josejduarte dimchloridobis2262terpyridinek3nnncopperiibistrifluoromethanesulfonate AT hadidarman dimchloridobis2262terpyridinek3nnncopperiibistrifluoromethanesulfonate
_version_	1718430532532961280

Di-μ-chlorido-bis[(2,2′:6′,2′′-terpyridine-κ3N,N′,N′′)copper(II)] bis(trifluoromethanesulfonate)

Ejemplares similares