Electroreforming of Biomass for Value-Added Products

Humanity’s overreliance on fossil fuels for chemical and energy production has resulted in uncontrollable carbon emissions that have warranted widespread concern regarding global warming. To address this issue, there is a growing body of research on renewable resources such as biomass, of which cell...

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Autores principales: Zi Iun Lai, Li Quan Lee, Hong Li
Formato: article
Lenguaje:EN
Publicado: MDPI AG 2021
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Acceso en línea:https://doaj.org/article/ee1e62d6f79146d8b4e5bd43e25bd454
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spelling oai:doaj.org-article:ee1e62d6f79146d8b4e5bd43e25bd4542021-11-25T18:23:46ZElectroreforming of Biomass for Value-Added Products10.3390/mi121114052072-666Xhttps://doaj.org/article/ee1e62d6f79146d8b4e5bd43e25bd4542021-11-01T00:00:00Zhttps://www.mdpi.com/2072-666X/12/11/1405https://doaj.org/toc/2072-666XHumanity’s overreliance on fossil fuels for chemical and energy production has resulted in uncontrollable carbon emissions that have warranted widespread concern regarding global warming. To address this issue, there is a growing body of research on renewable resources such as biomass, of which cellulose is the most abundant type. In particular, the electrochemical reforming of biomass is especially promising, as it allows greater control over valorization processes and requires milder conditions. Driven by renewable electricity, electroreforming of biomass can be green and sustainable. Moreover, green hydrogen generation can be coupled to anodic biomass electroforming, which has attracted ever-increasing attention. The following review is a summary of recent developments related to electroreforming cellulose and its derivatives (glucose, hydroxymethylfurfural, levulinic acid). The electroreforming of biomass can be achieved on the anode of an electrochemical cell through electrooxidation, as well as on the cathode through electroreduction. Recent advances in the anodic electroreforming of cellulose and cellulose-derived glucose and 5-hydrooxylmethoylfurural (5-HMF) are first summarized. Then, the key achievements in the cathodic electroreforming of cellulose and cellulose-derived 5-HMF and levulinic acid are discussed. Afterward, the emerging research focusing on coupling hydrogen evolution with anodic biomass reforming for the cogeneration of green hydrogen fuel and value-added chemicals is reviewed. The final chapter of this paper provides our perspective on the challenges and future research directions of biomass electroreforming.Zi Iun LaiLi Quan LeeHong LiMDPI AGarticlebiomass electroreformingelectrooxidationelectrochemical hydrogenationcellulosegreen hydrogenMechanical engineering and machineryTJ1-1570ENMicromachines, Vol 12, Iss 1405, p 1405 (2021)
institution DOAJ
collection DOAJ
language EN
topic biomass electroreforming
electrooxidation
electrochemical hydrogenation
cellulose
green hydrogen
Mechanical engineering and machinery
TJ1-1570
spellingShingle biomass electroreforming
electrooxidation
electrochemical hydrogenation
cellulose
green hydrogen
Mechanical engineering and machinery
TJ1-1570
Zi Iun Lai
Li Quan Lee
Hong Li
Electroreforming of Biomass for Value-Added Products
description Humanity’s overreliance on fossil fuels for chemical and energy production has resulted in uncontrollable carbon emissions that have warranted widespread concern regarding global warming. To address this issue, there is a growing body of research on renewable resources such as biomass, of which cellulose is the most abundant type. In particular, the electrochemical reforming of biomass is especially promising, as it allows greater control over valorization processes and requires milder conditions. Driven by renewable electricity, electroreforming of biomass can be green and sustainable. Moreover, green hydrogen generation can be coupled to anodic biomass electroforming, which has attracted ever-increasing attention. The following review is a summary of recent developments related to electroreforming cellulose and its derivatives (glucose, hydroxymethylfurfural, levulinic acid). The electroreforming of biomass can be achieved on the anode of an electrochemical cell through electrooxidation, as well as on the cathode through electroreduction. Recent advances in the anodic electroreforming of cellulose and cellulose-derived glucose and 5-hydrooxylmethoylfurural (5-HMF) are first summarized. Then, the key achievements in the cathodic electroreforming of cellulose and cellulose-derived 5-HMF and levulinic acid are discussed. Afterward, the emerging research focusing on coupling hydrogen evolution with anodic biomass reforming for the cogeneration of green hydrogen fuel and value-added chemicals is reviewed. The final chapter of this paper provides our perspective on the challenges and future research directions of biomass electroreforming.
format article
author Zi Iun Lai
Li Quan Lee
Hong Li
author_facet Zi Iun Lai
Li Quan Lee
Hong Li
author_sort Zi Iun Lai
title Electroreforming of Biomass for Value-Added Products
title_short Electroreforming of Biomass for Value-Added Products
title_full Electroreforming of Biomass for Value-Added Products
title_fullStr Electroreforming of Biomass for Value-Added Products
title_full_unstemmed Electroreforming of Biomass for Value-Added Products
title_sort electroreforming of biomass for value-added products
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/ee1e62d6f79146d8b4e5bd43e25bd454
work_keys_str_mv AT ziiunlai electroreformingofbiomassforvalueaddedproducts
AT liquanlee electroreformingofbiomassforvalueaddedproducts
AT hongli electroreformingofbiomassforvalueaddedproducts
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