Tailoring nanoscopic confines to maximize catalytic activity of hydronium ions

The rates of acid-catalysed reactions vary in constrained environments. Here the authors show that molecularly sized pores greatly promote aqueous phase alcohol dehydration by enhancing the association between substrate and hydronium ions, and even by lowering the free energy barrier.

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Autores principales:	Hui Shi, Sebastian Eckstein, Aleksei Vjunov, Donald M. Camaioni, Johannes A. Lercher
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2017
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/ee88384707244e91aced7e3a4cf5209f
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spelling	oai:doaj.org-article:ee88384707244e91aced7e3a4cf5209f2021-12-02T17:01:19ZTailoring nanoscopic confines to maximize catalytic activity of hydronium ions10.1038/ncomms154422041-1723https://doaj.org/article/ee88384707244e91aced7e3a4cf5209f2017-05-01T00:00:00Zhttps://doi.org/10.1038/ncomms15442https://doaj.org/toc/2041-1723The rates of acid-catalysed reactions vary in constrained environments. Here the authors show that molecularly sized pores greatly promote aqueous phase alcohol dehydration by enhancing the association between substrate and hydronium ions, and even by lowering the free energy barrier.Hui ShiSebastian EcksteinAleksei VjunovDonald M. CamaioniJohannes A. LercherNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-7 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Hui Shi Sebastian Eckstein Aleksei Vjunov Donald M. Camaioni Johannes A. Lercher Tailoring nanoscopic confines to maximize catalytic activity of hydronium ions
description	The rates of acid-catalysed reactions vary in constrained environments. Here the authors show that molecularly sized pores greatly promote aqueous phase alcohol dehydration by enhancing the association between substrate and hydronium ions, and even by lowering the free energy barrier.
format	article
author	Hui Shi Sebastian Eckstein Aleksei Vjunov Donald M. Camaioni Johannes A. Lercher
author_facet	Hui Shi Sebastian Eckstein Aleksei Vjunov Donald M. Camaioni Johannes A. Lercher
author_sort	Hui Shi
title	Tailoring nanoscopic confines to maximize catalytic activity of hydronium ions
title_short	Tailoring nanoscopic confines to maximize catalytic activity of hydronium ions
title_full	Tailoring nanoscopic confines to maximize catalytic activity of hydronium ions
title_fullStr	Tailoring nanoscopic confines to maximize catalytic activity of hydronium ions
title_full_unstemmed	Tailoring nanoscopic confines to maximize catalytic activity of hydronium ions
title_sort	tailoring nanoscopic confines to maximize catalytic activity of hydronium ions
publisher	Nature Portfolio
publishDate	2017
url	https://doaj.org/article/ee88384707244e91aced7e3a4cf5209f
work_keys_str_mv	AT huishi tailoringnanoscopicconfinestomaximizecatalyticactivityofhydroniumions AT sebastianeckstein tailoringnanoscopicconfinestomaximizecatalyticactivityofhydroniumions AT alekseivjunov tailoringnanoscopicconfinestomaximizecatalyticactivityofhydroniumions AT donaldmcamaioni tailoringnanoscopicconfinestomaximizecatalyticactivityofhydroniumions AT johannesalercher tailoringnanoscopicconfinestomaximizecatalyticactivityofhydroniumions
_version_	1718382186190602240

Tailoring nanoscopic confines to maximize catalytic activity of hydronium ions

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