X-ray crystallographic study of copper (II) mixed ligand coordination compounds with classic dioximes and bidentate bipyridines

The coordination chemistry of copper(II) dioximates is discussed. The insertion of 4,4’-bis-pyridine or 4,4’-bis-pyridine ethane as bridging ligands between two robust Cu(II)-dioximate building blocks is giving rise to binuclear aggregates with the “wheel-and-axle” geometry.

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Autor principal: Croitor, Lilia
Formato: article
Lenguaje:EN
Publicado: D.Ghitu Institute of Electronic Engineering and Nanotechnologies 2011
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Acceso en línea:https://doaj.org/article/ee8aa7914aeb4c5d81deea7ee3d64334
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Sumario:The coordination chemistry of copper(II) dioximates is discussed. The insertion of 4,4’-bis-pyridine or 4,4’-bis-pyridine ethane as bridging ligands between two robust Cu(II)-dioximate building blocks is giving rise to binuclear aggregates with the “wheel-and-axle” geometry.