Mesporous 3C-SiC Hollow Fibers
Abstract In the present work, for the first time, we reported the exploration of mesoporous 3C-SiC hollow fibers via single-spinneret electrospinning of polyureasilazane (PSN) and polyvinylpyrrolidone (PVP) solution followed by high-temperature pyrolysis treatment. The resultant products were charac...
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Nature Portfolio
2017
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oai:doaj.org-article:ef22ce8b8f4348c6b826c82309b426172021-12-02T16:08:09ZMesporous 3C-SiC Hollow Fibers10.1038/s41598-017-02147-82045-2322https://doaj.org/article/ef22ce8b8f4348c6b826c82309b426172017-05-01T00:00:00Zhttps://doi.org/10.1038/s41598-017-02147-8https://doaj.org/toc/2045-2322Abstract In the present work, for the first time, we reported the exploration of mesoporous 3C-SiC hollow fibers via single-spinneret electrospinning of polyureasilazane (PSN) and polyvinylpyrrolidone (PVP) solution followed by high-temperature pyrolysis treatment. The resultant products were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), high-resolution transmission electron microscopy (HRTEM) and N2 adsorption. The as-prepared hollow fibers with totally mesoporous walls were uniformly sized in diameter and high purity in morphology. They were composed of single-crystalline 3C-SiC nanoparticles with a surface area of 21.75 m2/g and average pore diameter of ~34 nm. The PSN concentration played a determined role on the formation of hollow fibers rather than the conventional solid counterparts, enabling their growth in a tunable manner. A possible mechanism was proposed for the formation of mesoporous SiC hollow fiber.Yangwen LiuHuilin HouXinbo HeWeiyou YangNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 7, Iss 1, Pp 1-8 (2017) |
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Medicine R Science Q Yangwen Liu Huilin Hou Xinbo He Weiyou Yang Mesporous 3C-SiC Hollow Fibers |
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Abstract In the present work, for the first time, we reported the exploration of mesoporous 3C-SiC hollow fibers via single-spinneret electrospinning of polyureasilazane (PSN) and polyvinylpyrrolidone (PVP) solution followed by high-temperature pyrolysis treatment. The resultant products were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), high-resolution transmission electron microscopy (HRTEM) and N2 adsorption. The as-prepared hollow fibers with totally mesoporous walls were uniformly sized in diameter and high purity in morphology. They were composed of single-crystalline 3C-SiC nanoparticles with a surface area of 21.75 m2/g and average pore diameter of ~34 nm. The PSN concentration played a determined role on the formation of hollow fibers rather than the conventional solid counterparts, enabling their growth in a tunable manner. A possible mechanism was proposed for the formation of mesoporous SiC hollow fiber. |
format |
article |
author |
Yangwen Liu Huilin Hou Xinbo He Weiyou Yang |
author_facet |
Yangwen Liu Huilin Hou Xinbo He Weiyou Yang |
author_sort |
Yangwen Liu |
title |
Mesporous 3C-SiC Hollow Fibers |
title_short |
Mesporous 3C-SiC Hollow Fibers |
title_full |
Mesporous 3C-SiC Hollow Fibers |
title_fullStr |
Mesporous 3C-SiC Hollow Fibers |
title_full_unstemmed |
Mesporous 3C-SiC Hollow Fibers |
title_sort |
mesporous 3c-sic hollow fibers |
publisher |
Nature Portfolio |
publishDate |
2017 |
url |
https://doaj.org/article/ef22ce8b8f4348c6b826c82309b42617 |
work_keys_str_mv |
AT yangwenliu mesporous3csichollowfibers AT huilinhou mesporous3csichollowfibers AT xinbohe mesporous3csichollowfibers AT weiyouyang mesporous3csichollowfibers |
_version_ |
1718384628916551680 |