Mesporous 3C-SiC Hollow Fibers

Abstract In the present work, for the first time, we reported the exploration of mesoporous 3C-SiC hollow fibers via single-spinneret electrospinning of polyureasilazane (PSN) and polyvinylpyrrolidone (PVP) solution followed by high-temperature pyrolysis treatment. The resultant products were charac...

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Autores principales: Yangwen Liu, Huilin Hou, Xinbo He, Weiyou Yang
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Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/ef22ce8b8f4348c6b826c82309b42617
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spelling oai:doaj.org-article:ef22ce8b8f4348c6b826c82309b426172021-12-02T16:08:09ZMesporous 3C-SiC Hollow Fibers10.1038/s41598-017-02147-82045-2322https://doaj.org/article/ef22ce8b8f4348c6b826c82309b426172017-05-01T00:00:00Zhttps://doi.org/10.1038/s41598-017-02147-8https://doaj.org/toc/2045-2322Abstract In the present work, for the first time, we reported the exploration of mesoporous 3C-SiC hollow fibers via single-spinneret electrospinning of polyureasilazane (PSN) and polyvinylpyrrolidone (PVP) solution followed by high-temperature pyrolysis treatment. The resultant products were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), high-resolution transmission electron microscopy (HRTEM) and N2 adsorption. The as-prepared hollow fibers with totally mesoporous walls were uniformly sized in diameter and high purity in morphology. They were composed of single-crystalline 3C-SiC nanoparticles with a surface area of 21.75 m2/g and average pore diameter of ~34 nm. The PSN concentration played a determined role on the formation of hollow fibers rather than the conventional solid counterparts, enabling their growth in a tunable manner. A possible mechanism was proposed for the formation of mesoporous SiC hollow fiber.Yangwen LiuHuilin HouXinbo HeWeiyou YangNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 7, Iss 1, Pp 1-8 (2017)
institution DOAJ
collection DOAJ
language EN
topic Medicine
R
Science
Q
spellingShingle Medicine
R
Science
Q
Yangwen Liu
Huilin Hou
Xinbo He
Weiyou Yang
Mesporous 3C-SiC Hollow Fibers
description Abstract In the present work, for the first time, we reported the exploration of mesoporous 3C-SiC hollow fibers via single-spinneret electrospinning of polyureasilazane (PSN) and polyvinylpyrrolidone (PVP) solution followed by high-temperature pyrolysis treatment. The resultant products were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), high-resolution transmission electron microscopy (HRTEM) and N2 adsorption. The as-prepared hollow fibers with totally mesoporous walls were uniformly sized in diameter and high purity in morphology. They were composed of single-crystalline 3C-SiC nanoparticles with a surface area of 21.75 m2/g and average pore diameter of ~34 nm. The PSN concentration played a determined role on the formation of hollow fibers rather than the conventional solid counterparts, enabling their growth in a tunable manner. A possible mechanism was proposed for the formation of mesoporous SiC hollow fiber.
format article
author Yangwen Liu
Huilin Hou
Xinbo He
Weiyou Yang
author_facet Yangwen Liu
Huilin Hou
Xinbo He
Weiyou Yang
author_sort Yangwen Liu
title Mesporous 3C-SiC Hollow Fibers
title_short Mesporous 3C-SiC Hollow Fibers
title_full Mesporous 3C-SiC Hollow Fibers
title_fullStr Mesporous 3C-SiC Hollow Fibers
title_full_unstemmed Mesporous 3C-SiC Hollow Fibers
title_sort mesporous 3c-sic hollow fibers
publisher Nature Portfolio
publishDate 2017
url https://doaj.org/article/ef22ce8b8f4348c6b826c82309b42617
work_keys_str_mv AT yangwenliu mesporous3csichollowfibers
AT huilinhou mesporous3csichollowfibers
AT xinbohe mesporous3csichollowfibers
AT weiyouyang mesporous3csichollowfibers
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