Substituted Organotin Complexes of 4-Methoxybenzoic Acid for Reduction of Poly(vinyl Chloride) Photodegradation

Poly(vinyl chloride) suffers from degradation through oxidation and decomposition when exposed to radiation and high temperatures. Stabilizers are added to polymeric materials to inhibit their degradation and enable their use for a longer duration in harsh environments. The design of new additives t...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	Angham G. Hadi, Sadiq J. Baqir, Dina S. Ahmed, Gamal A. El-Hiti, Hassan Hashim, Ahmed Ahmed, Benson M. Kariuki, Emad Yousif
Formato:	article
Lenguaje:	EN
Publicado:	MDPI AG 2021
Materias:	poly(vinyl chloride) synthesis 4-methoxybenzoic acid-tin complexes irradiation photodegradation peroxide quenchers Organic chemistry QD241-441
Acceso en línea:	https://doaj.org/article/efd716924558426987a1561d6580bac2
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:efd716924558426987a1561d6580bac2
record_format	dspace
spelling	oai:doaj.org-article:efd716924558426987a1561d6580bac22021-11-25T18:48:39ZSubstituted Organotin Complexes of 4-Methoxybenzoic Acid for Reduction of Poly(vinyl Chloride) Photodegradation10.3390/polym132239462073-4360https://doaj.org/article/efd716924558426987a1561d6580bac22021-11-01T00:00:00Zhttps://www.mdpi.com/2073-4360/13/22/3946https://doaj.org/toc/2073-4360Poly(vinyl chloride) suffers from degradation through oxidation and decomposition when exposed to radiation and high temperatures. Stabilizers are added to polymeric materials to inhibit their degradation and enable their use for a longer duration in harsh environments. The design of new additives to stabilize poly(vinyl chloride) is therefore desirable. The current study includes the synthesis of new tin complexes of 4-methoxybenzoic acid and investigates their potential as photostabilizers for poly(vinyl chloride). The reaction of 4-methoxybenzoic acid and substituted tin chlorides gave the corresponding substituted tin complexes in good yields. The structures of the complexes were confirmed using analytical and spectroscopic methods. Poly(vinyl chloride) was doped with a small quantity (0.5%) of the tin complexes and homogenous thin films were made. The effects of the additives on the stability of the polymeric material on irradiation with ultraviolet light were assessed using different methods. Weight loss, production of small polymeric fragments, and drops in molecular weight were lower in the presence of the additives. The surface of poly(vinyl chloride), after irradiation, showed less damage in the films containing additives. The additives, in particular those containing aromatic (phenyl groups) substitutes, inhibited the photodegradation of polymeric films significantly. Such additives act as efficient ultraviolet absorbers, peroxide quenchers, and hydrogen chloride scavengers.Angham G. HadiSadiq J. BaqirDina S. AhmedGamal A. El-HitiHassan HashimAhmed AhmedBenson M. KariukiEmad YousifMDPI AGarticlepoly(vinyl chloride)synthesis4-methoxybenzoic acid-tin complexesirradiationphotodegradationperoxide quenchersOrganic chemistryQD241-441ENPolymers, Vol 13, Iss 3946, p 3946 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	poly(vinyl chloride) synthesis 4-methoxybenzoic acid-tin complexes irradiation photodegradation peroxide quenchers Organic chemistry QD241-441
spellingShingle	poly(vinyl chloride) synthesis 4-methoxybenzoic acid-tin complexes irradiation photodegradation peroxide quenchers Organic chemistry QD241-441 Angham G. Hadi Sadiq J. Baqir Dina S. Ahmed Gamal A. El-Hiti Hassan Hashim Ahmed Ahmed Benson M. Kariuki Emad Yousif Substituted Organotin Complexes of 4-Methoxybenzoic Acid for Reduction of Poly(vinyl Chloride) Photodegradation
description	Poly(vinyl chloride) suffers from degradation through oxidation and decomposition when exposed to radiation and high temperatures. Stabilizers are added to polymeric materials to inhibit their degradation and enable their use for a longer duration in harsh environments. The design of new additives to stabilize poly(vinyl chloride) is therefore desirable. The current study includes the synthesis of new tin complexes of 4-methoxybenzoic acid and investigates their potential as photostabilizers for poly(vinyl chloride). The reaction of 4-methoxybenzoic acid and substituted tin chlorides gave the corresponding substituted tin complexes in good yields. The structures of the complexes were confirmed using analytical and spectroscopic methods. Poly(vinyl chloride) was doped with a small quantity (0.5%) of the tin complexes and homogenous thin films were made. The effects of the additives on the stability of the polymeric material on irradiation with ultraviolet light were assessed using different methods. Weight loss, production of small polymeric fragments, and drops in molecular weight were lower in the presence of the additives. The surface of poly(vinyl chloride), after irradiation, showed less damage in the films containing additives. The additives, in particular those containing aromatic (phenyl groups) substitutes, inhibited the photodegradation of polymeric films significantly. Such additives act as efficient ultraviolet absorbers, peroxide quenchers, and hydrogen chloride scavengers.
format	article
author	Angham G. Hadi Sadiq J. Baqir Dina S. Ahmed Gamal A. El-Hiti Hassan Hashim Ahmed Ahmed Benson M. Kariuki Emad Yousif
author_facet	Angham G. Hadi Sadiq J. Baqir Dina S. Ahmed Gamal A. El-Hiti Hassan Hashim Ahmed Ahmed Benson M. Kariuki Emad Yousif
author_sort	Angham G. Hadi
title	Substituted Organotin Complexes of 4-Methoxybenzoic Acid for Reduction of Poly(vinyl Chloride) Photodegradation
title_short	Substituted Organotin Complexes of 4-Methoxybenzoic Acid for Reduction of Poly(vinyl Chloride) Photodegradation
title_full	Substituted Organotin Complexes of 4-Methoxybenzoic Acid for Reduction of Poly(vinyl Chloride) Photodegradation
title_fullStr	Substituted Organotin Complexes of 4-Methoxybenzoic Acid for Reduction of Poly(vinyl Chloride) Photodegradation
title_full_unstemmed	Substituted Organotin Complexes of 4-Methoxybenzoic Acid for Reduction of Poly(vinyl Chloride) Photodegradation
title_sort	substituted organotin complexes of 4-methoxybenzoic acid for reduction of poly(vinyl chloride) photodegradation
publisher	MDPI AG
publishDate	2021
url	https://doaj.org/article/efd716924558426987a1561d6580bac2
work_keys_str_mv	AT anghamghadi substitutedorganotincomplexesof4methoxybenzoicacidforreductionofpolyvinylchloridephotodegradation AT sadiqjbaqir substitutedorganotincomplexesof4methoxybenzoicacidforreductionofpolyvinylchloridephotodegradation AT dinasahmed substitutedorganotincomplexesof4methoxybenzoicacidforreductionofpolyvinylchloridephotodegradation AT gamalaelhiti substitutedorganotincomplexesof4methoxybenzoicacidforreductionofpolyvinylchloridephotodegradation AT hassanhashim substitutedorganotincomplexesof4methoxybenzoicacidforreductionofpolyvinylchloridephotodegradation AT ahmedahmed substitutedorganotincomplexesof4methoxybenzoicacidforreductionofpolyvinylchloridephotodegradation AT bensonmkariuki substitutedorganotincomplexesof4methoxybenzoicacidforreductionofpolyvinylchloridephotodegradation AT emadyousif substitutedorganotincomplexesof4methoxybenzoicacidforreductionofpolyvinylchloridephotodegradation
_version_	1718410687388057600

Substituted Organotin Complexes of 4-Methoxybenzoic Acid for Reduction of Poly(vinyl Chloride) Photodegradation

Ejemplares similares