Application of two spirobifluorene derivatives containing arylamine groups in organic light emitting diodes and fluorescent probe for water

Two novel spirobifluorene derivatives (<b>SPF-1</b> and <b>SPF-2</b>) incorporating arylamine groups were prepared. The fluorescent intensity of <b>SPF-1</b> can be made to measure the water content of organic solvents. The detection limits are respectively estima...

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Autores principales: QIU Lyuming, LU Yuhao, ZHANG Pengting, QIN Dongsheng, XIAO Haibo
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ZH
Publicado: Academic Journals Center of Shanghai Normal University 2021
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spelling oai:doaj.org-article:f009a084e4574985b7cb8ad87ffed6e52021-11-12T03:34:00ZApplication of two spirobifluorene derivatives containing arylamine groups in organic light emitting diodes and fluorescent probe for water1000-513710.3969/J.ISSN.1000-5137.2021.05.002https://doaj.org/article/f009a084e4574985b7cb8ad87ffed6e52021-10-01T00:00:00Zhttp://qktg.shnu.edu.cn/zrb/shsfqkszrb/ch/reader/view_abstract.aspx?file_no=20210502https://doaj.org/toc/1000-5137Two novel spirobifluorene derivatives (<b>SPF-1</b> and <b>SPF-2</b>) incorporating arylamine groups were prepared. The fluorescent intensity of <b>SPF-1</b> can be made to measure the water content of organic solvents. The detection limits are respectively estimated at 0.049% in tetrahydrofuran (THF) and 0.018% in 1,4-dioxane, which are superior to most reported results in the literature. The electroluminescence (EL) devices, where <b>SPF-1</b> and <b>SPF-2</b> serve as emitting materials, exhibit a peak around 506 nm with CIE coordinates of (0.24, 0.48) for <b>SPF-1</b> and dual band emissions at 471 and 502 nm with CIE coordinates of (0.31, 0.54) for <b>SPF-2</b>, respectively. These devices showed excellent performance with low turn-on voltages and high thermal stability. The maximum brightness,maximum current efficiencies and power efficiencies are 1 660 cd·m<sup>-2</sup>,2.1 cd·A<sup>-1</sup>and 1.28 lm·W<sup>-1</sup> for <b>SPF-1</b>,and 1 653 cd·m<sup>-2</sup>,2.55 cd·A<sup>-1</sup> and 1.23 lm·W<sup>-1</sup> for <b>SPF-2</b>, respectively.QIU LyumingLU YuhaoZHANG PengtingQIN DongshengXIAO HaiboAcademic Journals Center of Shanghai Normal Universityarticlefluorescent sensorwater contentelectroluminescent propertyspirobifluorenearylaminethermal stabilityScience (General)Q1-390ENZHJournal of Shanghai Normal University (Natural Sciences), Vol 50, Iss 5, Pp 528-537 (2021)
institution DOAJ
collection DOAJ
language EN
ZH
topic fluorescent sensor
water content
electroluminescent property
spirobifluorene
arylamine
thermal stability
Science (General)
Q1-390
spellingShingle fluorescent sensor
water content
electroluminescent property
spirobifluorene
arylamine
thermal stability
Science (General)
Q1-390
QIU Lyuming
LU Yuhao
ZHANG Pengting
QIN Dongsheng
XIAO Haibo
Application of two spirobifluorene derivatives containing arylamine groups in organic light emitting diodes and fluorescent probe for water
description Two novel spirobifluorene derivatives (<b>SPF-1</b> and <b>SPF-2</b>) incorporating arylamine groups were prepared. The fluorescent intensity of <b>SPF-1</b> can be made to measure the water content of organic solvents. The detection limits are respectively estimated at 0.049% in tetrahydrofuran (THF) and 0.018% in 1,4-dioxane, which are superior to most reported results in the literature. The electroluminescence (EL) devices, where <b>SPF-1</b> and <b>SPF-2</b> serve as emitting materials, exhibit a peak around 506 nm with CIE coordinates of (0.24, 0.48) for <b>SPF-1</b> and dual band emissions at 471 and 502 nm with CIE coordinates of (0.31, 0.54) for <b>SPF-2</b>, respectively. These devices showed excellent performance with low turn-on voltages and high thermal stability. The maximum brightness,maximum current efficiencies and power efficiencies are 1 660 cd·m<sup>-2</sup>,2.1 cd·A<sup>-1</sup>and 1.28 lm·W<sup>-1</sup> for <b>SPF-1</b>,and 1 653 cd·m<sup>-2</sup>,2.55 cd·A<sup>-1</sup> and 1.23 lm·W<sup>-1</sup> for <b>SPF-2</b>, respectively.
format article
author QIU Lyuming
LU Yuhao
ZHANG Pengting
QIN Dongsheng
XIAO Haibo
author_facet QIU Lyuming
LU Yuhao
ZHANG Pengting
QIN Dongsheng
XIAO Haibo
author_sort QIU Lyuming
title Application of two spirobifluorene derivatives containing arylamine groups in organic light emitting diodes and fluorescent probe for water
title_short Application of two spirobifluorene derivatives containing arylamine groups in organic light emitting diodes and fluorescent probe for water
title_full Application of two spirobifluorene derivatives containing arylamine groups in organic light emitting diodes and fluorescent probe for water
title_fullStr Application of two spirobifluorene derivatives containing arylamine groups in organic light emitting diodes and fluorescent probe for water
title_full_unstemmed Application of two spirobifluorene derivatives containing arylamine groups in organic light emitting diodes and fluorescent probe for water
title_sort application of two spirobifluorene derivatives containing arylamine groups in organic light emitting diodes and fluorescent probe for water
publisher Academic Journals Center of Shanghai Normal University
publishDate 2021
url https://doaj.org/article/f009a084e4574985b7cb8ad87ffed6e5
work_keys_str_mv AT qiulyuming applicationoftwospirobifluorenederivativescontainingarylaminegroupsinorganiclightemittingdiodesandfluorescentprobeforwater
AT luyuhao applicationoftwospirobifluorenederivativescontainingarylaminegroupsinorganiclightemittingdiodesandfluorescentprobeforwater
AT zhangpengting applicationoftwospirobifluorenederivativescontainingarylaminegroupsinorganiclightemittingdiodesandfluorescentprobeforwater
AT qindongsheng applicationoftwospirobifluorenederivativescontainingarylaminegroupsinorganiclightemittingdiodesandfluorescentprobeforwater
AT xiaohaibo applicationoftwospirobifluorenederivativescontainingarylaminegroupsinorganiclightemittingdiodesandfluorescentprobeforwater
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