Composited Film of Poly(3,4-ethylenedioxythiophene) and Graphene Oxide as Hole Transport Layer in Perovskite Solar Cells
It is important to lower the cost and stability of the organic–inorganic hybrid perovskite solar cells (PSCs) for industrial application. The commonly used hole transport materials (HTMs) such as Spiro-OMeTAD, poly[bis(4-phenyl)(2,4,6-trimethylphenyl)amine] (PTAA) and poly(3-hexylthiophene-2,5-diyl)...
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2021
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oai:doaj.org-article:f0505445eb1e42c181a9413bc58d4d192021-11-25T18:48:04ZComposited Film of Poly(3,4-ethylenedioxythiophene) and Graphene Oxide as Hole Transport Layer in Perovskite Solar Cells10.3390/polym132238952073-4360https://doaj.org/article/f0505445eb1e42c181a9413bc58d4d192021-11-01T00:00:00Zhttps://www.mdpi.com/2073-4360/13/22/3895https://doaj.org/toc/2073-4360It is important to lower the cost and stability of the organic–inorganic hybrid perovskite solar cells (PSCs) for industrial application. The commonly used hole transport materials (HTMs) such as Spiro-OMeTAD, poly[bis(4-phenyl)(2,4,6-trimethylphenyl)amine] (PTAA) and poly(3-hexylthiophene-2,5-diyl) (P3HT) are very expensive. Here, 3,4-ethylenedioxythiophene (EDOT) monomers are in-situ polymerized on the surface of graphene oxide (GO) as PEDOT-GO film. Compared to frequently used polystyrene sulfonic acid (PSS), GO avoids the corrosion of the perovskite and the use of H<sub>2</sub>O solvent. The composite PEDOT-GO film is between carbon pair electrode and perovskite layer as hole transport layer (HTL). The highest power conversion efficiency (PCE) is 14.09%.Tian YuanJin LiShimin WangMDPI AGarticleperovskite solar cellhole transport layercarbon materialspolymeric compositessolar energy materialsOrganic chemistryQD241-441ENPolymers, Vol 13, Iss 3895, p 3895 (2021) |
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DOAJ |
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perovskite solar cell hole transport layer carbon materials polymeric composites solar energy materials Organic chemistry QD241-441 |
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perovskite solar cell hole transport layer carbon materials polymeric composites solar energy materials Organic chemistry QD241-441 Tian Yuan Jin Li Shimin Wang Composited Film of Poly(3,4-ethylenedioxythiophene) and Graphene Oxide as Hole Transport Layer in Perovskite Solar Cells |
description |
It is important to lower the cost and stability of the organic–inorganic hybrid perovskite solar cells (PSCs) for industrial application. The commonly used hole transport materials (HTMs) such as Spiro-OMeTAD, poly[bis(4-phenyl)(2,4,6-trimethylphenyl)amine] (PTAA) and poly(3-hexylthiophene-2,5-diyl) (P3HT) are very expensive. Here, 3,4-ethylenedioxythiophene (EDOT) monomers are in-situ polymerized on the surface of graphene oxide (GO) as PEDOT-GO film. Compared to frequently used polystyrene sulfonic acid (PSS), GO avoids the corrosion of the perovskite and the use of H<sub>2</sub>O solvent. The composite PEDOT-GO film is between carbon pair electrode and perovskite layer as hole transport layer (HTL). The highest power conversion efficiency (PCE) is 14.09%. |
format |
article |
author |
Tian Yuan Jin Li Shimin Wang |
author_facet |
Tian Yuan Jin Li Shimin Wang |
author_sort |
Tian Yuan |
title |
Composited Film of Poly(3,4-ethylenedioxythiophene) and Graphene Oxide as Hole Transport Layer in Perovskite Solar Cells |
title_short |
Composited Film of Poly(3,4-ethylenedioxythiophene) and Graphene Oxide as Hole Transport Layer in Perovskite Solar Cells |
title_full |
Composited Film of Poly(3,4-ethylenedioxythiophene) and Graphene Oxide as Hole Transport Layer in Perovskite Solar Cells |
title_fullStr |
Composited Film of Poly(3,4-ethylenedioxythiophene) and Graphene Oxide as Hole Transport Layer in Perovskite Solar Cells |
title_full_unstemmed |
Composited Film of Poly(3,4-ethylenedioxythiophene) and Graphene Oxide as Hole Transport Layer in Perovskite Solar Cells |
title_sort |
composited film of poly(3,4-ethylenedioxythiophene) and graphene oxide as hole transport layer in perovskite solar cells |
publisher |
MDPI AG |
publishDate |
2021 |
url |
https://doaj.org/article/f0505445eb1e42c181a9413bc58d4d19 |
work_keys_str_mv |
AT tianyuan compositedfilmofpoly34ethylenedioxythiopheneandgrapheneoxideasholetransportlayerinperovskitesolarcells AT jinli compositedfilmofpoly34ethylenedioxythiopheneandgrapheneoxideasholetransportlayerinperovskitesolarcells AT shiminwang compositedfilmofpoly34ethylenedioxythiopheneandgrapheneoxideasholetransportlayerinperovskitesolarcells |
_version_ |
1718410748401549312 |