Composited Film of Poly(3,4-ethylenedioxythiophene) and Graphene Oxide as Hole Transport Layer in Perovskite Solar Cells

It is important to lower the cost and stability of the organic–inorganic hybrid perovskite solar cells (PSCs) for industrial application. The commonly used hole transport materials (HTMs) such as Spiro-OMeTAD, poly[bis(4-phenyl)(2,4,6-trimethylphenyl)amine] (PTAA) and poly(3-hexylthiophene-2,5-diyl)...

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Autores principales: Tian Yuan, Jin Li, Shimin Wang
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Lenguaje:EN
Publicado: MDPI AG 2021
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spelling oai:doaj.org-article:f0505445eb1e42c181a9413bc58d4d192021-11-25T18:48:04ZComposited Film of Poly(3,4-ethylenedioxythiophene) and Graphene Oxide as Hole Transport Layer in Perovskite Solar Cells10.3390/polym132238952073-4360https://doaj.org/article/f0505445eb1e42c181a9413bc58d4d192021-11-01T00:00:00Zhttps://www.mdpi.com/2073-4360/13/22/3895https://doaj.org/toc/2073-4360It is important to lower the cost and stability of the organic–inorganic hybrid perovskite solar cells (PSCs) for industrial application. The commonly used hole transport materials (HTMs) such as Spiro-OMeTAD, poly[bis(4-phenyl)(2,4,6-trimethylphenyl)amine] (PTAA) and poly(3-hexylthiophene-2,5-diyl) (P3HT) are very expensive. Here, 3,4-ethylenedioxythiophene (EDOT) monomers are in-situ polymerized on the surface of graphene oxide (GO) as PEDOT-GO film. Compared to frequently used polystyrene sulfonic acid (PSS), GO avoids the corrosion of the perovskite and the use of H<sub>2</sub>O solvent. The composite PEDOT-GO film is between carbon pair electrode and perovskite layer as hole transport layer (HTL). The highest power conversion efficiency (PCE) is 14.09%.Tian YuanJin LiShimin WangMDPI AGarticleperovskite solar cellhole transport layercarbon materialspolymeric compositessolar energy materialsOrganic chemistryQD241-441ENPolymers, Vol 13, Iss 3895, p 3895 (2021)
institution DOAJ
collection DOAJ
language EN
topic perovskite solar cell
hole transport layer
carbon materials
polymeric composites
solar energy materials
Organic chemistry
QD241-441
spellingShingle perovskite solar cell
hole transport layer
carbon materials
polymeric composites
solar energy materials
Organic chemistry
QD241-441
Tian Yuan
Jin Li
Shimin Wang
Composited Film of Poly(3,4-ethylenedioxythiophene) and Graphene Oxide as Hole Transport Layer in Perovskite Solar Cells
description It is important to lower the cost and stability of the organic–inorganic hybrid perovskite solar cells (PSCs) for industrial application. The commonly used hole transport materials (HTMs) such as Spiro-OMeTAD, poly[bis(4-phenyl)(2,4,6-trimethylphenyl)amine] (PTAA) and poly(3-hexylthiophene-2,5-diyl) (P3HT) are very expensive. Here, 3,4-ethylenedioxythiophene (EDOT) monomers are in-situ polymerized on the surface of graphene oxide (GO) as PEDOT-GO film. Compared to frequently used polystyrene sulfonic acid (PSS), GO avoids the corrosion of the perovskite and the use of H<sub>2</sub>O solvent. The composite PEDOT-GO film is between carbon pair electrode and perovskite layer as hole transport layer (HTL). The highest power conversion efficiency (PCE) is 14.09%.
format article
author Tian Yuan
Jin Li
Shimin Wang
author_facet Tian Yuan
Jin Li
Shimin Wang
author_sort Tian Yuan
title Composited Film of Poly(3,4-ethylenedioxythiophene) and Graphene Oxide as Hole Transport Layer in Perovskite Solar Cells
title_short Composited Film of Poly(3,4-ethylenedioxythiophene) and Graphene Oxide as Hole Transport Layer in Perovskite Solar Cells
title_full Composited Film of Poly(3,4-ethylenedioxythiophene) and Graphene Oxide as Hole Transport Layer in Perovskite Solar Cells
title_fullStr Composited Film of Poly(3,4-ethylenedioxythiophene) and Graphene Oxide as Hole Transport Layer in Perovskite Solar Cells
title_full_unstemmed Composited Film of Poly(3,4-ethylenedioxythiophene) and Graphene Oxide as Hole Transport Layer in Perovskite Solar Cells
title_sort composited film of poly(3,4-ethylenedioxythiophene) and graphene oxide as hole transport layer in perovskite solar cells
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/f0505445eb1e42c181a9413bc58d4d19
work_keys_str_mv AT tianyuan compositedfilmofpoly34ethylenedioxythiopheneandgrapheneoxideasholetransportlayerinperovskitesolarcells
AT jinli compositedfilmofpoly34ethylenedioxythiopheneandgrapheneoxideasholetransportlayerinperovskitesolarcells
AT shiminwang compositedfilmofpoly34ethylenedioxythiopheneandgrapheneoxideasholetransportlayerinperovskitesolarcells
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