Developing a Thin Film Composite Membrane with Hydrophilic Sulfonated Substrate on Nonwoven Backing Fabric Support for Forward Osmosis

This study describes the fabrication of sulfonated polyethersulfone (SPES) as a super-hydrophilic substrate for developing a composite forward osmosis (FO) membrane on a nonwoven backing fabric support. SPES was prepared through an indirect sulfonation procedure and then blended with PES at a certai...

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Autores principales: Soleyman Sahebi, Mohammad Kahrizi, Nasim Fadaie, Soheil Hadadpour, Bahman Ramavandi, Ralph Rolly Gonzales
Formato: article
Lenguaje:EN
Publicado: MDPI AG 2021
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spelling oai:doaj.org-article:f0b9c946c6e043aabc18cdcfb35d96442021-11-25T18:19:32ZDeveloping a Thin Film Composite Membrane with Hydrophilic Sulfonated Substrate on Nonwoven Backing Fabric Support for Forward Osmosis10.3390/membranes111108132077-0375https://doaj.org/article/f0b9c946c6e043aabc18cdcfb35d96442021-10-01T00:00:00Zhttps://www.mdpi.com/2077-0375/11/11/813https://doaj.org/toc/2077-0375This study describes the fabrication of sulfonated polyethersulfone (SPES) as a super-hydrophilic substrate for developing a composite forward osmosis (FO) membrane on a nonwoven backing fabric support. SPES was prepared through an indirect sulfonation procedure and then blended with PES at a certain ratio. Applying SPES as the substrate affected membrane properties, such as porosity, total thickness, morphology, and hydrophilicity. The PES-based FO membrane with a finger-like structure had lower performance in comparison with the SPES based FO membrane having a sponge-like structure. The finger-like morphology changed to a sponge-like morphology with the increase in the SPES concentration. The FO membrane based on a more hydrophilic substrate via sulfonation had a sponge morphology and showed better water flux results. Water flux of 26.1 L m<sup>−2</sup> h<sup>−1</sup> and specific reverse solute flux of 0.66 g L<sup>−1</sup> were attained at a SPES blend ratio of 50 wt % when 3 M NaCl was used as the draw solution and DI water as feed solution under the FO mode. This work offers significant insights into understanding the factors affecting FO membrane performance, such as porosity and functionality.Soleyman SahebiMohammad KahriziNasim FadaieSoheil HadadpourBahman RamavandiRalph Rolly GonzalesMDPI AGarticleforward osmosishydrophilic substratesulfonated polyethersulfonethin-film compositenonwoven-embedded substrateChemical technologyTP1-1185Chemical engineeringTP155-156ENMembranes, Vol 11, Iss 813, p 813 (2021)
institution DOAJ
collection DOAJ
language EN
topic forward osmosis
hydrophilic substrate
sulfonated polyethersulfone
thin-film composite
nonwoven-embedded substrate
Chemical technology
TP1-1185
Chemical engineering
TP155-156
spellingShingle forward osmosis
hydrophilic substrate
sulfonated polyethersulfone
thin-film composite
nonwoven-embedded substrate
Chemical technology
TP1-1185
Chemical engineering
TP155-156
Soleyman Sahebi
Mohammad Kahrizi
Nasim Fadaie
Soheil Hadadpour
Bahman Ramavandi
Ralph Rolly Gonzales
Developing a Thin Film Composite Membrane with Hydrophilic Sulfonated Substrate on Nonwoven Backing Fabric Support for Forward Osmosis
description This study describes the fabrication of sulfonated polyethersulfone (SPES) as a super-hydrophilic substrate for developing a composite forward osmosis (FO) membrane on a nonwoven backing fabric support. SPES was prepared through an indirect sulfonation procedure and then blended with PES at a certain ratio. Applying SPES as the substrate affected membrane properties, such as porosity, total thickness, morphology, and hydrophilicity. The PES-based FO membrane with a finger-like structure had lower performance in comparison with the SPES based FO membrane having a sponge-like structure. The finger-like morphology changed to a sponge-like morphology with the increase in the SPES concentration. The FO membrane based on a more hydrophilic substrate via sulfonation had a sponge morphology and showed better water flux results. Water flux of 26.1 L m<sup>−2</sup> h<sup>−1</sup> and specific reverse solute flux of 0.66 g L<sup>−1</sup> were attained at a SPES blend ratio of 50 wt % when 3 M NaCl was used as the draw solution and DI water as feed solution under the FO mode. This work offers significant insights into understanding the factors affecting FO membrane performance, such as porosity and functionality.
format article
author Soleyman Sahebi
Mohammad Kahrizi
Nasim Fadaie
Soheil Hadadpour
Bahman Ramavandi
Ralph Rolly Gonzales
author_facet Soleyman Sahebi
Mohammad Kahrizi
Nasim Fadaie
Soheil Hadadpour
Bahman Ramavandi
Ralph Rolly Gonzales
author_sort Soleyman Sahebi
title Developing a Thin Film Composite Membrane with Hydrophilic Sulfonated Substrate on Nonwoven Backing Fabric Support for Forward Osmosis
title_short Developing a Thin Film Composite Membrane with Hydrophilic Sulfonated Substrate on Nonwoven Backing Fabric Support for Forward Osmosis
title_full Developing a Thin Film Composite Membrane with Hydrophilic Sulfonated Substrate on Nonwoven Backing Fabric Support for Forward Osmosis
title_fullStr Developing a Thin Film Composite Membrane with Hydrophilic Sulfonated Substrate on Nonwoven Backing Fabric Support for Forward Osmosis
title_full_unstemmed Developing a Thin Film Composite Membrane with Hydrophilic Sulfonated Substrate on Nonwoven Backing Fabric Support for Forward Osmosis
title_sort developing a thin film composite membrane with hydrophilic sulfonated substrate on nonwoven backing fabric support for forward osmosis
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/f0b9c946c6e043aabc18cdcfb35d9644
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AT mohammadkahrizi developingathinfilmcompositemembranewithhydrophilicsulfonatedsubstrateonnonwovenbackingfabricsupportforforwardosmosis
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AT ralphrollygonzales developingathinfilmcompositemembranewithhydrophilicsulfonatedsubstrateonnonwovenbackingfabricsupportforforwardosmosis
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