Redox-switchable breathing behavior in tetrathiafulvalene-based metal–organic frameworks

Redox-switchable breathing behavior in tetrathiafulvalene-based metal–organic frameworks

Modulating the adsorption behaviours of metal-organic frameworks using external stimuli is desirable, but challenging to achieve. Here, Zhou and colleagues design an indium-based MOF in which tetrathiafulvalene ligands undergo reversible redox reactions that alter the framework breathing behaviour.

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Autores principales: Jian Su, Shuai Yuan, Hai-Ying Wang, Lan Huang, Jing-Yuan Ge, Elizabeth Joseph, Junsheng Qin, Tahir Cagin, Jing-Lin Zuo, Hong-Cai Zhou
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/f0d1b01c25dc4d5eb70b7e4abc0fa5aa
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spelling oai:doaj.org-article:f0d1b01c25dc4d5eb70b7e4abc0fa5aa2021-12-02T13:24:14ZRedox-switchable breathing behavior in tetrathiafulvalene-based metal–organic frameworks10.1038/s41467-017-02256-y2041-1723https://doaj.org/article/f0d1b01c25dc4d5eb70b7e4abc0fa5aa2017-12-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-02256-yhttps://doaj.org/toc/2041-1723Modulating the adsorption behaviours of metal-organic frameworks using external stimuli is desirable, but challenging to achieve. Here, Zhou and colleagues design an indium-based MOF in which tetrathiafulvalene ligands undergo reversible redox reactions that alter the framework breathing behaviour.Jian SuShuai YuanHai-Ying WangLan HuangJing-Yuan GeElizabeth JosephJunsheng QinTahir CaginJing-Lin ZuoHong-Cai ZhouNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-8 (2017)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Jian Su
Shuai Yuan
Hai-Ying Wang
Lan Huang
Jing-Yuan Ge
Elizabeth Joseph
Junsheng Qin
Tahir Cagin
Jing-Lin Zuo
Hong-Cai Zhou
Redox-switchable breathing behavior in tetrathiafulvalene-based metal–organic frameworks
description Modulating the adsorption behaviours of metal-organic frameworks using external stimuli is desirable, but challenging to achieve. Here, Zhou and colleagues design an indium-based MOF in which tetrathiafulvalene ligands undergo reversible redox reactions that alter the framework breathing behaviour.
format article
author Jian Su
Shuai Yuan
Hai-Ying Wang
Lan Huang
Jing-Yuan Ge
Elizabeth Joseph
Junsheng Qin
Tahir Cagin
Jing-Lin Zuo
Hong-Cai Zhou
author_facet Jian Su
Shuai Yuan
Hai-Ying Wang
Lan Huang
Jing-Yuan Ge
Elizabeth Joseph
Junsheng Qin
Tahir Cagin
Jing-Lin Zuo
Hong-Cai Zhou
author_sort Jian Su
title Redox-switchable breathing behavior in tetrathiafulvalene-based metal–organic frameworks
title_short Redox-switchable breathing behavior in tetrathiafulvalene-based metal–organic frameworks
title_full Redox-switchable breathing behavior in tetrathiafulvalene-based metal–organic frameworks
title_fullStr Redox-switchable breathing behavior in tetrathiafulvalene-based metal–organic frameworks
title_full_unstemmed Redox-switchable breathing behavior in tetrathiafulvalene-based metal–organic frameworks
title_sort redox-switchable breathing behavior in tetrathiafulvalene-based metal–organic frameworks
publisher Nature Portfolio
publishDate 2017
url https://doaj.org/article/f0d1b01c25dc4d5eb70b7e4abc0fa5aa
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AT shuaiyuan redoxswitchablebreathingbehaviorintetrathiafulvalenebasedmetalorganicframeworks
AT haiyingwang redoxswitchablebreathingbehaviorintetrathiafulvalenebasedmetalorganicframeworks
AT lanhuang redoxswitchablebreathingbehaviorintetrathiafulvalenebasedmetalorganicframeworks
AT jingyuange redoxswitchablebreathingbehaviorintetrathiafulvalenebasedmetalorganicframeworks
AT elizabethjoseph redoxswitchablebreathingbehaviorintetrathiafulvalenebasedmetalorganicframeworks
AT junshengqin redoxswitchablebreathingbehaviorintetrathiafulvalenebasedmetalorganicframeworks
AT tahircagin redoxswitchablebreathingbehaviorintetrathiafulvalenebasedmetalorganicframeworks
AT jinglinzuo redoxswitchablebreathingbehaviorintetrathiafulvalenebasedmetalorganicframeworks
AT hongcaizhou redoxswitchablebreathingbehaviorintetrathiafulvalenebasedmetalorganicframeworks
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