Redox-switchable breathing behavior in tetrathiafulvalene-based metal–organic frameworks

Modulating the adsorption behaviours of metal-organic frameworks using external stimuli is desirable, but challenging to achieve. Here, Zhou and colleagues design an indium-based MOF in which tetrathiafulvalene ligands undergo reversible redox reactions that alter the framework breathing behaviour.

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Autores principales: Jian Su, Shuai Yuan, Hai-Ying Wang, Lan Huang, Jing-Yuan Ge, Elizabeth Joseph, Junsheng Qin, Tahir Cagin, Jing-Lin Zuo, Hong-Cai Zhou
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/f0d1b01c25dc4d5eb70b7e4abc0fa5aa
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