Adsorption of Heavy Metals from Aqueous Solution onto Sawdust Activated Carbon

In this study, sawdust as a cheap method and abundant raw material was utilized to produce active carbon (SDAC). Physiochemical activation was utilized where potassium hydroxide   used as a chemical activating agent and carbon dioxide was used as a physical activating agent. Taguchi method of exper...

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Autores principales: Marah W. Khalid, Sami D. Salman
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Lenguaje:EN
Publicado: Al-Khwarizmi College of Engineering – University of Baghdad 2019
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Acceso en línea:https://doaj.org/article/f0e8517e988f4032a4d1d006a8957b94
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spelling oai:doaj.org-article:f0e8517e988f4032a4d1d006a8957b942021-12-02T11:05:13ZAdsorption of Heavy Metals from Aqueous Solution onto Sawdust Activated Carbon1818-11712312-0789https://doaj.org/article/f0e8517e988f4032a4d1d006a8957b942019-09-01T00:00:00Zhttp://alkej.uobaghdad.edu.iq/index.php/alkej/article/view/650https://doaj.org/toc/1818-1171https://doaj.org/toc/2312-0789 In this study, sawdust as a cheap method and abundant raw material was utilized to produce active carbon (SDAC). Physiochemical activation was utilized where potassium hydroxide   used as a chemical activating agent and carbon dioxide was used as a physical activating agent. Taguchi method of experimental design was used to find the optimum conditions of SDAC production. The produced SDAC was characterized using SEM to investigate surface morphology and BET to estimate the specific surface area. SDAC was used in aqueous lead ions adsorption. Adsorption process was modeled statistically and represented by an empirical model. The highest specific surface area of SDAC was 688.3 m2/gm. Langmuir and Freundlich isotherms were used to fit the adsorption process, where equilibrium data was best represented by Langmuir isotherm model.  Pseudo-first order and pseudo-second order equations were used to study adsorption kinetics, lead adsorption on SDAC fitted pseudo- second order more adequately. Best removal efficiency was found to be 99.63% with highest adsorption capacity of 19.92 mg/g.   Marah W. KhalidSami D. SalmanAl-Khwarizmi College of Engineering – University of BaghdadarticleChemical engineeringTP155-156Engineering (General). Civil engineering (General)TA1-2040ENAl-Khawarizmi Engineering Journal, Vol 15, Iss 3 (2019)
institution DOAJ
collection DOAJ
language EN
topic Chemical engineering
TP155-156
Engineering (General). Civil engineering (General)
TA1-2040
spellingShingle Chemical engineering
TP155-156
Engineering (General). Civil engineering (General)
TA1-2040
Marah W. Khalid
Sami D. Salman
Adsorption of Heavy Metals from Aqueous Solution onto Sawdust Activated Carbon
description In this study, sawdust as a cheap method and abundant raw material was utilized to produce active carbon (SDAC). Physiochemical activation was utilized where potassium hydroxide   used as a chemical activating agent and carbon dioxide was used as a physical activating agent. Taguchi method of experimental design was used to find the optimum conditions of SDAC production. The produced SDAC was characterized using SEM to investigate surface morphology and BET to estimate the specific surface area. SDAC was used in aqueous lead ions adsorption. Adsorption process was modeled statistically and represented by an empirical model. The highest specific surface area of SDAC was 688.3 m2/gm. Langmuir and Freundlich isotherms were used to fit the adsorption process, where equilibrium data was best represented by Langmuir isotherm model.  Pseudo-first order and pseudo-second order equations were used to study adsorption kinetics, lead adsorption on SDAC fitted pseudo- second order more adequately. Best removal efficiency was found to be 99.63% with highest adsorption capacity of 19.92 mg/g.  
format article
author Marah W. Khalid
Sami D. Salman
author_facet Marah W. Khalid
Sami D. Salman
author_sort Marah W. Khalid
title Adsorption of Heavy Metals from Aqueous Solution onto Sawdust Activated Carbon
title_short Adsorption of Heavy Metals from Aqueous Solution onto Sawdust Activated Carbon
title_full Adsorption of Heavy Metals from Aqueous Solution onto Sawdust Activated Carbon
title_fullStr Adsorption of Heavy Metals from Aqueous Solution onto Sawdust Activated Carbon
title_full_unstemmed Adsorption of Heavy Metals from Aqueous Solution onto Sawdust Activated Carbon
title_sort adsorption of heavy metals from aqueous solution onto sawdust activated carbon
publisher Al-Khwarizmi College of Engineering – University of Baghdad
publishDate 2019
url https://doaj.org/article/f0e8517e988f4032a4d1d006a8957b94
work_keys_str_mv AT marahwkhalid adsorptionofheavymetalsfromaqueoussolutionontosawdustactivatedcarbon
AT samidsalman adsorptionofheavymetalsfromaqueoussolutionontosawdustactivatedcarbon
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